• Title/Summary/Keyword: Green Organic Light Emitting Diodes (OLEDs)

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Solution Processed Hexaazatrinaphthylene derivatives as a efficient hole injection layer for phosphorescent organic light-emitting diodes (신규 용액공정 정공주입층 소재 Hexaazatrinaphthylene 유도체를 도입한 인광 유기전기발광소자)

  • Lee, Jangwon;Sung, Baeksang;Lee, Seung-Hoon;Yoo, Jae-Min;Lee, Jae-Hyun;Lee, Jonghee
    • Journal of IKEEE
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    • v.24 no.3
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    • pp.706-712
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    • 2020
  • To improve light-emitting performance of green phosphorescent organic light-emitting diodes (OLEDs), we introduced new hole injection materials-hexaazatrinaphthylene (HATNA) derivatives as a solution processed hole injection layer (HIL). The HATNA derivative has a low the lowest unoccupied molecular orbital (LUMO) energy level, similar to the work function of Indium Tin Oxide (ITO), showing a different concept of hole injection mechanism. It was confirmed that the device efficiency of OLEDs using HATNA-HIL showed the improved external quantum efficiency from 10.8% to 15.6% and current efficiency from 32.7 cd/A to 42.7 cd/A due to the balance of electrons and holes in the emissive layer.

Highly Efficient Green Phosphorescent Organic Light Emitting Diodes

  • Lee, Se-Hyung;Park, Hyung-Dol;Kang, Jae-Wook;Kim, Hyong-Jun;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.496-498
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    • 2008
  • We have developed green phosphorescent organic light-emitting diodes (OLEDs) with high quantum efficiency. Wide-energy-gap material, 1,1-bis[(di-4-tolylamino) phenyl]cyclohexane (TAPC), with high triplet energy level was used as a hole transporting layer. Electrophosphorescent devices fabricated using TAPC as a hole-transporting layer and N,N'-dicarbazolyl-4,4'-biphenyl (CBP) doped with fac-tris(2-phenylpyridine) iridium [Ir(ppy)3] as the emitting layer showed the maximum external quantum efficiency ($\eta_{ext}$) of 19.8 %, which is much higher than the devices adopting 4,4'-bis[N-(1-naphthyl)-N-phenyl-amino]biphenyl (NPB) (${\eta}B_{ext}=14.6%$) as a hole transporting layer.

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Synthesis and Characteristics of Organic Emitting Materials for OLEDs using Color Conversion Method (색변환법 유기전계발광 소자용 유기 발광 재료의 합성 및 특성 분석)

  • Kwak, Seon-Yeop;Ryu, Jung-Yi;Nam, Jang-Hyun;Lee, Tae-Hoon;Kim, Tae-Hoon;Son, Se-Mo
    • Journal of the Korean Graphic Arts Communication Society
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    • v.23 no.1
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    • pp.77-97
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    • 2005
  • Organic light-emitting diodes(OLEDs) have received considerable attention since they were first reported by Tang. Novel organic fluorescent materials have been reported on synthesis and application of new organic light-emitting materials. Despite of much recent progress, fabrication of full-color OLEDs still remained to be done. Many method have been proposed to full-color OLEDs displays such as using separated red, green and blue emitters, stacking separate rad, green and blue emitter, using a white emitter with individually pattered color filters, microcavity structures and using a blue emitter with individually patterned fluorescent materials. The last method has much attention because of easy fabrication of OLEDs and low-priced fabrication. This paper reports the optical and electrical characteristics of OLEDs using novel molecules containing biphenyl structure. Optical properties of biphenyl derivatives doped with poly(9-vinyl carbazole)(PVK) are measured and found Forster energy transfer process in the blends. And devices were fabricated as ITO/PEDOT/PVK doped with biphenyl derivatives/$Alq_3$/Li:Al and I-V-L characteristics and EL efficiency of devices were examined.

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4.1' Flexible Organic Light Emitting Diodes Driven by Organic Thin-Film Transistors

  • Hu, Tarng-Shiang;Wang, Yi-Kai;Lin, Tsung-Hsien;Yan, Jing-Yi;Lee, Tzu-Wei;Yu, Chien-Hsien;Wen, Jiing-Fa;Kao, Chi-Jen;Chen, Liang-Hsiang;Shen, Yu-Yuan;Yeh, Shu-Tang;Tseng, Mei-Rurng;Wu, Po-Sheng;Ho, Jia-Chong;Lee, Cheng-Chung
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.314-316
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    • 2006
  • In this paper, the plastic organic thin-film transistors (OTFTs) with $32{\ast}32$ array are presented. Flexible organic light emitting diodes (OLEDs) operated by OTFTs are fabricated with a novel lamination method and the results are also presented. OTFT pixels defined by photolithography, and pentacene deposited by thermal evaporation. Fabrication method and the performances of green PHOLEDs with high efficiency, stability, and electrical performance are discussed.

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Fabrication of Red, Green, and Blue Organic Light-emitting Diodes using m-MTDATA as a Common Hole-injection Layer

  • Seol, Ji-Youn;Yeo, Seok-Ki;Song, Min-Chul;Park, Chin-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1408-1409
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    • 2005
  • Organic light-emitting diodes (OLEDs) of metalsemiconductor-metal (MSM) structure have been fabricated by using m-MTDATA [4,4',4"-tris (3-methylphenylphenylamino) triphenylamine] as a hole-injection layer (HIL). The m-MTDATA is shown to be an effective hole-injecting material for the OLED, in that the insertion of m-MTDATA greatly reduces the roughness of anode surface and improves the device performance.

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Effect of Hole Transport Layer on the Electrical and Optical Characteristics of Inverted Organic Light-Emitting Diodes (정공수송층이 역구조 OLED의 전기 및 광학적 특성에 미치는 영향)

  • Se-Jin Im;Dae-Gyu Moon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.4
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    • pp.397-402
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    • 2023
  • We have developed inverted green phosphorescent organic light emitting diodes (OLEDs) using 1,1-bis[(di-4-tolylamino)phenyl]cyclohexane (TAPC) and bis(carbazole-9-yl)biphenyl (CBP) hole transport layers. The driving voltage, current efficiency, power efficiency, and emission characteristics of devices were investigated. While the driving voltage for the same current density was about 1~2 V lower in the devices with the TAPC layer, the maximum luminance was higher in the device with the CBP layer. The maximum current efficiency and power efficiency were 3.2 and 2.7 times higher in the device with the CBP layer, respectively. The higher efficiency in the CBP device resulted from the enhanced hole-electron balance although weak parasitic recombination takes place in the CBP hole transport layer.

Synthesis of 5,6-Dihydro[1,10]phenanthroline Derivatives and Their Properties as Hole-Blocking Layer Materials for Phosphorescent Organic Light-Emitting Diodes

  • Lee, Hyo-Won;An, Jung-Gi;Yoon, Hee-Kyoon;Jang, Hyo-Sook;Kim, Nam-Gwang;Do, Young-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1569-1574
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    • 2005
  • To develop new hole-blocking materials for phosphorescent organic light-emitting diodes (PhOLEDs), 5,6-dihydro-2,9-diisopropyl-4,7-diphenyl[1,10]phenanthroline (1) and 5,6-dihydro-2,9-diisopropyl-4-(4-methoxyphenyl)-7-phenyl[1,10]phenanthroline (2) were synthesized. While the absorption spectrum of 1 is very similar to that of 2, the photoluminescence spectrum of 1 has the feature of the narrower and blue-shifted blueviolet emission at the peak of 356 nm compared to that of 2. The HOMO and LUMO energy levels of 1 and 2 were estimated from the measurement of cyclic voltammetry, and 1 has the appropriate levels for a holeblocking layer (HBL). The use of 1 as a HBL in a green PhOLED led to good efficiency of 23.6 cd/A at 4.4 mA/$cm^2$.

Photobiomodulation-based Skin-care Effect of Organic Light-emitting Diodes (유기발광다이오드를 이용한 Photobiomodulation 기반 스킨케어 효과)

  • Kim, Hongbin;Jeong, Hyejung;Jin, Seokgeun;Lee, Byeongil;Ahn, Jae Sung
    • Korean Journal of Optics and Photonics
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    • v.32 no.5
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    • pp.235-243
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    • 2021
  • Photobiomodulation (PBM)-based therapy, which uses a phenomenon in which a light source of a specific wavelength band promotes ATP production in mitochondria, has attracted much attention in the fields of biology and medicine because of its effects on wound healing, inflammation reduction, and pain relief. Research on PBM-based therapy has mainly used lasers and light-emitting diodes (LEDs) as light sources and, despite the advantages of organic light-emitting diodes (OLEDs), there have been only a few cases where OLEDs were used in PBM-based therapy. In this research, the skin-care effect of PBM was analyzed using red (λ = 620 nm), green (λ = 525 nm), and blue (λ = 455 nm) OLED lighting modules, and was compared to the PBM effect of LEDs. We demonstrated the PBM-based skin-care effect of the red, green, blue OLED lighting modules by measuring the increase in the amount of collagen type-1 synthesis, the inhibition of melanin synthesis, and the suppression of nitric oxide generation, respectively.

Blue organic light emitting diodes with carbazole based small molecules and color tunning by controlled side group

  • Kim, Y.B.;Ahn, Y.J.;Park, J.H.;Khang, M.W.;Woo, H.S.;Park, J.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.514-516
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    • 2003
  • We have fabricated an air stable blue emitting organic electroluminescent devices (OLEDs) with a carbazole based emitting molecule, Bis(3-N-ethylcarbazolyl)terephthalidene (BECP). Our device emits strong blue at 472 nm with the luminance efficiency of near 1 lm/W at a voltage and current density of 8 V and 5.7 mA/cm2, respectively, reaching the brightness up to 5000 cd/m2 at 270 mA/cm2. Finally, in order to tune the emission color from blue to green, we have used Bis(3-N-ethylcarbazolyl)cynoterephthalidene (BECCP), a derivative of BECP by adding cyno group in side chain, and compared the electroluminscence (EL) of OLEDS prepared by BECCP to that of BECP based OLEDs.

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