• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.85.1-85.1
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• 2011

In this study, Grafoil$^{TM}$ which has comparable electric resistance and chemical stability but is flexible, fragile, and cheap material was adopted as bipolar plates for proton exchange membrane fuel cell(PEMFC) having only one straight line flow channel. Because of its flexibility, pressurizations of cell with various pressures showed different operating characteristics compared to ordinary graphite-used PEMFC. While performances of both cells decreased as these were pressurized, investigation of ohmic and faradaic resistance by electrochemical impedance measurement indicated different tendency of change. Ohmic resistance of graphite-used cell increased with increasing pressure, which is reversed in Grafoil$^{TM}$-used cell. It is speculated that effective chemical reaction area is decreased with increasing pressure in case of graphite-used one, but because of flexible property of Grafoil$^{TM}$, gas diffusion layer in Grafoil$^{TM}$-used cell was well-activated. Different rate of change of faradaic resistances in both cells support this supposition. However, although optimum point of pressurization is found, it is required to investigate other operating conditions because of low performance compared to graphite-used cell.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.82.2-82.2
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• 2010

The development of bipolar plate having high efficiency and chemical properties has a major impact on fuel cell applications commercialization. Even though graphite bipolar plate has high electric conductivity and chemical resistance, it has demerits about mass production and brittle property for commercialization. Hence, metallic bipolar plate can be substitute for fuel cell bipolar plate. Although its inadequate corrosion behavior under PEMFC environment lead to a deterioration of membrane by dissolved metal ions, metallic bipolar plate for PEMFC is more suitable for automotive and residential power generation system because of its high mechanical strength, low gas permeability and applicability to mass production. Therefore, several types of coating has been applied to prevent corrosion and oxide film growth and to achieve more high durability. This work presents durability of coated metal bipolar plate for low temperature PEMFC which made for fuel cell vehicle. This results showed surface treatment increase long-term durability, even electric conductivity and corrosion resistance.

• Proceeding of KASS Symposium
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• 2008.05a
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• pp.74-79
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• 2008

In this study, impact transient responses of (Graphite/Epoxy) laminated composite subjected to low-velocity impact are investigated using a finite element method. Dynamic von-Karman plate equations considering large deflection of plate are modified to include the effect of transverse shear deformations as in Mindlin plate theory and also the rotary inertia effect is considered. The convergence of transient responses is used contact law established through the statical indentation test. We investigate displacements, contact forces and strains by thickness variation of various laminated composite. We compare and analyze each results.

• Journal of the Korean institute of surface engineering
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• v.44 no.5
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• pp.226-231
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• 2011

Graphene was coated on STS 316L by electro spray coating method to improve its properties of corrosion resistance and contact resistance. Exfoliated graphite (graphene) was made of the graphite by chemical treatment. Graphene is distributed using dispersing agent, and STS 316L was coated with diffuse graphene solution by electro spray coating method. The structure of the exfoliated graphite was analyzed using XRD and the coating layer of surface was analyzed by using SEM. Analysis showed that multi-layered graphite structure was destroyed and it was transformed into fine layers graphene structure. And the result of SEM analysis on the surface and the cross section, graphene layer was uniformly formed with 3~5 ${\mu}m$ thickness on the surface of substrate. Corrosion resistance test was applied in the corrosive solution which is similar to the PEM fuel cell stack inside. And interfacial contact resistance test was measured to simulate the internal operating conditions of PEM fuel cell stack. The results of measurements show that stainless steel coated with graphene was improved in corrosion resistance and surface contact resistance than stainless steel without graphene coating layer.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2002.10b
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• pp.325-329
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• 2002

This study targets mainly to reduce the manufacturing costs of cam spindles and manufacturing of mechanical components with longer service durations through application of surface engineering techniques on cam spindles. Within the frame of this study, we have attempted to establish the performances of cam spindles manufacture from forged steel and SGCI, through performance of wear tests in plate-disk system, metalographic investigations, SEM imaging, EDS analyses and micro hardness scans on test samples having the same sizes with original cam that once obtained from casting of Spherical Graphite Cast Iron (SGCI) are subjected partially to Boronising and partially to hardening in a salt solution and cam spindles currently manufactured from CK 45 through cauterization based reshaping.

• Tribology and Lubricants
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• v.5 no.2
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• pp.94-100
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• 1989

Friction and Wear behavior of continuous graphite fiber composites was studied for different fiber orientations against the sliding direction. The effect of fiber orientation on friction and wear of the composite and on the deformation of the counterface was investigated experimentally. Pin on disk type testing machine was built and employed to generate the friction and wear data. A graphite fiber composite plate was produced by the bleeder ply molding in an autoclave and machined into rectangular pin specimens with specific fiber orientations, i.e., normal, transverse, and longitudinal directions. Three different wear conditions were employed for two different periods of time, 24 and 48 hours. The wear track of the worn specimens and the metal counterface was examined with a scanning electron microscope (SEM) to observe the damaged fibers on the surface and wear film generation on the counterface. Wear mechanism of the composite during sliding wear is proposed based on the experimental results.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.25 no.2
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• pp.51-55
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• 2015

The present research is focused on the effect of porous graphite what is influenced on the 4H-SiC crystal growth by PVT method. We expect that it produces more C-rich and a change of temperature gradient for polytype stability of 4H-SiC crystal as adding the porous graphite in the growth cell. The SiC seeds and high purity SiC source materials were placed on opposite side in a sealed graphite crucible which was surrounded by graphite insulator. The growth temperature was around $2100{\sim}2300^{\circ}C$ and the growth pressure was 10~30 Torr of an argon pressure with 5~15 % nitrogen. 2 inch $4^{\circ}$ off-axis 4H-SiC with C-face (000-1) was used as a seed material. The porous graphite plate was inserted on SiC powder source to produce a more C-rich for polytype stability of 4H-SiC crystal and uniform radial temperature gradient. While in case of the conventional crucible, various polytypes such as 6H-, 15R-SiC were observed on SiC wafers, only 4H-SiC polytype was observed on SiC wafers prepared in porous graphite inserted crucible. The defect level such as MP and EP density of SiC crystal grown in the conventional crucible was observed to be higher than that of porous graphite inserted crucible. The better crystal quality of SiC grown using porous graphite plate was also confirmed by rocking curve measurement and Raman spectra analysis.

• Transactions of Materials Processing
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• v.21 no.1
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• pp.5-12
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• 2012

The weight of the bipolar plate is one of the crucial aspects of improving power density in PEMFC stacks. Aluminum alloys have good mechanical properties such as density, electrical resistivity, and thermal conductivity. Furthermore, using aluminum in a bipolar plate instead of graphite reduces the bipolar plate cost and makes machining easier. Therefore in this study, an aluminum alloy was selected as the appropriate material for a bipolar plate. Results from feasibility experiments with the aim of developing fuel cells consisting of Al bipolar plates with multiple channels are presented. Dynamic loading was applied and the formability of micro channels was estimated as a function of punch pressure and die radius. Sheets of Al5052 with a thickness of 0.3mm were used. For a die radius of 0.1mm the formability was optimized with a sine wave dynamic load of 90kN at maximum pressure and 5 cycles of a sine wave punch travel. The experimental results demonstrate the feasibility of the proposed manufacturing technique for producing bipolar plates.

• Journal of the Korean Electrochemical Society
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• v.12 no.1
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• pp.68-74
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• 2009

The effect of physico-electrochemical properties of carbon bipolar plate(BPP) on hydrogen and formic acid fuel cell performance has been investigated. BPP made of conventional graphite and carbon fiber composite were compared with the factors of interfacial contact resistance (ICR), corrosion behaviours, and hydrophobicity. Among them, the ICR of carbon fiber composite BPP has 50% higher than conventional graphite and the surface of carbon fiber composite BPP became rougher due to weaker corrosion resistance. Fuel cell performance was strongly dependent of ICR value of carbon bipolar plate.

• Elastomers and Composites
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• v.43 no.4
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• pp.253-258
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• 2008

In this study polyamide 6,6 based thermoplastic composite with graphite and carbon black had been examined feasibility for separators of fuel cell which requires good mechanical and electrical properties with gas impermeability. The effects of molding pressure and filler content on the properties of the composite were investigated. Maximum flexural modulus was obtained about 80 wt% graphite, while electrical conductivity increased with graphite content. Flexural strength increased with molding pressure and tended to level-off from $400\;kgf/cm^2$. Molding pressure did not affect the electrical conductivity. The addition of carbon black enhanced the electrical conductivity of the composite. Mechanical properties were decreased under acidic condition.