• Title/Summary/Keyword: Growth kinetic

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Composite copper powder from Kelex 100 (Kelex100로부터 구리입자 분말 합성)

  • ;P.R Taylor
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.131-137
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    • 1998
  • A composite copper coated powder was generated by pressure hydrogen stripping copper from Kelex 100 solvent extractant in the presence of silica powder. Within the limitation of solvent extraction under constant conditions, both loading level and stripping rate were reproducible. The stripping copper kinetics are reduced from a divalent state to a metallic state and then deposited on the surface of the silica powder. Copper nucleates heterogeneously on the seed particles. They are giving an agglomerated and non - uniform powder.

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Effect of Culture Conditions on Cathepsin B Inhibitor Production by a Marine Bacterium, Pseudomonas sp. Strain PB01

  • Hoang, Le Thu Van;Kim, Moon-Moo;Kim, Se-Kwon
    • Journal of Microbiology and Biotechnology
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    • v.18 no.6
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    • pp.1115-1120
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    • 2008
  • A novel cathepsin B inhibitor-producing bacterium was isolated from marine sediments and identified based on its 16S rDNA sequence as Pseudomonas sp. strain PB01 (Accession No. EU126129). The growth and enzyme inhibitor production were investigated under various culture conditions. A mixture of organic nitrogen source was required for the optimal production, whereas both glucose and maltose proved to be the effective carbon sources for cathepsin B inhibitor production. Other optimal culture conditions included temperature range between 25 and $28^{\circ}C$, initial medium pH of 6.6, and shaking speed of 200 rpm. Under these optimal conditions, the maximum inhibitory activity from culture broth was approximately 50% after 30 h of cultivation. Additionally, kinetic study revealed that inhibitor production paralleled with cell growth, which suggested that the inhibitor may be a primary metabolite of that bacterium.

Estimation of Microstructures and Material Properties of HAZ in SA508 Reactor Pressure Vessel (원자로 압력용기 용접열영향부의 미세조직 및 재료물성 예측)

  • Lee, S.G.;Kim, J.S.;Jin, T.E.
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.138-143
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    • 2001
  • To perform the rigorous integrity evaluation of RPV, it is necessary to consider metallurgical factors such as microstructure evolution during multi-pass welding process and PWHT. The microstructures of the heat affected zone(HAZ) of SA508 steel were predicted by a combination of simulated thermal analysis and a simple kinetic models for austenite grain growth and austenite-ferrite transformation. Phase equilibrium of SA508 steel were calculated using a Thermo-Calc package. Carbide growth in th HAZ were predicted by a empirical model, taking into account the predicted microstructure evolution.

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Product Phase Control During Interdiffusion Reactions (상호 확산 반응 중의 생성상 제어)

  • Park, Joon-Sik;Kim, Ji-Hoon;Perepezko, John R.
    • Journal of Korea Foundry Society
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    • v.26 no.1
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    • pp.27-33
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    • 2006
  • Phase evolutions involving nucleation stages together with diffusional growth have been examined in order to provide a guideline for determining rate limiting stages during phase evolutions. In multiphase materials systems in coatings, composites or multilayered structures, diffusion treatments often result in the development of metastable/intermediate phases at the reaction interfaces. The development of metastable phases during solid state interdiffusion demonstrates that the nucleation reaction can be one controlling factor. Also, the concentration gradient and the relative magnitudes of the component diffusivities provide a basis for a phase selection and the application of a kinetic bias strategy in the phase selection. For multicomponent alloy systems, the identification of the operative diffusion pathway is central to control phase formation. Experimental access to the nucleation and growth stage is discussed in thin film multi layers and bulk samples.

Application of thermodynamics to chemical vapor deposition

  • Latifa Gueroudji;Hwang, Nong-Moon
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.09a
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    • pp.1-20
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    • 1998
  • Processing of thin films by chemical vapor deposition (CVD) is accompanied by chemical reactions, in which the rigorous kinetic analysis is difficult to achieve. In these conditions, thermodynamic calculation leads to better understanding of the CVD process and helps to optimise the experimental parameters to obtain a desired product. A CVD phase diagram has been used as guide lines for the process. By determining the effect of each process variable on the driving force for deposition, the thermodynamic limit for the substrate temperature that diamond can deposit is calculated in the C-H system by assuming that the limit is defined by the CVD diamond phase diagram. The addition of iso-supersaturation ratio lines to the CVD phase diagram in the Si-Cl-H system provides additional information about the effects of CVD process variables.

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Specific Inhibition of Polar Auxin Transport by n-Octanol in Maize Coleoptiles (옥수수(Zea mays L.) 자엽초 조직 절편에서 n-Octanol에 의한 옥신 극성 이동 억제)

  • 윤인선
    • Journal of Plant Biology
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    • v.36 no.1
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    • pp.67-74
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    • 1993
  • Both polar and gravity-induced lateral transport of auxin was markedly reduced in corn coleoptile segments by octanol treatment. Octanol enhance net auxin uptake without affecting that of benzoic acid, suggesting that the effect did not result from a nonspecific action on general membrane permeability. Since naphthylphthalamic acid (NPA) action on both transport and net uptake of auxin was substantially decreased in the presence of octanol, a specific interaction of octanol with the NPA site (efflux carrier) can be postulated. Studies on in vitro binding of NPA to membrane vesicles indicated that octanol did not interfere with NPA binding. When basipetal transport of auxin was impared by plasmolysis, octanol still inhibited auxin transport in the plasmolyzed tissues. The results ruled out the possibility of octanol acting at the plasmodesmata. Kinetic analysis of growth indicated that IAA-sustained growth was rapidly blocked by octanol implicating a common system by which auxin transport is linked to auxin action. Possible mechanisms for octanol action will be discussed.

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Optimization of Semi-Batch Process for Ethanol Production (에타놀 생산을 위한 Semi-batch 발효 공정의 최적화)

  • Lee, Jae-Heung
    • Microbiology and Biotechnology Letters
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    • v.11 no.1
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    • pp.33-38
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    • 1983
  • As flocculent strains are likely to have considerable potential for internal cell recycle, kinetic studies on glucose medium with flocculent Saccharomyces uvarum were carried out in batch and continuous culture. Using a mathematical model, the kinetic parameters at each temperature and pH were estimated in order to establish optimal conditions. It was found that an overall optimum temperature for growth and ethanol production in the range 33-35$^{\circ}C$ was desirable. With regard to the effect of pH, ethanol production by S. uvarum was found to be relatively insensitive to pH value between 4 and 6, with an optimum pH of around 5. At these optimal conditions a maximum ethanol productivity of 12 g/$\ell$/h was determined using semi-batch process together with 5. uvarum.

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Numerical Model for SBR Aerobic Digestion Combined with Ultrasonication and Parameter Calibration (초음파 결합형 SBR 호기성 소화의 모델과 매개변수의 보정)

  • Kim, Sunghong;Lee, Inho;Yun, Jeongwon;Lee, Dongwoo
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.4
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    • pp.457-468
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    • 2013
  • Based on the activated sludge model(ASM), a mathematical model which represents the aerobic sludge digestion by sequencing batch reactor(SBR) combined with ultrasonic treatment was composed and performed in this study. Aerobic digestion using sequencing batch reactor(SBR) equipped with ultrasound treatment was also experimented for the purpose of parameter calibration. Most of the presented kinetic parameters in ASM or ASM2 could be used for the aerobic digestion of sludge but the parameters related in hydrolysis and decay rate needed modification. Hydrolysis rate constant of organic matter in aerobic condition was estimated at $0.3day^{-1}$ and the maximum growth rate for autotrophs in aerobic condition was $0.618day^{-1}$. Solubilization reactions of particulate organics and nitrogen by ultrasonication was added in this kinetic model. The solubilization rate is considered to be proportional to the specific energy which is defined by specific ultrasound power and sonication time. The solubilization rate constant by ultrasonication was estimated at $0.202(W/L)^{-1}day^{-1}$ in this study. Autotrophs as well as heterotrophs also decomposed by ultrasonic treatment and the nitrification reaction was limited by the lack of autotrophs accumulation in the digester.

Inhibitory Effect of Sorbus cortex Extract on (1,3)-$\beta$-Glucan Synthase (정공피 추출물의 (1,3)$\beta$-Glucan Synthase에 대한 억제효과)

  • You, Myung-Ja;Kim, Bo-Mi;Lee, Jeong-Ho;Lee, Young-Hang;Chai, Kyu-Yun;Baek, Seung-Hwa
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.22 no.5
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    • pp.1196-1201
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    • 2008
  • A examination of the kinetic properties of UDP-glucose : (1,3)-$\beta$-glucan (callose) synthase from mung bean seedings (Sorbus cortex) shows that these enzymes have a complex interaction with UDP-glucose and various effectors. Deoxynojirimycin increased the inhibitory effect of (1,3)-$\beta$-glucan synthase at the concentration-dependent manner by fluorescence assay. The inhibitory effect of Fr. 2-16 (97.15%) showed higher than that of deoxynojirimycin (80.63%). Fr. 2-3 inhibited the growth of the Candida albicans at 1 mm inhibition zone by disk diffusion method. These results suggest that Sorbus cortex extract can be used as a stable antifungal material.

Assessment of kinetics behavior of electrocoagulation process for the removal of suspended solids and metals from synthetic water

  • Singh, Hariraj;Mishra, Brijesh Kumar
    • Environmental Engineering Research
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    • v.22 no.2
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    • pp.141-148
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    • 2017
  • Globalization, industrialization, mining, and uncontrolled population growth have fostered a shortage of potable water. Therefore, it has become imperative to understand an effective and reasonable water purification technique. A renewed interest in electrocoagulation (EC) has been spurred by the search for reliable, cost-effective, water-treatment processes. This paper has elucidated a technical approach for getting rid of heavy metals and total suspended solids (TSS) from synthetic water using an aluminum electrode. The effect of operational parameters, such as current density, inter-electrode distance, operating time, and pH, were studied and evaluated for maximum efficiency. This study corroborates the correlation between current density and removal efficiency. Neutral pH and a low electrode gap have been found to aid the efficacy of the EC setup. The outcome indicates that a maximum TSS removal efficiency of 76.6% occurred at a current density of $5.3mA/cm^2$ during a contact time of 30 min. In the case of heavy metals remediation, 40 min of process time exhibited extremely reduced rates of 99%, 59.2%, and 82.1%, for Cu, Cr, and Zn, respectively. Moreover, kinetic study has also demonstrated that pollutants removal follows first-and second-order model with current density and EC time being dependent.