• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1998.06a
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• pp.43-49
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• 1998

Retardation effect of heavy metals in soils caused by adsorption onto the surfaces of solids particles is well known phenomena. The adsorption of metal ions has been recognized more strong in clay mineral and organic matter contents rather than sands and gravels. In this study, we investigated the retardation effect in two sandy soils by conducting batch and column tests. The column tests were conducted to obtain the relationship between concentration and time known as breakthrough curve (BTC). We applied pulse type injection of ZnCl$_2$solution on the inlet boundary and monitored the effluent concentration at the exit boundary under steady state condition using EC-meter and ICP-AES. Batch test consisted of an equilibrium procedure for fine fractions collected from two sandy soils for various initial ZnCl$_2$concentrations, and analysis of Zn ions in equilibrated solution using ICP-AES. The results of column test showed that i) the peak concentration of Zn analyzed by ICP was far less than that detected by EC-meter for both soils and ii) travel times for peak concentration were more less identical for two different monitoring techniques. The first result can be explained by ion exchange between Zn and other cations initially present in the soil particles since ICP analysis showed a significant amount of Ca, Mg ions in the effluent. From the second result, we found that retardation effect was not present in these soils due to strong cation exchange capacity of Zn ion over other cations since we did not apply a solution containing more adsorptive cations such as Al. The result of batch test also showed high distribution coefficients (K$_{d}$) for two soils supporting the dominant ion exchange phenomena. Based on the retardation factor obtained from the Kd, we predicted the BTC using CDE model and compared with the BTC of Zn concentration obtained from ICP The predicted BTC, however, disagreed with the monitored in terms of travel time and magnitude of the peak concentrations. The only way to describe the prominent decrease of Zn ion was to introduce decay or sink coefficient in the CDE model to account for irreversible decrease of Zn ions in liquid phase.e.

• Journal of Soil and Groundwater Environment
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• v.20 no.6
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• pp.62-72
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• 2015

This study investigates the in-situ implementation of bio-regenerated iron mineral catalyst to remove explosive compounds in ground water at a military shooting range in operation. A bio-regenerated iron mineral catalyst was synthesized using lepidocrocite (iron-bearing soil mineral), iron-reducing bacteria Shewanella putrefaciens CN32, and electron mediator (riboflavin) in the culture medium. This catalyst was then injected periodically in the ground to build a redox active zone acting like permeable reactive barrier through injection wells constructed at a live fire military shooting range. Ground water and core soils were sampled periodically for analysis of explosive compounds, mainly RDX and its metabolites, along with toxicity analysis and REDOX potential measurement. Results suggested that a redox active zone was formed in the subsurface in which contaminated ground water flows through. Concentration of RDX as well as toxicity (% inhibition) of ground water decreased in the downstream compared to those in the upstream while concentration of RDX reduction products increased in the downstream.

• Journal of Soil and Groundwater Environment
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• v.16 no.4
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• pp.53-61
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• 2011

This study examined evaluation on stabilization of major and trace elements in tailings by various surface water-preventing materials. Six columns were filled with tailings of the Sinlim mine, then covered with tailings only, compacted soils, clay, soil-bentonite mixture, pozzolan and bentonite mat. After injection of artificial rain water, the leachate was sampled with times (3, 6, 9 and 12 pore volume) and analysed for major (Ca, Na, Mg, K) and trace elements (As, Cd, Cu, Pb, Zn) by ICP-AES. With exception to pozzolan type, the pH values of leachate from the other types became stabilized from 5.5 to 7.5, and EC (electric conductivity) of leachate from them decreased with times. For the pozzolan type, however, the pH and EC of leachate increased with time due to its alkalinity producing system. Concentrations of most major and trace elements in leachate decreased and stabilized with time. Consequently, soil-bentonite mixed cover shows the best ability of water-preventing and reducing mobility of elements in tailings site.

• The Journal of Engineering Geology
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• v.9 no.3
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• pp.227-241
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• 1999

Groundwater flow in a fractured rock mass is related to the geometric characteristics of the fracture system. The objective of this study aims to analyze the probabilistic density function of fracture properties md their relations to the hydraulic conductivity in volcanic rocks of the northern Yosu area. Fracture characteristics were investigated by core logging and acoustic televiewer logging in four boreholes and the hydraulic conductivity was obtained from the constant pressure injection and fall-off tests. The 303 fractures were grouped into three sets by their orientation and three fracture types by the degree of opening in aperture. As a result of the study, the hydraulic conductivity in the test section intersected by open and semi-open fractures, conductive fractures, and set 1 fractures was very high, while closed fractures did rarely affect the hydraulic conductivity. It was recognized that the hydraulic conductivity in a fractured rock mass was preferentially affected by the aperture size of conductive fractures and fracture intersection frequency and size, secondly.

• Geomechanics and Engineering
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• v.25 no.4
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• pp.295-302
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• 2021

Cross-borehole electrical resistivity tomography (ERT) is an effective groundwater detection tool in geophysical investigations. In this paper, an artificial water injection test was conducted on a small clay sample, where the high-resolution cross-borehole ERT was used to investigate the moisture migration law over time. The moisture migration path can be two-dimensionally imaged based on the relationship between resistivity and saturation. The hydraulic conductivity was estimated, and the magnitude ranged from 10^-11 m/s to 10^-9 m/s according to the comparison between the simulation flow and the saturation distribution inferred from ERT. The results indicate that cross-borehole ERT could help determine the resistivity distribution of small size clay samples. Finally, the cross-borehole ERT technique has been applied to investigate the self-sealing characteristics of clay.

• The Journal of Engineering Geology
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• v.11 no.3
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• pp.279-294
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• 2001

When constructing subsurface structures and drilling wells, the precise hydraulic parameters must be obtained for operating safety and for developing enough quantity of groundwater, respectively. In this study we conducted water injection test at different depths on six boreholes drilled in the granite of Mt. Geumjeong. Hydraulic conductivity was calculated using Moye and Hvorslev methods. The relation between hydraulic conductivity and fracture frequency data obtained from acoustic televiewer and core log was analyzed. From the result, though the correlation coefficient between the hydraulic conductivity and the fracture frequency from acoustic televiewer data is higher than that between the hydraulic conductivity and the fracture frequency from core log data on most of the test holes, the correlation coefficient between the hydraulic conductivity and the fracture frequency from the televiewer data is lower than 0.5. This suggests that the hydraulic conductivity of granite in the study area is influenced not only by the fracture frequency but also by various factors of fracture network such as fracture aperture and length, interconnectivity of fractures, fracture orientation and angle, filling material and so on.

• Journal of Soil and Groundwater Environment
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• v.8 no.2
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• pp.62-69
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• 2003

The aim of research is the evaluation of the $Cr^{6+}$ emission features of the liquid injection through emission experiments in varying conditions, based on a field-mixing ratio. The results showed that the content of $Cr^{6+}$ content in cement measured had an Ordinary Potland Cement (OPC) of 25.3 mg/kg, which constitute the largest portion among the other materials. Likewise, the emission experiment of homo-gel and sand-gel generally satisfied the standard of KSLT (Korea Standard Leaching Test) in waste of 1.5 mg/L, but in case of the standard of KSLT in soil the emission of OPC $Cr^{6+}$ of 4.85 mg/kg. These conditions is a little exceeded the criteria in the ‘Ga’ area in terms of Korea Soil Environmental Preservation Law. In addition, results generated by the mock-up injection facilities revealed that $Cr^{6+}$ emission increased as Water/Cement and injection pressure increased. At injection pressure higher than 4 kg/㎤, $Cr^{6+}$ emission exceeded the water preservation standard of 0.5 mg/L. Similarly, a pattern experiment of C $r^{6+}$ emission according to pH was conducted, in order to evaluate the $Cr^{6+}$ emission features of grout materials in leachate below pH 5 such as pH 4 acid rain or landfill. Results show that $Cr^{6+}$ emission dramatically increased in high acidic or basic state. It indicates that $Cr^{6+}$ emission will probably increase in an environment where grout materials are injected. On the other hand, concentration of leachate was determined in areas where grout materials are used. The results show that the concentration of emission in an ultra purity condition does not manifest intensity, and is affected in the OPC>MC>SC order. It means that the pollutants or $Cr^{6+}$ emission increases with decreasing concentration. As such, $Cr^{6+}$ emission will probably exceed the countermeasure criteria according to the types of gout materials. Similarly, high pressure or injection will cause increased $Cr^{6+}$ emission. Therefore, the selection of materials or mixing ratio should be considered in general as well as according to specific industries, based on the strength and pH of $Cr^{6+}$ emission.

• Journal of Soil and Groundwater Environment
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• v.7 no.4
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• pp.77-86
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• 2002

Surfactant enhanced in-situ soil flushing was performed to remediate the soil and groundwater at an oil contaminated site, where had been used as a military vehicle repair area for 40 years. A section from the contaminated site (4.5 m $\times$ 4.5 m $\times$ 6.0 m) was selected for the research, which was composed of heterogeneous sandy and silt-sandy soils with average $K_d$ of 2.0$\times$$10^{-4}$cm/sec. Two percent of sorbitan monooleate (POE 20) and 0.07% of iso-prophyl alcohol were mixed for the surfactant solution and 3 pore volumes of surfactant solution were injected to remove oil from the contaminated section. Four injection wells and two extraction wells were built in the section to flush surfactant solution. Water samples taken from extraction wells and the storage tank were analyzed on a gas-chromatography (GC) for TPH concentration in the effluent with different time. Five pore volumes of solution were extracted while TPH concentration in soil and groundwater at the section were below the Waste Water Discharge Limit (WWDL). The effluent TPH concentration from wells with only water flushing was below 10 ppm. However, the effluent concentration using surfactant solution flushing increased to 1751 ppm, which was more than 170 times compared with the concentration with only water flushing. Total 18.5 kg of oil (TPH) was removed from the soil and groundwater at the section. The concentration of heavy metals in the effluent solution also increased with the increase of TPH concentration, suggesting that the surfactant enhanced in-situ flushing be available to remove not only oil but heavy metals from contaminated sites. The removal efficiency of surfactant enhanced in-situ flushing was investigated at the real contaminated site in Korea. Results suggest that in-situ soil flushing could be a successful process to remediate contaminated sites distributed in Korea.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.21 no.2
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• pp.32-38
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• 2020

This study summarizes test methods and evaluation methods for examining the thermal characteristics of Jeju-type ground heat exchangers (GHXs) installed on Jeju Island, and analyzes the ground temperature and thermal characteristics of ground heat exchangers installed in various regions by using thermal response tests (TRT). Jeju Island is composed of volcanic rock layers, and the groundwater flow is well developed. A Jeju-type GHX can be installed up to 30 m from groundwater level after drilling a borehole. The ground heat exchanger has a structure in which several pipes are inserted into the borehole. In order to examine the characteristics of the Jeju-type GHX, tests were conducted on ground heat exchangers installed in four places on Jeju Island (Pyoseon, Jeju, Namwon, and Hallym). As a result of the analysis of the Jeju-type ground heat exchanger, the ground circulating water temperature stabilized according to the heat injection, depending on the installed location, and was formed within one to three hours. The ground heat exchanger capacity in Hallym was highest at 73.4 kW (cooling) and 82.8 kW (heating), and the Jeju-type calculation was lowest at 34.1 kW (cooling) and 23.3 kW (heating).

• Economic and Environmental Geology
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• v.49 no.6
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• pp.445-458
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• 2016

Most of water curtain cultivation (WCC) area in Korea has been inveterately suffering from the gradual draw-down of groundwater level and related shortage of water resources at the late stage of WCC peak time. To solve this problem, artificial recharge techniques has been recently applied to some WCC area. This study introduces infiltration gallery, which is one of the artificial recharge methods, and tentatively examined the effectiveness of three galleries installed at Sangdae-ri WCC area of Cheongju City. Seven galleries are set up at each empty space between eight vinyl houses in this area and its dimension is designed as 50 cm in each width and height and 300 cm in each length. Installation process was including bed excavation, backfill with gravels and silica sands, and completion of gallery by equipment of piezometer and covering with non-woven cloth. For each B, C, D gallery, 3 types of test including preliminary, four step and one long-term injection were performed. The first preliminary test showed the rough relations between injection rates and water level rise as follows; 20 cm and 30 cm level rise for $33.29{\sim}33.84m^3/d$ and $45.60{\sim}46.99m^3/d$ in B gallery; 0 cm, 16 cm and 33 cm level rise for $21.1m^3/d$, $33.98m^3/d$ and $41.69m^3/d$ in C gallery; 29 cm and 42 cm level rise for $48.10m^3/d$ and $52.23m^3/d$ in D gallery. Afterwards, more quantitative results estimating effectiveness of artificial recharge were reasoned out through stepped and long-term injection tests, which is expected to be employed for estimating water quantity re-injected into the aquifer through these galleries by natural injection over the period of WCC peak time.