Journal of Korean Society of Environmental Engineers
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v.32
no.7
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pp.690-698
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2010
Contamination of groundwater resources by organic chemicals has become an issue of increasing environmental concern. Surfactant-enhanced aquifer remediation (SEAR) is widely recognized as one of the most promising techniques to remediate organic contaminations in-situ. Solutions of surfactant or surfactant with polymer are used to dramatically expedite the process, which in turn, may reduce the treatment time of a site compared to use of water alone. In the design of surfactant-based technologies for remediation of organic contaminated aquifers, it is very important to have a considerable analysis using extensive numerical simulations prior to full-scale implementation. This study investigated the formation and flow of microemulsions during SEAR of organic-contaminated aquifer using the finite difference model UTCHEM, a three-dimensional, multicomponent, multiphase, compositional model. The remediation process variables considered in this study were the sequence of injection fluids, the injection and extraction rate, the concentrations of polymer in surfactant slug and chase water, and the duration of surfactant injection. For each variable, temporal changes in injection and production wells and spatial distributions of relative saturations in the organic phase were compared. Cleanup time and cumulative organic recovery were also quantified. The study would provide useful information to design strategies for the remediation of nonaqueous phase liquid-contaminated aquifers.
Retention ponds have been dug along some of the motorways to control water flow during rainstorms and to minmize environmental pollution. A retention pond located at Les Ardilleres about 20km South of Orleans along the A-71 motorway has been selected to evaluate the effectiveness of such a pond as a trap for heavy metals. Based on the "index of geoaccumulation" and the "enrichment factor" normalized to Fe introduced by Muller in 1979 and by Helz in 1976, respectively, the degree of contamination by heavy metals for the roadside soil and the settling particles was evaluated. As expected, the contamination was very severe in the roadside soil, while it was not so great in the settling particles. Using these methods, cadmium anomaly was traced in the settling particles of the retention pond, their occurrence being attributed partly to natural and partly to anthropogenic pollution. The estimated input of heavy metals associated with settling particles to the pond was 0.9 g/day Pb, 2.1 g/day Zn and 6mg/day Cd. A tentative mass balance of Pb and Zn originated by motor vehicles suggested that only 5 to l1% of heavy metals deposited on the surface of the motorway is carried to the retention pond by runoff water ; suggestions are made to improve their efficiency.ve their efficiency.
Permeable Reactive Barriers (PRB) method is an economical method that does not require any other methods to be operated once it is installed as it controls of groundwater flow in the barrier, which is inserted a reactive material on the way of pollutant. The major dominant element of PRB is a reactive material in the reactive wall, and such factors as purification efficiency and used time based on the chemical and physical features in between the reactant and pollutant. High purification efficiency can be expected when a rational design that is synthetically considered in features of packing density, operation period, and adsorption reactant of pollutant. A column test was conducted for an application test using CFW as its adsorption reactant in order to remove copper($Cu^{2+}$) in the PRB system. The CFW was used for the reactant and selected inflow speed, density and thickness of PRB as its necessary factors for design of PRB. As a result of the experiment, the removal efficiency decreased as operating time of PRB increased and the efficiency linearly increased upon the length. Therefore, it is confirmed that the thickness of reactive materials in PRB system can be designed using the proposed formula considering purification time and density of CFW.
For the reasonable use of low grade-shallow geothermal energy by Standing Column Well(SCW) system, the basic requirements are depth-wise increase of earth temperature like $2^{\circ}C$ per every 100m depth, sufficient amount of groundwater production being about 10 to 30% of the design flow rate of GSHP with good water quality and moderate temperature, and non-collapsing of borehole wall during reinjection of circulating water into the SCW. A closed loop type-vertical ground heat exchanger(GHEX) with $100{\sim}150m$ deep can supply geothermal energy of 2 to 3 RT but a SCW with $400{\sim}500m$ deep can provide $30{\sim}40RT$ being equivalent to 10 to 15 numbers of GHEX as well requires smaller space. Being considered as an alternative of vertical GHEX, many numbers of SCW have been widely constructed in whole country without any account for site specific hydrogeologic and geothermal characteristics. When those are designed and constructed under the base of insufficient knowledges of hydrgeothermal properties of the relevant specific site as our current situations, a bad reputation will be created and it will hamper a rational utilization of geothermal energy using SCW in the near future. This paper is prepared for providing a guideline of SCW design comportable to our hydrogeothermal system.
The calcium hydroxide$(Ca(OH)_2)$ which is the cement hydrate flowed into the tunnel by groundwater is reacted with microorganism in the soil, carbon dioxide$(CO_2)$ and the vehicle's exhaust gas$(SO_3)$. So its by-products are precipitated at the drainage pipe and these cause the drainage clogging. By this phenomenon, Degradation of water flow at the drainage system of the tunnel occurred and also pore water pressure is increased. Hence the acceleration of seepage and degradation of lining is occurred. The purpose of this study is to evaluate the field applicability of the Quantum Stick and Magnetic treatment in prevention of scale deposits at the Namsan ${\bigcirc}{\bigcirc}$ tunnel and the Zone ${\bigcirc}{\bigcirc}{\bigcirc}$ of subway. These technologies were installed into drainpipes with their performance monitored through occasional site visits. SEM and XRD were also performed on scale collected from these drainpipes. As a result, in case which factor technology is applied, scale creation is remarkably decreased and especially Quantum Stick treatment performing better than Magnetic treatment. Therefore, additional application of Quantum Stick or Magnetic treatment to the existing drainage is expected to decrease the drainage clogging of the drainage.
Kim, Soo Hong;Kwon, Jun Wook;Kim, Sun Myung;Kim, Yun kwang;Jang, Yun Ho
Journal of Korean Tunnelling and Underground Space Association
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v.19
no.4
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pp.589-609
/
2017
This study carried out the density and energy dispersive X-ray spectroscopy and particle size analysis which are the physical characteristics of coal dust by collecting samples of coal dust in the five domestic mines to control the coal dust through ventilation in the workplace for coal mining in the country. This will contribute to a more comfortable working environment by understanding the physical characteristics of the coal dust which is derived from any hard coal produced domestically. In particular, the result of PSA analysis showed that the size of coal dust sample for this study ranged from $0.007{\sim}88.614{\mu}m$ were the particles less than $3.5{\mu}m$, the size range responsible for pneumoconiosis. To observe the flow of coal dust collected on the wind speed, the fallout of coal dust produced by the wind tunnel for the wind was measured and the particle size analysis of coal dust fallout was carried out. In addition, airborne dust is measured according to the mine velocity by using a multi-stage Anderson sampler in the mine where fine dust is generated in a large amount and the wind speed is found out to control the coal dust below $3.5{\mu}m$. In addition, natural ventilation pressure of A mine was calculated to prevent over design of the main fan.
Soil vapor extraction (SVE) is known to be an effective process to remove the contaminants from the soils by enhancing the vaporization of organic compounds using forced vapor flows or applying vacuum through soils. Experiments are carried out to investigate the effects of the organic contaminants, types of soils, and water contents on the removal efficiency with operating time. In the study, simulated soils include the glass bead which has no micropore, sand and molecular sieve which has a large volume of micropores. As model organic pollutants, toluene, methyl ethyl ketone, and trichloroethylene are selected. Desorption experiments are conducted by flowing nitrogen gas. Under the experimental conditions, it is found that there are linear relationships between logarithm of removal efficiency and logarithm of number of pore volumes. The number of pore volumes are defined as the total amount of air flow through the soil column divided by the pore volume of soil column. For three organic compounds studied, the removal rate is slow for no water content, while the number of pore volumes for removal of organic compounds are notably reduced for water contents up to 37%. For the removal of dense organic compound, such as trichloroethylene, a large number of pore volumes are needed. Also, the effects of the characteristics of simulated soils on the removal efficiency of organic compounds are studied. After the characterization of soil surface, porosity of soil columns and types of contaminants, the results could provide a basis for the design of SVE process.
Leachate is a result of the percolation of precipitation, uncontrolled runoff, and irrigation water into the landfill and can also include water initially contained in the waste as well as infiltrating groundwater. Behaviour of leachate by rainfall was studied to evaluate the variation of leachate generation and contaminants by rainfall in Sudokwon Landfill from January 1998 to October 1998. The quantity of leachate generated was measured with a flow meter, and the concentrations $BOD_5$, CODcr, T-N, $NE_3-N$, SS of leachate were also measured. Principal outcome obtained in this study are as follows : the quantity of leachate generated was the highest on August, the highest leachate generation volume in this period was 11,913㎥ and the lowest was $6,261m^3$. Although the similar amount of precipitation of 80mm applied to the two samples, there were difference in leachate generation due to precipitation duration, precipitation frequency, wet condition of solid wastes. As the result of regression analysis, the correlation coefficients(r) between the quantity of leachate generated and precipitation were 0.823, 0.976 between $BOD_5$ and CODcr, 0.992 between T-N and $NE_3-N$. As the quantity of leachate generated increased 48%, the concentration of $BOD_5$ and CODcr decreased 51% and 50% respectively. Therefore it was showed that the pollutant concentrations in leachate were diluted by precipitation. The concentrations of $BOD_5$ and COBcr in the rainy season were 2000~4000mg/1, 4000~6000mg/1 respectively, and 1000~3000 mg/1, 3000~5000 mg/l in the dry season. The loading of SS, $BOD_5$, CODcr(kg/month) on July was increased by 2.9 times, 2.8 times, 2.2 times with a basis on March. Therefore countermeasure of treatment facilities according to increase of loading by rainfall in summer is necessary.
Recently, the green spaces in the urban areas were greatly reduced due to urbanization and industrialization. As urban structures such as roads and buildings are built, the amount of impervious area within a watershed increases. High impervious surfaces are the common causes of high runoff volumes as the soil infiltration capacity decreases and the volume and rate of runoff increase thereby decreasing the groundwater recharge. These effects are causing many environmental problems, such as floods and droughts, climate change, heat island phenomenon, drying streams, etc. Most cities attempted to reduce sewer overflows by separating combined sewers, expanding treatment capacity or storage within the sewer system, or by replacing broken or decaying pipes. However, these practices can be enormously expensive than combined sewer overflows. Therefore, in order to improve these practices, alternative methods should be undertaken. A new approach termed as "Low Impact Development (LID)" technology is currently applied in developed countries around the world. The purpose of this study was to effectively manage runoff by adopting the LID techniques. Small Constructed Wetland(Horizontal Subsurface Flow, HSSF) Pilot-scale reactors were made in which monitoring and experiments were performed to investigate the efficiency of the system in removing pollutants from runoff. Based on the results of the Pilot-plant experiments, TSS, $COD_{Cr}$, TN, TP, Total Pb removal efficiency were 95, 82, 35, 91 and 57%, respectively. Most of the pollutants were reduced after passing the settling tank and the vertical filter media. The results of this study can contribute to the conservation of aquatic ecosystems and restoration of natural water cycle in the urban areas.
Proceedings of the Korean Society of Agricultural Engineers Conference
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2005.10a
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pp.490-495
/
2005
Organic compost has been widely applied to the cropland because it has been thought as Environmentally Sound Agriculture (ESA) in Korea. However, many field researches have been done to investigate water quality impacts of organic compost uses, compared to those from chemical fertilizer applications. It was found that pollutant loads from organic compost applied croplands were higher than those from chemical fertilizer applied areas. However, there might be other unknown factors affecting the results since the experiments were performed at the outside fields. In this study, indoor rainfall experiments using the Norton rainfall simulator systems were done to minimize and exclude errors from unknown sources by controlling soil characteristics, rainfall amount, rainfall intensity, and fertilizer treatments. The amounts of surface runoff and groundwater percolated from 10% and 20% slope plots were measured and water quality samples were collected and analyzed for BOD, COD, and T-P. Flow weighted mean concentration (FWMC) values were computed to assess effects of different fertilizer treatments. It was found that average concentration values of BOD were 5.57 mg/L from chemical fertilizer treated plot and 8.08 mg/L from organic compost treated plots. For 10% slope, FWMC BOD values from organic compost treated plots were higher by 29.9% than those from chemical fertilizer treated plots. For 20% slope, FWMC BOD values from organic plots were higher by 38.8% than those from chemical fertilizer plots. FWMC BOD values for 20% slope plots were higher than those from those for 10% slope plots. The similar trends were found for COD and T-P. In Korea, excessive use of organic compost has caused extremely high levels of organic matter contents at the cropland. Organic compost are usually applied to the cropland to improve soil quality, while chemical fertilizer is applied to help crop growth. Since organic compost is very slow in releasing its nutrients to the soil, farmers usually apply excessive organic compost for immediate effects and maximum crop yields, which has been causing soil and water quality degradations. Therefore, thorough investigations for better nutrient management plans are needed to develop the ESA strategy in Korea.
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