• Title/Summary/Keyword: Graphite fibers

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Development of Composite Bipolar Plate for Vanadium Redox Flow Battery (바나듐 레독스 흐름 전지용 복합재료 분리판 개발)

  • Lim, Jun Woo
    • Composites Research
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    • v.34 no.3
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    • pp.148-154
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    • 2021
  • Carbon/epoxy composite bipolar plate (BP) is a BP that is likely to replace existing graphite bipolar plate of vanadium redox flow cell (VRFB) due to its high mechanical properties and productivity. Multi-functional carbon/epoxy composite BP requires graphite coating or additional surface treatment to reduce interfacial contact resistance (ICR). However, the expanded graphite coating has the disadvantage of having low durability under VRFB operating conditions, and the surface treatments incur additional costs. In this work, an excessive resin absorption method is developed, which uniformly removes the resin rich area on the surface of the BP to expose carbon fibers by applying polyester fabric. This method not only reduces ICR by exposing carbon fibers to BP surfaces, but also forms a unique ditch pattern that can effectively hold carbon felt electrodes in place. The acidic environmental durability, mechanical properties, and gas permeability of the developed carbon/epoxy composite BP are experimentally verified.

Electrical and the Mechanical Properties of Graphite particle/carbon fiber hybrid Conductive Polymer Composites (흑연입자/탄소섬유 혼합 보강 전도성 고분자 복합재료의 전기적, 기계적 특성 연구)

  • Heo Seong-Il;Yun Jin-Cheol;Oh Kyung-Seok;Han Kyung-Seop
    • Composites Research
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    • v.19 no.2
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    • pp.7-12
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    • 2006
  • Graphite particle/carbon fiber hybrid conductive polymer composites were fabricated by the compression molding technique. Graphite particles were mixed with an epoxy resin to impart the electrical conductivity in the composite materials. In this study, graphite reinforced conductive polymer composites with high filler loadings were manufactured to accomplish high electrical conductivity above 100S/cm. Graphite particles were the main filler to increase the electrical conductivity of composites by direct contact between graphite particles. While high filler loadings are needed to attain good electrical conductivity, the composites becomes brittle. So carbon fiber was added to compensate weakened mechanical property. With increasing the carbon fiber loading ratio, the electrical conductivity gradually decreased because non-conducting regions were generated in the carbon fiber cluster among carbon fibers, while the flexural strength increased. In the case of carbon fiber 20wt.% of the total system, the electrical conductivity decreased 27%, whereas the flexural strength increased 12%.

Effect of Stabilization Conditions on the Microstructure and Electrochemical Properties of Melt-blown Graphite Fibers Prepared from NMP (NMP로부터 제조된 Melt-blown흑연섬유의 안정화조건에 따른 미세구조와 전기화학적 특성)

  • Kim Chan;Yang Kap Seung;Ko Jang Myoun;Park Sang Hee;Park Ho Chul;Kim Young-Min
    • Journal of the Korean Electrochemical Society
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    • v.4 no.3
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    • pp.104-108
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    • 2001
  • Naphthalene derived mesophase pitch WP) was spun into short fibers by using melt-blown technology. The pitch fibers oxidative stabilization were carried out heating rates of $2^{\circ}C/min,\;5^{\circ}C/min\;and\; 10^{\circ}/min$. The heating rate was a key factor to maximate the capacity of the Li-ion secondary battery through controlling the morphology of the graphitized fiber. The diameters of the melt-blown fibers prepared were in the range of $4{\mu}m\~16{\mu}m$ with functions of air jet speed, air temperature and the temperature of the nozzle. The graphitized fibers of $10{\mu}m$ diameters showed various morphological structure with heating rate of the stabilization. Radial, radial-random and skin-core cross-sectional structure of the fibers were observed at the respective heating rate of $2^{\circ}C/min\;5^{\circ}C/min\;and\;10^{\circ}C/min$. Most crystalline structure of graphite was obtained from the fiber stabilized at heating rate of $10^{\circ}C/min$ exhibiting the best anode performance with 400 mAh/g of capacitance and $96.8\%$ of charge/discharge efficiency.

Performance of carbon fiber added to anodes of conductive cement-graphite pastes used in electrochemical chloride extraction in concretes

  • Pellegrini-Cervantes, M.J.;Barrios-Durstewitz, C.P.;Nunez-Jaquez, R.E.;Baldenebro-Lopez, F.J.;Corral-Higuera, R.;Arredondo-Rea, S.P.;Rodriguez-Rodriguez, M.;Llanes-Cardenas, O.;Beltran-Chacon, R.
    • Carbon letters
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    • v.26
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    • pp.18-24
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    • 2018
  • Pollution of chloride ion-reinforced concrete can trigger active corrosion processes that reduce the useful life of structures. Multifunctional materials used as a counter-electrode by electrochemical techniques have been used to rehabilitate contaminated concrete. Cement-based pastes added to carbonaceous material, fibers or dust, have been used as an anode in the non-destructive Electrochemical Chloride Extraction (ECE) technique. We studied the performance of the addition of Carbon Fiber (CF) in a cement-graphite powder base paste used as an anode in ECE of concretes contaminated with chlorides from the preparation of the mixture. The experimental parameters were: 2.3% of free chlorides, 21 days of ECE application, a Carbon Fiber Volume Fraction (CFVF) of 0.1, 0.3, 0.6, 0.9%, a lithium borate alkaline electrolyte, a current density of $4.0A/m^2$ and a cement/graphite ratio of 1.0 for the paste. The efficiency of the ECE in the traditional technique using metal mesh as an anode was 77.6% and for CFVF of 0.9% it was 90.4%, with a tendency to increase to higher percentages of the CFVF in the conductive cement-graphite paste, keeping the pH stable and achieving a homogeneous ECE in the mass of the concrete contaminated with chlorides.

The Effect of Drawing Conditions on the Tensile Strength of Optical Fiber (광섬유의 인장강도에 미치는 Drawing Condition의 영향)

  • 한택상;최상삼
    • Journal of the Korean Ceramic Society
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    • v.19 no.1
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    • pp.44-50
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    • 1982
  • Drawing optical fibers in a graphite furnace is one of the most convenient and economical means of producing optical fiber. Since the flaw formation on optical fiber is mainly due to dust contaminations during drawing and surface corrosion by water vapor penetration through coating layer, the tensile strength of optical fiber drawn in a graphite furnace is greatly inflenced by the drawing conditions. The important factors found in this investigation were preform treatment (fire polishing), furnace interior environment (dust contamination, inert gas flows), primary coating condition (resin curing temperature, coating materials, method, thickness) and fiber pulling condition (furnace temperature, drawing speed, pulling tension). The tensile strength at optimum drawing conditions turned out to be 5 ~ 6 GPa.

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PCD 공구에 의한 Graphite/Epoxy 복합재료 가공시 발생하는 표면조도의 특성 연구

  • 왕덕현
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1992.10a
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    • pp.101-105
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    • 1992
  • Machined graphite/epoxy composite surfaces were studied by using SEM(Scanning Electron Microscopy). surface profilometry and its analysis to determine suitable surface describing parameters for machined unidirectional and laminate composite surface. The surface roughness and profile are found to be highly dependent on the fiber layup direction and the measurement direction. Machined unidirectional and 0.deg. 45 .deg. 90 .deg. plies in laminate composite surface profiles are found to be Gaussian in the direction of machining. Since there exist bare fibers without matrix smearing in 0 .deg. ply, higher surface roughness values were found in this orientation. It was possible to machine 90 .deg. and -45 .deg. plies due to the adjacent plies, which were holding those plies. It was found that the microgeometrical variations in terms of roughness parameters Ra without Dy (maximum Damage Depth) region and Dy are better descriptors of the machined laminate composite surface than commonly used roughness parameters Ra and Ra. The characteristics of surface profiles in laminate composite are well represented in CHD (Cumulative Height Distribution) plot and PPD (Percentage Probability Density) plot. Also, the power spectral density function is shown to be capable of identifying the wavelength distribution of the machining damage.

Numerical Evaluation of Phase Velocity and Attenuation of Ultrasonic Waves in Fiber-Reinforced Composites Using the Mass-Spring-Dashpot Lattice Model

  • Baek, Eun-Sol;Yim, Hyun-June
    • Journal of the Korean Society for Nondestructive Testing
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    • v.28 no.6
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    • pp.483-495
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    • 2008
  • The paper presents a numerical study to evaluate the phase velocities and attenuations of the average longitudinal and shear ultrasonic waves resulting from multiple scattering in fiber-reinforced composites. A computational procedure developed in this work is first used to produce a random, yet largely even distribution of fibers. Both the viscoelastic epoxy matrix and lossless randomly distributed graphite fibers are modeled using the mass-spring-dashpot lattice model, with no damping for the latter. By numerically simulating ultrasonic through-transmission tests using this direct model of composites, phase velocities and attenuations of the longitudinal and shear waves through the composite are found as functions of frequency or fiber concentration. The numerical results are observed to generally agree with the corresponding results in the literature. Discrepancies found in some detail aspects, particularly in the attenuation results, are also addressed.

Effects of Humidity and Structure on Friction and Wear Properties of Carbon Fiber/Epoxy Composites (탄소 섬유/에폭시 복합 재료의 마찰 및 마멸 성질에 미치는 습도 및 구조의 영향)

  • 심현해;권오관;윤재륜
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1990.11a
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    • pp.63-68
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    • 1990
  • Friction and wear behavior of a unidirectional high modulus carbon fiber reinforced epoxy composite exposed to high and low humidity was experimentally examined with various sliding speeds. The results show that the moisture at the sliding surface greatly influences friction and wear properties of the composite. It is also discoverd that the difference in friction and wear behavior between samples with different fiber orientations is mainly due to the anisotropic properties caused by the microstructure of oriented graphite crystals in the carbon fibers and the macrostructure of fiber orientation in the matrix.

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Effects of Humidity and Structure on Friction and Wear Properties of Carbon Fiber/Epoxy Composites (탄소 섬유/에폭시 복합 재료의 마찰 및 마멸 성질에 미치는 습도 및 구조의 영향)

  • 심현해;권오관;윤재륜
    • Tribology and Lubricants
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    • v.6 no.2
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    • pp.88-93
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    • 1990
  • Friction and wear behavior of a unidirectional high modulus carbon fiber reinforced epoxy composite exposed to high and low humidity was experimentally examined with various sliding speeds. The results show that the moisture at the sliding surface greatly influences friction and wear properties of the composite. It is also discoverd that the difference in friction and wear behavior between samples with different fiber orientations is mainly due to the anisotropic properties caused by the microstructure of oriented graphite crystals in the carbon fibers and the macrostructure of fiber orientation in the matrix.