• Carbon letters
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• v.7 no.2
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• pp.97-104
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• 2006

The influence of carbon surface area, carbon-oxygen groups associated with the carbon surface and the solution pH on the adsorption of Pb(II) ions from aqueous solutions has been studied using three activated carbons. The adsorption isotherms are Type I of BET classification and the data obeys Langmuir adsorption equation. The BET surface area has little effect on the adsorption while it is strongly influenced by the presence of acidic carbon oxygen surface groups. The amount of these surface groups was enhanced by oxidation of the carbons with different oxidizing agents and reduced by eliminating these groups on degassing at different temperatures. The adsorption of Pb(II) ions increases on each oxidation and decreases on degassing the oxidized carbons. The increase in adsorption on oxidation has been attributed to the formation of acidic carbon-oxygen surface groups and the decrease to the elimination of these acidic surface groups on degassing. The adsorption is also influenced by the pH of the aqueous solution. The adsorption is only small at pH values lower than 3 but is considerably larger at higher pH values. Suitable mechanisms consistent with the adsorption data have been suggested.

• Carbon letters
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• v.7 no.1
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• pp.1-8
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• 2006

The activated carbon "C" was obtained by carbonization followed by activation with steam at 40% of burn-off. Oxidized carbons C-N, C-P and C-H were obtained by oxidizing the activated carbon C with concentrated nitric acid, ammonium peroxysulfate and hydrogen peroxide, respectively. The textural properties of the carbons were determined from nitrogen adsorption at 77 K. The acidic surface functional groups were determined by pH titration, base neutralization capacity and electrophoretic mobility measurements. The cation exchange capacities of un-oxidized and oxidized carbons were determined by the removal of Cu(II) and Ni(II) from their aqueous solutions. The surface area and the total pore volume decreased but the pore radius increased by the treatment of activated carbon with oxidizing agents. These changes were more pronounced in case of oxidation with $HNO_3$. The surface pH of un-oxidized carbon was basic whereas those of the oxidized derivative were acidic. The removal of Cu(II) and Ni(II) was pH dependent and the maximum removal of the both ions was obtained at pH of 5-6. Cu(II) was more adsorbed, a phenomenon which was ascribed to its particular electronic configuration.

• Journal of the Korean Geographical Society
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• v.38 no.2
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• pp.156-172
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• 2003

In this paper we identify that there are High Higher surfaces(HH-surface) around Jeongdongjin and Daejin area where Higher surfaces(H-surface) of marine terrace are formed on a large scale. On the basis of an altitude of the ancient shoreline of the marine terraces, geomorphic surfaces can be classified into HH I (140m a.s.l), HH II (110m a.s.l), H I (90m a.s.l), H II (70m a.s.l), M (40m a.s.l), L I (25m a.s.l) and L II (10m a.s.l). Besides, we identify that the lowest surfaces(5~6m a.s.l) are found extensively in the research area which are assumed to be formed in the Holocene. Considering that the formation mechanism of the marine terraces in the research area is similar to that of the marine terraces at both Campo area in the south east coastal region of Korea md the thalassostatic terraces of Osip River in Samchuk in a short distance from the research area, we can assume that the HH-surfaces in both areas were formed in the same period. Based on the fact that L I- surface was formed on the Last Interglacial Stage of MIS 5, we can infer that M- was formed in MIS 7, H I- in MIS 9, H II- in MIS 11, HH I- in MIS 13 and HH II- in MIS 15. The reason for that H-surfaces, similar to those at Gampo area, to remain on a large scale is that the Holsteinian Interglacial continued for a long period of time and at that time there was a large wave-cut platform in the vicinity of the shoreline.

• Journal of the Korean Chemical Society
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• v.44 no.4
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• pp.305-310
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• 2000

Adsorpdon behaviors ofNi(II), Co(II), Sr(II), and(I) ions were nvestigated on amorphous alumina with varying pH at three different etalion concentrations under the condition of 0.I M ionlc strength.With increasingmctalion concentration, the percentage of adsorption decreased and the adsorption edge was shifted to a higher pH value. The adsorption data obtained usingthe metal ion concentration of $1.0{\times}10^{-4}$M were quantitatively analyzed by surfacecomplexation modelingof Ni(II) and Co(II) ions adsorbed at high pH (>8)were found to be in hydrolyzed forms.

• The Journal of Korean Academy of Prosthodontics
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• v.43 no.3
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• pp.363-378
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• 2005

Statement of problem. Hydroxyapatite(HA) coated titanium surfaces have not yet showed the reliable osseointegration in various conditions. Purpose. This study was aimed to investigate microstructures, chemical composition, and surface roughness of the surface coated by the hydrothermal method and to evaluate the effect of hydrothermal coating on the cell attachment, as well as cell proliferation. Material and Methods. Commercially pure(c.p.) titanium discs were used as substrates. The HA coating on c.p. titanium discs by hydrothermal method was performed in 0.12M HCl solution mixed with HA(group I) and 0.1M NaOH solution mixed with HA(group II). GroupⅠ was heated at 180 $^{\circ}C$ for 24, 48, and 72 hours. GroupⅡ was heated at 180 $^{\circ}C$ for 12, 24, and 36 hours. And the treated surfaces were evaluated by Scanning electron microscopy(SEM), Energy dispersive X-ray spectroscopy(EDS), X-ray photoelectron spectroscopy(XPS), X-ray diffraction method(XRD), Confocal laser scanning microscopy(CLSM). And SEM of fibroblast and 3-(4,5- dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide(MTT) assay were used for cellular responses of the treated surfaces. Results. The color of surface changed in both groups after the hydrothermal process. SEM images showed that coating pattern was homogeneous in group II, while inhomogeneous in group I. H72 had rosette-like precipitates. The crystalline structure grew gradually in group II, according to extending treatment period. The long needle-like crystals were prominent in N36. Calcium(Ca) and phosphorus(P) were not detected in H24 and H48 in EDS. In all specimens of group II and H72, Ca was found. Ca and P were identified in all treated groups through the analysis of XPS, but they were amorphous. Surface roughness did not increase in both groups after hydrothermal treatment. The values of surface roughness were not significantly different between groups I and II. According to the SEM images of fibroblasts, cell attachments were oriented and spread well in both treated groups, while they were not in the control group. However, no substantial amount of difference was found between groups I and II. Conclusions. In this study during the hydrothermal process procedure, coating characteristics, including the HA precipitates, crystal growth, and crystalline phases, were more satisfactory in NaOH treated group than in HCl treated group. Still, the biological responses of the modified surface by this method were not fully understood for the two tested groups did not differ significantly. Therefore, more continuous research on the relationship between the surface features and cellular responses seems to be in need.

• Journal of Environmental Science International
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• v.12 no.7
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• pp.817-824
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• 2003

Various kinds of zeolites, such as analcime (ANA), cancrinite (CAN), Na-Pl and sodalite octahydrate (SOD) could be synthesized from Hwangto by hydrothermal reaction in a high-pressure vessel. The adsorption characteristics of Cu(II) and Cd(II) by Hwangto and its synthetic zeolites were investigated using the chemical and electrochemical surface parameters of these adsorbents. The heavy metal adsorptivity among the adsorbents decreased in the following sequences: Na-Pl > SOD > ANA > CAN > Hwangto. This sequence was the same with the values of surface site density (Ns) of these adsorbents and was correlated inversely with the values of pHpzc (pH of the point of zero charge) and the va]ues of K$\_$a2/(int) (intrinsic surface deprotonation constant) of the adsorbents for synthetic zeolites, i.e., the adsorbents with higher values of Ns and with lower values of pHpzc and K$\_$a2/(int) for synthetic zeolites showed higher heavy metal adsorptivity. With increasing pH, the heavy metal adsorptivity increased greatly between pHpzc and pH 6 or 7 because of the steep increase of negatively charged sites for synthetic zeolites, but for Hwangto, it increased broadly because of slow increase of negatively charged sites based on its lower surface sites.

• Transactions of the Korean Society of Mechanical Engineers
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• v.12 no.4
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• pp.781-789
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• 1988

The fatigue crack growth and crack closure behavior of long through-thickness cracks and small half-penny shaped surface cracks were investigated in 5083-H113 Aluminum alloy under constant amplitude testing by the unloading elastic compliance method. It was found that, in the Region II, the crack growth behavior of both through-thickness and surface cracks exhibited the tri-linear form with two transitions and no concern with stress ratio R. In the Region I $I_{ab}$ and I $I_{b}$, through-thickness cracks grew faster than surface cracks in length direction, but at .DELTA. K .leq.4 MPa.root.m for R=0.1 the growth rates of surface cracks in depth direction, grew faster than those of through-thickness cracks. When the crack closure was considered, the growth rates of through-thickness cracks lay between the growth rates of depth direction and the growth rates of length direction in surface cracks. It is suspected that this was caused by the difference of crack closure at depth and length direction of surface cracks.s.

• The Korean Journal of Quaternary Research
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• v.17 no.2
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• pp.169-170
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• 2003

The existence of coastal terraces, HH(High higher) surfaces found at Gampo of southeast coast and at Jeongdongjin of the central east coast were confirmed at Jigyeong-Ri, the areal border between Gyeongju- and Ulsan city on the southeast coast of Korea Peninsula. Especially this study reports HH JK-surface located on the 155m a.s.l., which is the highest altitude among the ancient shorelines of the coastal terraces in Korea. The HH surfaces on the study area are classified into HH JK at 155m, HH-I at 140m and HH-II at 115m, and each formation stage is related to MIS 17(720∼690ka BP), MIS 15(630∼560ka BP) and MIS 13(510∼480ka BP) respectively. The HH-surfaces remain to be larger than those of H- and L-surfaces. The reason is caused by the unique factors of the coastal geology and morphology on the study area during the formation stage. And also the areal difference by the magnitude of upheaval doesn't exist from north to south because the altitude system of ancient shoreline on each coastal terrace is same along the east coast. The upheaval rate of the eastern coastal areas was measured in the relation to the ancient shoreline and formation stage among the coastal terraces such as HH JK-, HH-I, HH-II, H-III and H-IY surface, and was almost same as 0.23mm/y.

• Journal of the Korean Geographical Society
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• v.38 no.4
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• pp.490-504
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• 2003

The existence of coastal terraces, HH(High higher) surfaces found at Gampo of southeast coast and at Jeongdongjin of the central east coast were confirmed at Jjgyeong-Ri, the areal border between Gyeongjuand Ulsan city on the southeast coast of Korea Peninsula. Especially this study reports HH JK-surface located on the 155m a.s.l, which is the highest altitude among the ancient shorelines of the coastal terraces in Korea. The HH surfaces on the study area are classified into HH JK at 155m, HH I at 140m and HH II at 115m, and each formation stage is related to MIS 17(720∼690ka BP), MIS 15(630∼560ka BP) and MIS 13(510∼480ka BP) respectively. The HH-surfaces remain to be larger than those of H- and L-surfaces. The reason is caused by the unique factors of the coastal geology and morphology on the study area during the formation stage. And also the areal difference by the magnitude of upheaval doesn't exist from north to south because the altitude system of ancient shoreline on each coastal terrace is same along the east coast. The upheaval rate of the eastern coastal areas was measured in the relation to the ancient shoreline and formation stage among the coastal terraces such as HH JK-, HH I-, HH II, H I- and H II surface, and was almost same as 0.23mm/y.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.2
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• pp.452-457
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• 1993

For the calculation of transonic laminar relative flow fields on the axisymmetric H-S and B-B stream surfaces in turbomachinery, a finite volume method developed in Part (I) is extended. Energy equation is replaced for simplicity by the condition of constant rothalpy throughout the flow fields. For axisymmetric H-S flow the circumferential componets of absolute velocity are given in advance so that this component of momentum equations can be neglected. Some numerical results show good agreement with experimental data.