• Title/Summary/Keyword: Grain structure

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Solid State Reduction and Magnetic Properties of Iron Oxide-Iron System Induced by Ball Milling Process (볼밀링에 의한 철산화물-철계의 고상 환원반응 및 자기특성)

  • Chung Hyo Lee
    • Korean Journal of Materials Research
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    • v.34 no.6
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    • pp.309-314
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    • 2024
  • The structure and magnetic properties of composite powders prepared by ball milling a mixture of Fe2O3·(0.4-1.0)Fe were investigated. Hysteresis loops and differential scanning calorimetry (DSC) curves are used to characterize the materials and to examine the effect of the solid state reaction induced by ball milling. The results showed that a solid state reaction in Fe2O3·(0.4-1.0)Fe clearly proceeds after only 1 h of ball milling. The system is characterized by a positive reaction heat of +2.23 kcal/mole. The diffraction lines related to Fe2O3 and Fe disappeared after 1 h of ball milling and, instead, diffraction lines of the intermediate phase of Fe3O4 plus FeO formed. The magnetization and coercivity of the Fe2O3·0.8Fe powders were changed by the solid state reaction process of Fe2O3 by Fe during ball milling. The coercivity of the Fe2O3·0.8Fe powders increased with increasing milling time and reached a maximum value of 340 Oe after 5 h of ball milling. This indicates the grain size of Fe3O4 was clearly reduced during ball milling. The magnetic properties of the annealed powders depend on the amount of magnetic Fe and Fe3O4 phases.

Dielectric properties of KTN(80/20) thin films with pzt buffer layer for tunable microwave devices

  • Kyeong-Min Kim;Sam-Haeng Lee;Byeong-Jun Park;Joo-Seok Park;Sung-Gap Lee
    • Journal of Ceramic Processing Research
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    • v.23 no.1
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    • pp.29-32
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    • 2022
  • K(Ta0.80Nb0.20)O3 films with Pb(Zr0.52Ti0.48)O3PZT buffer layer on Pt/Ti/SiO2/Si substrate were fabricated by sol-gel and spin-coating method. Structural and electrical properties were measured with variation of the sintering temperature, and the applicability to microwave materials was investigated. All K(Ta0.80Nb0.20)O3 films showed a cubic crystal structure. Average grain size was about 123~193 nm and average thickness of the K(Ta0.80Nb0.20)O3 films was approximately 366 nm. Through the AFM results, root mean square roughness (Rrms) of all K(Ta0.80Nb0.20)O3 films was around 6 nm. All K(Ta0.80Nb0.20)O3 films showed a tendency to increase dielectric loss as frequency increased. As the sintering temperature increased, tunability with an applied DC voltage indicated a decreasing tendency. Tunability and temperature coefficient of the K(Ta0.80Nb0.20)O3 film sintered at 700 ℃ showed good values of 22.1% at 10 V, -0.594/℃.

Effect of Temperature on the Deposition Rate and Bending Strength Characteristics of Chemical Vapor Deposited Silicon Carbide Using Methyltrichlorosilane (메틸트리클로로실란을 이용한 화학증착 탄화규소의 증착율 및 굽힘강도 특성에 미치는 온도의 영향)

  • Song, Jun-Baek;Im, Hangjoon;Kim, Young-Ju;Jung, Youn-Woong;Ryu, Hee-Beom;Lee, Ju-Ho
    • Composites Research
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    • v.31 no.2
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    • pp.43-50
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    • 2018
  • The effects of deposition temperature on chemical vapor deposited silicon carbide (CVD-SiC) were studied to obtain high deposition rates and excellent bending strength characteristics. Silicon carbide prepared at $1250{\sim}1400^{\circ}C$ using methyltrichlorosilane(MTS : $CH_3SiCl_3$) by hot-wall CVD showed deposition rates of $95.7{\sim}117.2{\mu}m/hr$. The rate-limiting reaction showed the surface reaction at less than $1300^{\circ}C$, and the mass transfer dominant region at higher temperature. The activation energies calculated by Arrhenius plot were 11.26 kcal/mole and 4.47 kcal/mole, respectively. The surface morphology by the deposition temperature changed from $1250^{\circ}C$ pebble to $1300^{\circ}C$ facet structure and multi-facet structure at above $1350^{\circ}C$. The cross sectional microstructures were columnar at below $1300^{\circ}C$ and isometric at above $1350^{\circ}C$. The crystal phases were all identified as ${\beta}$-SiC, but (220) peak was observed from $1300^{\circ}C$ or higher at $1250^{\circ}C$ (111) and completely changed to (220) at $1400^{\circ}C$. The bending strength showed the maximum value at $1350^{\circ}C$ as densification increased at high temperatures and the microstructure changed from columnar to isometric. On the other hand, at $1400^{\circ}C$, the increasing of grain size and the direction of crystal growth were completely changed from (111) to (220), which is the closest packing face, so the bending strength value seems to have decreased.

Study on the Community Structure of Meiofauna in Marian Cove, King George Island, Antarctica (남극 King George Islands, Marian Cove의 중형저서생물 군집 구조에 관한 연구)

  • Bang Hyun Woo;Kang Sung-Ho;Lee Wonchoel
    • Korean Journal of Environmental Biology
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    • v.23 no.2 s.58
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    • pp.191-199
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    • 2005
  • The community structure, vertical distribution and harpacticoids composition of the meiofauna community were observed from five stations in Marian Cove, King George Island and one station on the northeastern side of Nelson Island. Sample was taken by a free-fall corer in December 2002. Generally, 11 taxa of meiofauna were found, and meiofauna abundance ranged from 322 to 1575 indiv. $10cm^{-2}$ (mean 781 indiv. $10cm^{-2}$). Nematodes were the most dominant group, making up $89\%$ of total meiofauna, followed by harpacticoids $(6.8\%)$. Benthic harpacticoids appeared 19 species of nine families at all the stations, and most various taxa appeared at station B (13 species of seven families). For vertical distribution, more than $70\%$ of meiofauna was concentrated in the upper $0\~2cm$ sediment layers, and the density abruptly decreased with depth in all the stations. Total biomass of meiofauna varied between 41 and $360{\mu}gC\;10cm^{-2}$, and overall mean biomass was $205{\mu}gC\;10cm^{-2}$. Also nematodes had the highest percentage of total maiofauna biomass $(62.4\%)$. The analysis results of Canonical Correspondence Analysis between meiofauna community and sediment grain size showed that polychaets, oligochaets and cumaceans were influenced by silt&cray, and sand, granule and pebble had a influence on harpacticoids, kinorhynchs and ostracods respectively. But nematodes were not affected by sediment grain size.

Fabrication and Characterization of $CuInSe_2$Thin Films from $In_2Se_3$ and$Cu_2Se$Precursors ($In_2Se_3$$Cu_2Se$를 이용한 $CuInSe_2$박막제조 및 특성분석)

  • Heo, Gyeong-Jae;Gwon, Se-Han;Song, Jin-Su;An, Byeong-Tae
    • Korean Journal of Materials Research
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    • v.5 no.8
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    • pp.988-996
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    • 1995
  • CuInSe$_2$this films as a light absorber layer were fabricated by vacuum evaporation using In$_2$Se$_3$and Cu$_2$Se precursors and their properties were analyzed. Indium selenide films of 0.5${\mu}{\textrm}{m}$ thickness were first deposited by vacuum evaporation of In$_2$Se$_3$ on a Corning 7059 glass substrate. The films deposited at suscepor temperature of 40$0^{\circ}C$ showed a flat surface morphology with densely Packed grain structure. CuInSe$_2$films directly formed by evaporating Cu$_2$Se on the predeposited In$_2$Se$_2$films also showed a very flat surface when the susceptor temperature was $700^{\circ}C$. Cu$_2$Se, a second phase in the CuInSe$_2$film, was removed by evaporating additional In$_2$Se$_3$on the CuInSe$_2$film at $700^{\circ}C$. The grain size of 1.2${\mu}{\textrm}{m}$ thick CuInSe$_2$, film was about 2${\mu}{\textrm}{m}$ and the film had a (112) preferred orientation. As the amount of deposited In$_2$Se$_3$increased, the electrical resistivity of CuInSe$_2$films increased because of the decrease of hole concentration. But the optical band gap was almost constant at the value of 1.04eV, The CuInSe$_2$film grown on a Mo/glass substrate had a similar smooth microstructure compared to that on a glass substrate. A solar cell with ZnO/CdS/CuInSe$_2$/Mo structure may be realized based on the above CuInSe$_2$films.

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Spatio-temporal Distribution of Macrozoobenthos in the Three Estuaries of South Korea (우리나라 3개 하구역 대형저서동물 군집 시공간 분포)

  • LIM, HYUN-SIG;LEE, JIN-YOUNG;LEE, JUNG-HO;SHIN, HYUN-CHUL;RYU, JONGSEONG
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.24 no.1
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    • pp.106-127
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    • 2019
  • This study aims to understand spatio-temporal variations of macrozoobenthos community in Han River (HRE), Geum River (GRE), and Nakdong River estuaries (NRE) of Korea, sampled by National Survey of Marine Ecosystem. The survey was seasonally performed at a total of 20 stations for three years (2015-2017). Sediment samples were taken three times with van Veen grab of $0.1m^2$) areal size and sieved through a 1 mm pore size mesh on site. A total of 1,008 species were identified with 602 species in HRE, 612 in GRE, and 619 in NRE, showing similar number of species between estuaries. Mean density was $1,357ind./m^2$, showing the high in NRE ($1,357ind./m^2$), mid in GRE ($1,357ind./m^2$), and low in HRE ($1,127ind./m^2$). Mean biomass was $116.8g/m^2$, showing similar variations to density ($174.2g/m^2$ in NRE, $129.0g/m^2$ in GRE, $49.0g/m^2$ in HRE). Polychaeta dominated in number of species and density in three estuaries. Biomass-dominated taxon was Mollusca in HRE and GRE, and Echinodermata in NRE. Polychaetous species dominated all three estuaries over 4% of density, such as Dispio oculata, Heteromastus filiformis and Aonides oxycephala in HRE, Heteromastus filiformis and Scoletoma longifolia in GRE, and Pseudopolydora sp. and Aphelochaeta sp. in NRE, showing various density between estuaries. Community structure was determined by various environmental variables among estuaries such as mean grain size and sorting (HRE), salinity and mean grain size (GRE), and salinity, dissolved oxygen, loss on ignition and mud content (NRE). Our study demonstrates the application of different measures to manage ecosystems in three estuaries. HRE needs to alleviate sedimentary stressors such as sand mining, land-filling, dike construction. Management of GRE should be focused on fresh water control and sedimentary stressors. In NRE, monitoring of dominant benthos and process study on hypoxia occurrence in inner Masan Bay are necessary.

Seasonal Fluctuation of Meiobenthic Fauna Community at Keunso Tidal Flat in Taean, Korea (서해안 태안 근소만 갯벌에 서식하는 중형저서동물 군집의 계절 변동)

  • SHIN, AYOUNG;KIM, DONGSUNG;KANG, TEAWOOK;OH, JE HYEOK;LEE, JIMIN;HONG, JAE-SANG
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.21 no.4
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    • pp.144-157
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    • 2016
  • The community structure of meiobenthos was investigated from seasonal surveys at four stations of Keunso Bay in Taean. Samples of meiobenthos were collected in August, October, 2013 and January, April, 2014. Triplicate faunal samples were collected by using an acryl corer with a 3.6 cm diameter at each station. The mean grain size of the study area ranged from 3.65 ø to 6.35 ø. Total 13 meiofaunal groups were found in the study area. The total density of meiobenthos at each station was be $1,521-7,849ind./10cm^2$. Nematodes were the most dominant faunal group at all stations. The subdominant group were Sarcomastigophorans and benthic harpacticoid copepods. The highest meiofaunal density was shown in spring, whereas the lowest density was recorded in summer. A total of 13 meiobenthic taxa were found, the richest taxa in October at station 2 ($13ind./10cm^2$), and the lowest in April at station 4 ($5ind./10cm^2$). There were seasonal fluctuations in the number of meiobenthic taxa decreasing from summer to spring. The density of meiobenthos gradually decreased as the depth of sediment increased. Seasonal changes in the vertical distribution of meiobenthos in the study area occurred mainly near the sediment surface.

The Effect of Titaniuml Surface Treatment on Osteoblast-Like Cell Attachment and Proliferation (Titanium 표면처리 방법이 Osteoblast-like Cells의부착 및 증식에 미치는 영향)

  • Kim, Do-Yung;Seol, Yang-Jo;Rhyu, In-Cheul;Hahm, Byung-Do;Chung, Chong-Pyoung;Choi, Sang-Mook;Kim, Woo-Jin;Baik, Hong-Koo;Heo, Seong-Joo;Han, Chong-Hyun;Kim, Myung-Ho;Choi, Yong-Chang;Chun, Heoung-Jae;Kwon, Soo-Kyoung
    • Journal of Periodontal and Implant Science
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    • v.30 no.3
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    • pp.491-504
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    • 2000
  • In clinical therapy, the current goal of dental implants is to enhance quantity and quality of osseointegration. Surface roughness and oxide structure are considered to influence the behavior of adherent cells. The purpose of this study is to evaluate the effect of different surface treatment on cellular response. The attachment and proliferation of osteoblast-like cell on sandblasted, sandblasted and etched, thermal oxidated surfaces have been compared. Sandblasting was done with $Al_2O_3$ particles(grain size of $50{\mu}m$), etching was processed with $NH_4OH$ : $H_2O_2$ : $H_2O(1:1:5)$ at $90^{\circ}C$ for 1 minute. Thermal oxidation was followed sandblasting and etching at $400^{\circ}C$, $600^{\circ}C$, $800^{\circ}C$ for 2 hours. Measurement of surface roughness after the different treatment did not show any differences of Ra value between terated surfaces. Cell attachment and proliferation were increased during experiment period, but no difference was observed. SEM evaluation revealed a similar pattern of osteoblast-like cells, well attached with dendritic extension and producing numerous matrix vesicles on cell surface. The results of this study showed that oxide layer alteration by thermal oxidation did not affect the attachment and proliferation of osteoblast-like cells. This suggests the possibility that the cellular responses are further influenced by surface roughness than titaniun oxide structure.

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Variation of Meiobenthic Community in the Sediment of Coastal Area in Bangameori Daebudo, Korea (대부도 방아머리 연안 퇴적물에 서식하는 중형저서동물 군집 변동)

  • 김동성;민원기;이재학
    • Korean Journal of Environmental Biology
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    • v.22 no.2
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    • pp.308-320
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    • 2004
  • The Community structure of meiobenthos was studied seasonally at 5 stations of Bangameori tidal flat and 3 stations of subtidal area in Daebudo near the Shiwha dike in the west coast of Korea, from May 2000 to February 2001. Mean grain size of intertidal stations ranged from $3.16\;\varphi\;to\;3.73\varphi$ (sand), subtidal stations were $5.81~6.67\;\varphi$ (mud). Nematodes were the most dominant group among the representative 19 meiofaunal groups at all stations in both tidal flat and sub-tidal area. The subdominant groups were benthic harpacticoid copepods and Sarcomastigophorans. The density of meiobenthos ranged from 145 inds. $10cm^{-2}$ to 2,057 inds. $10cm^{-2}$ (0~1 cm) in the sediment of intertidal stations, and from 391 to 3,787 inds. $10cm^{-2}$ (0~5 cm) in the subtidal stations. The lowest meiofaunal density was recorded in winter, whereas the highest density was shown in spring. Comparing with another previous work at the same area, data from this study does not statistically shown differences with results before discharge of shiwha lake water.

Effect of Canopy Structure on Paddy Yield in Relation to Nutrient Uptake (수도(水稻)의 군락(群落) 및 양분(養分) 흡수(吸收)가 수량(收量)에 미치는 영향)

  • Kwon, Hang Gwang;Kim, Yung Sup;Park, Jung Kew
    • Korean Journal of Soil Science and Fertilizer
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    • v.5 no.1
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    • pp.33-39
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    • 1972
  • For the increase of productivity, canopy structure and nutritional status in various productivity grades (high>700, medium>600 and low>500kg/l0a as head rice) were investigated in a study using Jinheung(Oryza sativa L.) for the increase of producticity with following results: 1. High yield plot showed greater leaf area and slow decrease of it after heading stage. While low yield plot had rapidly decrease of leaf area. 2. High yield plot showed higher light transmission ratio (LTR) durnig early grow stage, low LTR. during late grow stage, and higher leaf area per LTR. 3. Net assimilation ratio was decrease with the increase of leaf area index (LAI) and it was always higher in high yield plot. 4. High yield plant had greater amount of total nitrogen uptake, slow uptake rate, and considerable uptake after heading while low yield plant showed higher uptake of nitrogen in early stage of growth and no uptake after heading. 5. The percent ratio starch at heading to total at harvesting was 40% for low yield plant and 10% for highyield plant inderting that high yield depends much on past-heading starch synthesis. 6. Main factor determining secondary yield was ripened grain ratio.

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