• Title/Summary/Keyword: Growth temperature reduction

Search Result 402, Processing Time 0.023 seconds

Freeze Drying Process and Pore Structure Characteristics of Porous Cu with Various Sublimable Vehicles (다양한 동결제를 이용하여 동결건조 공정으로 제조한 Cu 다공체의 기공구조 특성)

  • Lee, Gyuhwi;Oh, Sung-Tag;Suk, Myung-Jin;Jeong, Young-Keun
    • Journal of Powder Materials
    • /
    • v.27 no.3
    • /
    • pp.198-202
    • /
    • 2020
  • The effect of sublimable vehicles on the pore structure of Cu fabricated by freeze drying is investigated. The 5 vol% CuO-dispersed slurries with camphene and various camphor-naphthalene compositions are frozen in a Teflon mold at -25℃, followed by sublimation at room temperature. After hydrogen reduction at 300℃ and sintering at 600 ℃, the green bodies of CuO are completely converted to Cu with various pore structures. The sintered samples prepared using CuO/camphene slurries show large pores that are aligned parallel to the sublimable vehicle growth direction. In addition, a dense microstructure is observed in the bottom section of the specimen where the solidification heat was released, owing to the difference in the solidification behavior of the camphene crystals. The porous Cu shows different pore structures, such as dendritic, rod-like, and plate shaped, depending on the composition of the camphornaphthalene system. The change in pore structure is explained by the crystal growth behavior of primary camphor and eutectic and primary naphthalene.

Excitonic transitions and dynamics in front and back surfaces of ZnO films grown by plasma-assisted molecular beam epitaxy

  • Lee, Seon-Gyun;Go, Hang-Ju;Yao, Takafumi;Jo, Yong-Hun
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.02a
    • /
    • pp.119-119
    • /
    • 2010
  • We report strong exciton transition and exciton-phonon couplings in photoluminescence (PL) of ZnO thin films grown on MgO/sapphire (buffer/substrate) by plasma-assisted molecular beam epitaxy. The PL spectra at 10 K showed the intensity of the dominant emission, donor-bound exciton transition of front surface (top surface, the latter part in growth) is found to be about 100 times higher than that of back surface (in-depth bottom area, the initial part), while the room temperature PL spectra showed dominant contributions from the free exciton emissions and phonon-replicas of free excitons for front surface and back surface, respectively, It could be attributed to the strong contributions of exciton-phonon coupling. Time resolved PL spectra reveal that the life time of exciton recombination from the front surface are longer than those from back surface. This is most probably due to the fact that reduction of non-radiative recombination in the front surface. This investigation indicates that the existence of native defects or trap centers which can be reduced by the proper initial condition in growth and the exciton-phonon interaction couplings play an important role in optical properties and crystal quality of ZnO thin films.

  • PDF

Preparation of $WO_3/TiO_2$ and $V_2O_5/TiO_2$ powders and their catalytic performances in the SCR of $NO_x$ ($WO_3/TiO_2$$V_2O_5/TiO_2$ 분말의 합성 및 $NO_x$ 제거 SCR특성)

  • Lee, Tae-Suk;Lee, In-Gyu;Lee, Byeong-Woo;Shin, Dong-Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.16 no.5
    • /
    • pp.216-221
    • /
    • 2006
  • An investigation of the influence of $WO_3$ and $V_2O_5$ catalysts on the microstructure, phase formation and selective catalytic reduction (SCR) efficiency of the synthesized SCR powders has been carried out. A commercial anatase-$TiO_2$ was used as the catalysts support. For $WO_3(10wt%)/TiO_2$, the W loading to the $TiO_2$ support led to the lower in anatase to rutile transition temperature from $1200^{\circ}C$ of $TiO_2$ support to ${\sim}900^{\circ}C$. The transition temperature was also lowered to below $650^{\circ}C$ in the $V_2O_5$(5 and 10 wt%) added composition. The $WO_3(10wt%)/TiO_2$ SCR powder obtained at $450^{\circ}C$ showed near 100% of $NO_x$ conversion efficiency at $350{\sim}400^{\circ}C$ and for the powder prepared at $650^{\circ}C$ the same efficiency was achieved in wider temperature range $300{\sim}400^{\circ}C$. The highest $NO_x$ conversion efficiency of 100% was obtained in the $V_2O_5(5wt%)/TiO_2$ SCR composition calcined at $650^{\circ}C$ in the relatively wider temperature range $250{\sim}350^{\circ}C$, while the catalytic efficiency considerably decreased for the $V_2O_5(10wt%)/TiO_2$. The lowered conversion efficiency of $NO_x$ observed in the $V_2O_5(10wt%)/TiO_2$ composition calcined at $650^{\circ}C$ was considered to be correlated with the lowered surface area resulting from the increased crystallite growth by highly reactive vanadium loading.

Changes in Anthesis, Grain Filling and Grain Yield Accompanied by Hastening of Heading in Winter Wheat and Barley (추파 대.소맥의 조기출수에 따른 개화, 등숙 및 수량성 변화)

  • Kim, Seok-Dong;Kwon, Yong-Woong
    • KOREAN JOURNAL OF CROP SCIENCE
    • /
    • v.30 no.1
    • /
    • pp.39-46
    • /
    • 1985
  • Heading time was hastened by the combination of seeding time and longday treatment in order to elucidate the effect of early heading on earliness in maturity, vegetative growth and grain yield in five barley varieties and four wheat varieties under field conditions in Suwon, Korea, 1978-79. About 15 days of earliness in heading accelerated only 2 to 6 days in maturity. Furthermore, the duration of grain fill was not much prolonged comparing with the extension of days from heading to maturity, because of the extension of periods from heading to anthesis at lower temperature resulting in somewhat greater final grain weight. Periods from heading to anthesis and from anthesis to maturity were negatively correlated with the air temperature. In early heading, leaf area at 10 days after anthesis and net assimilation rate were much limited, and although leaf area duration got larger, presumably, it could not make up for the reduction of grain yield. Grain yield per plant reduced noticeably in early heading. This was mainly caused by the reduction of spike number and grain number per spike.

  • PDF

The Effects of Carbon Dioxide as Additives on Soot Formatio in Jet Diffusion Flames (제트확산화염에서 이산화탄소의 첨가가 매연생성에 미치는 영향)

  • Ji, Jung-Hoon;Lee, Eui-Ju
    • Fire Science and Engineering
    • /
    • v.24 no.6
    • /
    • pp.170-175
    • /
    • 2010
  • The effect of carbon dioxide addition on soot formation was investigated in jet diffusion flames in coflow. Flame temperature were measured with R-type thermocouple and the boundary temperature between blue and yellow flame was confirmed. Light-extinction method was introduced for the relative soot density (1-I/$I_0$) in the in-flame region. He-Ne laser with wave length at 632.8 nm was used for the light source, and the signal attenuated by absorption and scattering was detected directly. Oxidizer velocity effect on soot formation was studied to know that the thermal influence for soot formation. The results showed that the temperature of both blue and yellow flame were decreased according to the dilution of carbon dioxide but boundary temperature was nearly constant. The relative soot density was lower when carbon dioxide was added in oxidizer stream and oxidizer velocity increased. These were caused by the reduction of flame temperature and shorter residence time for soot growth. Also carbon dioxide addition enhanced the instability of jet flames like flickering, so the flame length was a little longer than pure ethylene/air flame.

Planning for Adapting to the Rural Region Impacts of Climate Change - Case study in Yesan - (기후변화에 따른 농촌지역 영향 및 대응방안 연구 - 예산군을 대상으로 -)

  • Lee, Gyeong-Jin;Cha, Jung-Woo
    • Journal of Korean Society of Rural Planning
    • /
    • v.19 no.4
    • /
    • pp.115-123
    • /
    • 2013
  • Owing to increase of meteorological disasters by climate change, it needs to study of climate change which will be able to deal with adaption for basic local authorities. A case study area of Yesan have been impacted by land-use which alter natural environment demage. It has led to micro-climate change impacts in rural area, Yesan. In order to adapt to the effects, this paper estimated temperature change in productivity of fruits and conducted decline of nonpoint pollutant loadings. As the results of temperature change of effecting on growth of apple, since a rise in temperature have not increased high, therefore the apple productivity could not be influence until 2030s. While the apple productivity could be declined 14.8% in 2060s. In addition, it supposes that the productivity would be decreased 44.5% in 2090s. Furthermore, it showed that the apple maturity has become worse, because length of high temperature has dramatic increased 54.2% in 2030s, 103.2% in 2060s and 154.0% in 2060s beside 2000, respectively, compared with 2000. As results of analysing between the future rainfall characteristics and nonpoint pollutant loadings, the subject of reduction of nonpoint pollutant was efficiency when it implemented around Oga-myeon or Deoksan-myeon Dun-ri. This study classified the region more detail each Eup and Myeon after that it analysed the rural region impacts of climate change for basic local authorities. Hence, this study is able to predict adaptation of rural region impacts of climate change. Due to increase of green house gases emission, meteorological disasters could often occur in the future. Therefore, it needs follow-up studies that assess climate change of effecting on rural region.

INVESTIGATION ON THE CORROSION BEHAVIOR OF HAHA-4 CLADDING BY OXIDE CHARACTERIZATION

  • Park, Jeong-Yong;Choi, Byung-Kwon;Jeong, Yong-Hwan
    • Nuclear Engineering and Technology
    • /
    • v.41 no.2
    • /
    • pp.149-154
    • /
    • 2009
  • The microstructure, the corrosion behavior and the oxide properties were examined for Zr-1.5Nb-0.4Sn-0.2Fe-0.1Cr (HANA-4) alloys which were subjected to two different final annealing temperatures: $470^{\circ}C$ and $570^{\circ}C$. HANA-4 was shown to have $\ss$-enriched phase with a bcc crystal structure and Zr(Nb,Fe,Cr)$_2$ with a hcp crystal structure with $\ss$-enriched phase being more frequently observed compared with Zr(Nb,Fe,Cr)$_2$. The corrosion rate of HANA-4 was increased with an increase of the final annealing temperature in the PWR-simulating loop, $360^{\circ}C$ pure water and $400^{\circ}C$ steam conditions, which was correlated well with a reduction in the size of the columnar grains in the oxide/metal interface region. The oxide growth rate of HANA-4 was considerably affected by the alloy microstructure determined by the final annealing temperature.

Production of Exo-Polymers by Submerged Mycelial Culture of Cordyceps militaris and Its Hypolipidemic Effect

  • Yang, Byung-Keun;Ha, Ji-Young;Jeong, Sang-Chul;Das, Surajit;Yun, Jong-Won;Lee, Young-Se;Choi, Jang-Won;Song, Chi-Hyun
    • Journal of Microbiology and Biotechnology
    • /
    • v.10 no.6
    • /
    • pp.784-788
    • /
    • 2000
  • Hypolipidemic effect of exo-polymers(EPs) form submerged mycelial culture of Cordyceps militaris was investigated in male Sprague-Dawley rats. For a dose-dependent study, EPs were administered at the level of 50-100 mg/kg body weight (BW) and the data was compared with the saline administered control group. A significant reduction of both the plasma total cholesterol (TC) and triglyceride (TG) was registered under the influence of EPs. It reduced the lowe density lipoprotein (LDL) cholesterol level as much as 40.5%. Levels of high density lipoprotein (HDL) choloesterol did not vary significantly within the different experimental groups, but the HDL: TC ratio showed consistently a high value with the increasing dose. The effects of cultural conditions (pH and temperature) in mycelial growth and EPs production were studied. Both the biomass and EPs were produced in a wide range of pH and temperature.

  • PDF

Carbon nanotube/silicon hybrid heterojunctions for photovoltaic devices

  • Castrucci, Paola
    • Advances in nano research
    • /
    • v.2 no.1
    • /
    • pp.23-56
    • /
    • 2014
  • The significant growth of the Si photovoltaic industry has been so far limited due to the high cost of the Si photovoltaic system. In this regard, the most expensive factors are the intrinsic cost of silicon material and the Si solar cell fabrication processes. Conventional Si solar cells have p-n junctions inside for an efficient extraction of light-generated charge carriers. However, the p-n junction is normally formed through very expensive processes requiring very high temperature (${\sim}1000^{\circ}C$). Therefore, several systems are currently under study to form heterojunctions at low temperatures. Among them, carbon nanotube (CNT)/Si hybrid solar cells are very promising, with power conversion efficiency up to 15%. In these cells, the p-type Si layer is replaced by a semitransparent CNT film deposited at room temperature on the n-doped Si wafer, thus giving rise to an overall reduction of the total Si thickness and to the fabrication of a device with cheaper methods at low temperatures. In particular, the CNT film coating the Si wafer acts as a conductive electrode for charge carrier collection and establishes a built-in voltage for separating photocarriers. Moreover, due to the CNT film optical semitransparency, most of the incoming light is absorbed in Si; thus the efficiency of the CNT/Si device is in principle comparable to that of a conventional Si one. In this paper an overview of several factors at the basis of this device operation and of the suggested improvements to its architecture is given. In addition, still open physical/technological issues are also addressed.

Treatment of Food Processing Wastewater bearing Furfural by Candida utilis (Candida utilis를 이용한 furfural 함유 식품가공 폐수의 처리)

  • 박기영;정진영
    • KSBB Journal
    • /
    • v.18 no.4
    • /
    • pp.272-276
    • /
    • 2003
  • A yeast treatment process was applied to treat food processing organic wastewater containing inhibitory material to anaerobic bacteria. The wastewater contained high concentration of the furfural as a by-product from the food processing. Aerobic yeast (Candida utilis) was selected to remove organics in wastewater. The batch test showed that the wastewater had an inhibition to anaerobic bacteria. The optimum level of temperature for yeast treatment was ranged from 25 to 45$^{\circ}C$. The pH range from 4 to 8 was favorable to yeast growth. The continuous flow reactor was operated at various SRTs. The results were satisfactory with the reduction of COD up to 90% at SRT of more than 1 day. Through the kinetic study of the yeast, the remained COD concentration was mainly caused by the formation of soluble microbial product (SMP).