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Numerical Study on Operating Factors Affecting Performance of Surfactant-Enhanced Aquifer Remediation Process  

Lee, Kun-Sang (Department of Environmental and Energy Systems Engineering, Kyonggi University)
Publication Information
Abstract
Contamination of groundwater resources by organic chemicals has become an issue of increasing environmental concern. Surfactant-enhanced aquifer remediation (SEAR) is widely recognized as one of the most promising techniques to remediate organic contaminations in-situ. Solutions of surfactant or surfactant with polymer are used to dramatically expedite the process, which in turn, may reduce the treatment time of a site compared to use of water alone. In the design of surfactant-based technologies for remediation of organic contaminated aquifers, it is very important to have a considerable analysis using extensive numerical simulations prior to full-scale implementation. This study investigated the formation and flow of microemulsions during SEAR of organic-contaminated aquifer using the finite difference model UTCHEM, a three-dimensional, multicomponent, multiphase, compositional model. The remediation process variables considered in this study were the sequence of injection fluids, the injection and extraction rate, the concentrations of polymer in surfactant slug and chase water, and the duration of surfactant injection. For each variable, temporal changes in injection and production wells and spatial distributions of relative saturations in the organic phase were compared. Cleanup time and cumulative organic recovery were also quantified. The study would provide useful information to design strategies for the remediation of nonaqueous phase liquid-contaminated aquifers.
Keywords
Surfactant-enhanced Remediation; Nonaqueous Phase Liquids; Aquifer; Polymer; UTCHEM;
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Times Cited By KSCI : 1  (Citation Analysis)
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1 Delshad, M., Pope, G. A. and Sepehrnoori, K., "A compositional simulator for modeling surfactant enhanced aquifer remediation, 1 formulation," J. Contam. Hydrol., 23(4), 303-327(1996).   DOI   ScienceOn
2 Littmann, W., Polymer Flooding, Elsevier, Amsterdam, Netherlands(1988).
3 Ying, O., Cho, J. S. and Mansell, R. S., "Simulated formation and flow of microemulsions during surfactant flushing of contaminated soil," Water Res., 36(1), 33-40(2002).   DOI   ScienceOn
4 Schaerlaekens, J., Mertens, J., Linden, J. V., Vermeiren, G., Carmeliet, J. and Feyen, J., "A multi-objective optimization framework for surfactant-enhanced remediation of DNAPL contaminations," J. Contam. Hydrol., 86(3-4), 176-194(2006).   DOI   ScienceOn
5 Lowe, D. F., Oubre, C. L. and Ward, C. H., Surfactants and Cosolvents for NAPL Removal, Lewis Publishers, Boca Raton, FL(1999).
6 Qin, X. S., Huang, G. H., Chakma, A., Chen, B. and Zeng, G. M., "Simulation-based process optimization for surfactant-enhanced aquifer remediation at heterogeneous DNAPL-contaminated sites," Sci. Total Environ., 381(1-3), 17-37(2007).   DOI   ScienceOn
7 Jain, V. and Demond, A. H., "Impact of surfactants for aquifer remediation on physical properties of the aqueous phase," J. Contam. Hydrol., 40(1), 25-35(1999).   DOI   ScienceOn
8 Anderson, G. A., Simulation of Chemical Flood Enhanced Oil Recovery Processes Including the Effects of Reservoir Wettability, M. S. Thesis, U. of Texas at Austin, Austin, TX (2006).
9 Fiorenza, S., Miller, C. A., Oubre, C. L. and Ward, C. H., NAPL Removal: Surfactants, Foams, and Microemulsions, Lewis Publishers, Boca Raton, FL(2000).
10 Mulligan, C. N., Yong, R. N. and Gibbs, B. F., "Surfactant-enhanced remediation of contaminated soil: a review," Eng. Geol., 60(1-4), 371-380(2001).   DOI   ScienceOn
11 임경희, "계면활성제를 이용한 토양 복원 및 지하수 정화," 공업화학전망, 5(6), 7-15(2002).
12 Saba, T., Illangasekare, T.H., and Ewing, J., "Investigation of surfactant-enhanced dissolution of entrapped nonaqueous phase liquid chemicals in a two-dimensional groundwater flow field," J. Contam. Hydrol., 51(1-2), 63-82(2001).   DOI   ScienceOn
13 Intera Inc. and Naval Facilities Engineering Service Center, Surfactant-Enhanced Aquifer Remediation (SEAR) Implementation Manual, Naval Facilities Engineering Command, Washington, DC(2003).
14 송태을, 강주명, "계면활성제를 이용한 불포화 지층에 포집된 저비중 비수용성 유기용매 제거에 관한 실험적 연구," 한국자원공학회지, 35(2), 165-176(1998).
15 백기태, 양지원, "계면활성제 미셀과 한외여과를 이용한 지하환경 복원," 공업화학, 15(2), 153-162(2004).
16 Center for Petroleum and Geosystems Engineering, UTCHEM-9.0 A Three-Dimensional Chemical Flood Simulator, U. of Texas at Austin, Austin, TX(2000).
17 Paria, S., "Surfactant-enhanced remediation of organic contaminated soil and water," Adv. Colloid Interface Sci., 138(1), 24-58(2008).   DOI   ScienceOn