• 제목/요약/키워드: Group separation

검색결과 613건 처리시간 0.033초

폐기물의 분리 수거 및 재활용에 대한 의식조사 (Cititude to the source separation and recycling of domesticwaste.)

  • 정재춘;이무춘
    • 한국환경교육학회지:환경교육
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    • 제5권1호
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    • pp.62-70
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    • 1993
  • The study was performed to investigate the present situation of sourceseparation, recycling of domestic waste and citizen's attitude to them. The selected study area were Dobonggu in Seoul, Siheung city, Kimpogun. The result showed that most of the citizen in the selected area is performing source separation effort by group activity basis. However, there is no strong economic incentives for continuous source separation effect since the price of the recyclables is relatively low. For the recycled products, most people appears to think that the diversification of the product should be necessary for a bitter market competativeness. For the disporsable product, most citizen feels that free that supply in the public facilities should be prohibited.

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Adsorption and separation behaviors of Y(III) and Sr(II) in acid solution by a porous silica based adsorbent

  • Wu, Hao;Kawamura, Taiga;Kim, Seong-Yun
    • Nuclear Engineering and Technology
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    • 제53권10호
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    • pp.3352-3358
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    • 2021
  • Aiming at selective adsorption and separation of Y(III) from the Y(III)-Sr(II) group in acid solution, a silica-based TODGA impregnated adsorbent [(TODGA+1-dodecanol)/SiO2-P-F600] has been prepared. Batch adsorption experiments were conducted under the effect of contact time, acid concentration, solution temperature, and adsorption capacity etc. Chromatography recovery of more than 90% Y(III) was successfully achieved under elution with 0.01 M DTPA solution in nitric acid adsorption system, and 0.1 M HCl solution in hydrochloride adsorption system, respectively.

가교된 PVA 막을 이용한 MTBE/methanol 혼합물의 증기투과(Vapor Permeation)분리 (Vapor Permeation Separation of MTBE-Methanol Mixtures Using Cross-linked PVA Membranes)

  • 김연국;임지원
    • 멤브레인
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    • 제10권3호
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    • pp.148-154
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    • 2000
  • 본 연구에서는 sulfur-succinic acid의 가교제를 이용한 가교된 폴리비닐알코올(poly(vinyl alcohol), PVA) 가교막을 이용하여 MTBE-methanol 혼합액에 대하여 조업온도, 가교제의 조성에 따른 증기투과 공정의 투과 특성을 조사 하였다. 팽윤 실험을 통해 PVA/SSA 가교막에 대하여 가교제 조성에 따른 막의 구조와 PVA의 하이드록실기(-OH), SSA의 설폰기(-$SO_3$H)와 용매와의 수소결합의 두 가지 인자가 상호 보완적으로 작용하고 있음을 알 수 있었다. 투과 특성에 있어 SSA의 설폰기가 중요한 인자로 작용하였다. 예를 들면 7% SSA 막에 대해서는 수소결합의 효과보다는 가교도의 효과가 투과 특성에 중요한 요인으로 작용하며 5% SSA에 대해서는 수소결합의 효과가 중요하게 작용하였다. 증기투과 공정에 있어 막과 직접 접촉하는 증기상이 액상에 비하여 methanol의 농도가 낮아 PVA의 하이드록실기와 methanol과의 수소결합 확률이 감소함에 따라 투과 특성에 영향을 미친다. 결과적으로 7% SSA 막에 대하여 MTBE/mthanol=80/20 혼합액에 대하여 공급액의 온도 3$0^{\circ}C$에서 선택도 2187, 투과도 4.84g/$m^2$hr를 보여 주었다.

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Adsorption behavior of platinum-group metals and Co-existing metal ions from simulated high-level liquid waste using HONTA and Crea impregnated adsorbent

  • Naoki Osawa;Seong-Yun Kim;Masahiko Kubota;Hao Wu;Sou Watanabe;Tatsuya Ito;Ryuji Nagaishi
    • Nuclear Engineering and Technology
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    • 제56권3호
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    • pp.812-818
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    • 2024
  • The volume and toxicity of radioactive waste can be decreased by separating the components of high-level liquid waste according to their properties. An impregnated silica-based adsorbent was prepared in this study by combining N,N,N',N',N",N"-hexa-n-octylnitrilotriacetamide (HONTA) extractant, N',N'-di-n-hexyl-thiodiglycolamide (Crea) extractant, and macroporous silica polymer composite particles (SiO2-P). The performance of platinum-group metals adsorption and separation on prepared (HONTA + Crea)/SiO2-P adsorbent was then assessed together with that of co-existing metal ions by batch-adsorption and chromatographic separation studies. From the batch-adsorption experiment results, (HONTA + Crea)/SiO2-P adsorbent showed high adsorption performance of Pd(II) owing to an affinity between Pd(II) and Crea extractant based on the Hard and Soft Acids and Bases theory. Additionally, significant adsorption performance was observed toward Zr(IV) and Mo(VI). Compared with studies using the Crea extractant, the high adsorption performance of Zr(IV) and Mo(VI) is attributed to the HONTA extractant. As revealed from the chromatographic experiment results, most of Pd(II) was recovered from the feed solution using 0.2 M thiourea in 0.1 M HNO3. Additionally, the possibility of recovery of Zr(IV), Mo(VI), and Re(VII) was observed using the (HONTA + Crea)/SiO2-P adsorbent.

Clinical and Radiological Outcomes of Acute Acromioclavicular Joint Dislocation: Comparison of Hook Plate Fixation with Single Tight Rope Technique

  • Lee, Sung Hyun;Kim, Jeong Woo;Kook, Seng Hwan
    • Clinics in Shoulder and Elbow
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    • 제20권3호
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    • pp.153-161
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    • 2017
  • Background: This study was conducted to compare the clinical and radiological outcomes of the locking hook plate fixation (HP) technique and the single tight rope (TR) technique applied for acute high-grade acromioclavicular (AC) joint separations. Methods: Between 2009 and 2014, 135 consecutive patients with acute AC joint separation Rockwood types III, IV, and V were subjected to surgical reconstruction. One hundred fourteen patients (84.4%) were available for retrospective evaluation. Of them, 62 and 52 were treated using the single TR group and clavicular HP group techniques, respectively. The visual analogue scale, Constant, American Shoulder and Elbow Surgeons (ASES), and Taft scores were used for clinical assessment. Postoperative shoulder range of motion was also assessed. An anteroposterior radiograph of the coracoclavicular distance (CCD) was obtained to evaluate the radiographic signs of recurrence. Results: The TR group patients had better Constant, ASES, and Taft scores than the HP group patients. The loss of reduction in terms of the CCD did not differ between groups. Subacromial osteolysis was observed in 34.6% of the cases in the HP group. However, there were no significant differences in the clinical outcomes between the patients with and without osteolysis in the HP group. Subcoracoid osteolysis, drill tunnel widening, and metal displacement were observed in 3.2%, 22.6%, and 4.8% of the cases in the TR group, respectively. Conclusions: The single TR technique was relatively more effective at treating acute high-grade AC joint injuries than the HP fixation technique (level of evidence: therapeutic; retrospective comparative study, Level III).

$CO_2$ 선택투과 분리를 위한 Silica 코팅 Alumina 막의 세공 제어 (Pore Size Control of Silica-Coated Alumina Membrane for $CO_2$ Separation)

  • 서봉국;김성수;김태옥
    • 한국환경과학회지
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    • 제8권2호
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    • pp.263-269
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    • 1999
  • For effective $CO_2$ separation using pore size controlled membrane, silica was deposited in the mesopores of a $\gamma$-alumina film by chemical vapor deposition of tetraethoxysilane (TEOS) and phenyl-substituted ethoxysilanes at 773-873K. The membranes prepared with phenyl-substituted ethoxysilanes were calcined to remove the phenyl group and control the pore size. The gas permaselectivity of prepared membranes was evaluated by using $H_2$, $CO_2$ $N_2$, $CH_2$ and $C_3H_8$ single component and a mixture of $CO_2$ and $N_2$. The membranes produced using TEOS contained micropores having permselectivity only to hydrogen, but the phenyl-subsitituted ethoxysilane derived membranes possessed micorpores which are recognizable molecules of $CO_2$, $N_2$ and $CH_4$. In the diphenyl-diethoxysilane-derived membrane, the $CO_2$ permeance and selectivity of $CO_2$/$CH_4$ were $10^{-6} m^3(STP) \cdot m^{-2} \cdot s^{-1} \cdot kPa^{-1}$ and 11, respectively. Therefore, the use of phenyl-substituted ethoxysilane was effective in controlling micropore size for $CO_2$ separation.

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nm-수준의 상분리를 이용하여 제조한 고강도 고인성 철계 비정질 합금 (Fe-based Amorphous Alloy with High Strength and Toughness Synthesized based on nm-scale Phase Separation)

  • 이광복;박경원;이상호;이재철
    • 대한금속재료학회지
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    • 제48권1호
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    • pp.1-7
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    • 2010
  • Experiments have demonstrated that the addition of a moderate amount of V to $Fe_{52}Co_{(20-x)}B_{20}Si_4Nb_4V_x$ amorphous alloy enhances the plasticity of the alloy. In particular, $Fe_{52}Co_{17.5}B_{20}Si_4Nb_4V_{2.5}$ alloy withstood a maximum of 8.3% strain prior to fracture along with a strength exceeding 4.7 GPa. Energy dispersive x-ray spectroscopy conducted on the $Fe_{52}Co_{17.5}B_{20}Si_4Nb_4V_{2.5}$ alloy exhibited evidence of compositional modulation, indicating that nm-scale phase separation had occurred at local regions. In this study, the role played by nm-scale phase separation on the plasticity was investigated in terms of structural disordering and shear localization in order to better understand the structural origin of the enhanced plasticity shown by the developed alloy.

간흡충 감염 마우스에 있어서 환관 상피세포의 미세구조에 대한 Aflatoxin $B_1$의 영향 (Effect of Aflatoxin $B_1$ on Ultrastructural Changes of Biliary Epithelial Cells in Mice Experimentally Infected with Clonorchis sinensis)

  • 민홍기
    • Parasites, Hosts and Diseases
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    • 제25권2호
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    • pp.99-109
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    • 1987
  • The present study was carried out to examine the effect of a calcinogen, aflatoxin B1 on the ultrastructural changes of ciliary epithelial cells in mice infected with Clonerchis sinensis. A total of 93 male albino mice(BALB/c strain) was divided into 3 groups; group I, treated with 1.0 ppm aflatoxin Bl for 12 weeks; group II, given 50 C. sinensis n;etacercariae, and group III, given 50 metacercariae and treated with 1.0 ppm aflatoxin Bl for 12 weeks. Three mice served for untreated-uninfected controls. From 4 weeks after the treatsment and/or in(ection, three mice from each group were sacrificed at 4 week intervals up to the 40th week, and their hepatobiliary tissues were prepared for transmission electron microscopy. The most prominent ultrastructural changes in group I were remarkable enlargement of nuclear size, separation of nucleolus, dispersed chromatin granules in nuclei and increased dense granules along the inner membrane of nuclei. In the cytoplasm there was slight proliferation of mitochondria and endoplasmic reticulum (ER) at earlier stage. At the 12th week separation of fibrillar and granular components of the nucleolus was a characteristic finding. As the time elapsed, epithelial cells showed fiattened-cuboidal form and a tendency of atrophy. Most of the nuclei were elongated and polygonal in shape. In group II the appearance of elaborate interwoven folds of lateral cytoplasm forming a labyrinth of interconnected intercellular space and variety in nuclear shape were the prominent fadings at earlier stage. The cytoplasm showed slight proliferation and dilatation of mitochondria and ER, and a small number of mucin droplets. In the basement membrane scanty fibrous cells were seen. With time, variety in nuclear shape, marked proliferation and dilatation of rough ER and some collagen fibrils were demonstrated. Other features of intracellular organelles and mucin droplets persisted. In group III cuboidal epithelial cells showed their remarkably enlarged and irregular nuclei, increased chromatin granules in the nuclei, separated nucleoli, proliferated and dilated rough ER. With time, sequestered mitochondria showed blob-like evaginations which lacked cristae and dense matrix, and were limited by a single membrane. Since the 20th week, microvilli were relatively scanty and poorly developed. Organelles and inclusions in the cytoplasm of metaplastic cells were poor. Nuclei were variable in shape. The nlost prominent changes at later stage were separation of nuclei from the cytoplasm, and appearance of numerous and irregularly angled electron dense granules in the nuclei.

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한의약분업과 관련된 여러 가지 문제 (Tasks for the Separation of Prescribing and Dispensing medicinal herbs in Traditional Korean Medicine)

  • 이해웅;김훈;김경철;김종환;신우진;박동일;황원덕
    • 대한한의학원전학회지
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    • 제23권1호
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    • pp.133-142
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    • 2010
  • Preconditions for the separation of prescribing and dispensing medicinal herbs in Traditional Korean Medicine are classification of medicinal herbs for general public and special medical uses, establishment of national medicinal herb distribution company of governmental base, restriction in purchase of medicinal herbs for special medical use, partnership between doctors and pharmacists of Traditional Korean Medicine, and coverage of herbal medicine-based medication in national health insurance, etc. The number of Traditional Korean Medicine Pharmacists which was born during 'the herbal medicine conflict' initiated in 1993, goes over 1,000 and will increase by 120 annually. The number of Traditional Korean Medical Doctors is over 17,000 and increases by 850 annually. So in order to engage partnership between two groups, the government have to arrange the number of outputs of each group. Standardization and classification of diagnosis and diseases in Traditional Korean Medicine is a matter of course in the separation of prescribing and dispensing medicinal herbs. Related societies and academies need to do researches with governmental fund first. After these works, we can launch a task force team for implementation of process for the separation of prescribing and dispensing medicinal herbs in Traditional Korean Medicine properly. Entering the national health insurance system for full coverage of Korean Medicine care service will be essential for the patients. Implementation the separation of prescribing and dispensing medicinal herbs in Traditional Korean Medicine would be the core of health insurance coverage for medication.

기체분리용 고분자 멤브레인의 최근 개발 동향 (A Numerical Analysis of Direct Contact Membrane Distillation for Hollow Fiber Membrane)

  • 김태헌;정종채;박종만;우창화
    • 멤브레인
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    • 제20권4호
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    • pp.267-277
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    • 2010
  • 가스분리막을 이용한 분리공정은 기존의 분리공정을 대체할 공정으로서 수십 년간 발전이 되어 왔다. 특히 분리막 공정은 가스분리에 있어서 기존공정에 비해서 에너지 소모가 적고 설치에 필요한 공간이 간소하며, 스케일업이 간단한 장점이 있다. 최근에는 기체분리막 공정은 질소발생장치, 수소발생장치, 막제습기, 선박이나 항공기용 불활성기체충진장치, 천연가스 정제, 바이오가스 정제, 연료전지분야에서 널리 사용이 되고 있으며, 향후에는 이산화탄소의 분리에도 강력한 대체공정으로 사용이 될 수 있다. 이러한 가스분리막 공정을 좀 더 널리 보급하기 위해서는 로베슨 플롯의 한계를 넘어설 수 있는 새로운 소재의 개발이 절실하며, 이러한 한계를 돌파하기 위하여 많은 연구자와 회사들이 카도그룹이나 스피로 구조를 가지는 고분자나 PIMs 같은 소재의 개발에 박차를 가하고 있다.