• Title/Summary/Keyword: Grain sizes

Search Result 446, Processing Time 0.025 seconds

Photoluminescence Characteristics of $Y_3Al_5O_{12}:Eu^{3+}$ Nano-Phosphors by Combustion Method (연소합성법으로 제작한 $Y_3Al_5O_{12}:Eu^{3+}$ 나노형광체의 광학적 특성)

  • Kwak, Hyun-Ho;Kim, Se-Jun;Park, Yong-Seo;Choi, Hyung-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.11a
    • /
    • pp.406-407
    • /
    • 2008
  • For this study, Yttrium aluminum garnet (YAG) particles doped $Eu^{3+}$ ions were prepared via the combustion process using the 1:1 ratio of metal ions to reagents. The characteristics of the synthesized nano powder were investigated by means of X-ray diffraction (XRD), Scanning Electron Microscope (SEM), and photoluminescence (PL). The various YAG peaks, with the (420) main peak, appeared at all sintering temperature XRD patterns. The YAG phase crystallized with results that are in good agreement with the JCPDS diffraction file 33-0040. The SEM image showed that the resulting YAG:Eu powders had larger sizes with the increse in the sintering temperature. The grain size was about 50nm at $1000^{\circ}C$. The PL intensity of $Eu^{3+}$ has the line peaks of 598, 610, 632nm and has main peak at 591nm.

  • PDF

Impact of Biochar Particle Shape and Size on Saturated Hydraulic Properties of Soil

  • Lim, Tae-Jun;Spokas, Kurt
    • Korean Journal of Environmental Agriculture
    • /
    • v.37 no.1
    • /
    • pp.1-8
    • /
    • 2018
  • BACKGROUND: Different physical and chemical properties of biochar, which is made out of a variety of biomass materials, can impact water movement through amended soil. The objective of this research was to develop a decision support tool evaluating the impact of the shape and the size distribution of biochar on soil saturated hydraulic conductivity ($K_{sat}$). METHODS AND RESULTS: Plastic beads of different size and morphology were compared with biochar to assess impacts on soil $K_{sat}$. Bead and biochar were added at the rate of 5% (v/w) to coarse sand. The particle size of bead and biochar had an effect on the $K_{sat}$, with larger and smaller particle sizes than the original sand grain (0.5 mm) decreasing the $K_{sat}$ value. The equivalent size bead or biochar to the sand grains had no impact on $K_{sat}$. The amendment shape also influenced soil hydraulic properties, but only when the particle size was between 3-6 mm. Intra-particle porosity had no significant influence on the $K_{sat}$ due to its small pore size and increased tortuosity compared to the inter-particle spaces (macro-porosity). CONCLUSION: The results supported the conclusion that both particle size and shape of the amended biochar impacted the $K_{sat}$ value.

Exploit the Unexploited : the Potential of the PAH 3.3mm emission feature as a star formation rate proxy and beyond

  • Kim, Ji-Hoon;Im, Myung-Shim;Lee, Hyung-Mok;Lee, Myung-Gyoon;AMUSES team, AMUSES team
    • The Bulletin of The Korean Astronomical Society
    • /
    • v.35 no.2
    • /
    • pp.40.2-40.2
    • /
    • 2010
  • Polycyclic aromatic hydrocarbon (PAH) features have emerged as one of the most important infrared (IR) features since these PAH features dominate mid-IR spectra of galaxies and are ubiquitous within galactic and extragalactic objects. These PAH features have the potentials to become reliable star formation rate (SFR) proxies and diagnostics of physical conditions of interstellar medium, such as ionization states of dust grains and grain sizes. While constructing an unbiased library of 44 sample galaxies selected from 5MUSES sample, AKARI mJY Unbiased Survey of Extragalactic Sources in 5MUSES (AMUSES) intends to measure and to calibrate the PAH 3.3 mm emission feature which has not been studied extensively due to its weak strength and dearth of capable instruments. Out of 20 target galaxies, we detected the 3.3mm feature from eight galaxies and measured their line strengths, line widths and line ratios with other PAH emission features. Sample galaxies whose spectral energy distributions (SEDs) are classified as starburst-type have clearly stronger 3.3mm emission features than ones with AGN-type SEDs. We also found that there is a correlation between the PAH 3.3mm luminosity and total IR luminosity within our sample galaxies, albeit a large scatter. We further discuss implications of our results.

  • PDF

Effects of Mo Addition on the Microstructures and Mechanical Properties of $Al_2O_3$ Ceramics (Mo첨가가 $Al_2O_3$ 세라믹스의 미세구조 및 기계적 성질에 미치는 영향)

  • 박정현;문성환;백승수;정동익
    • Journal of the Korean Ceramic Society
    • /
    • v.25 no.3
    • /
    • pp.201-206
    • /
    • 1988
  • To investigate the effects of Mo addition on the microstructures and mechanical properties of Al_2O_3$ ceramics, two kinds of Mo particles with average sizes of 2-${\mu}{\textrm}{m}$ and 6-${\mu}{\textrm}{m}$ were used as additives. It was shown that Mo particles inhibited the grain growth of Al_2O_3$, and the smaller Mo particles were more effective. In case of 2-${\mu}{\textrm}{m}$ Mo dispersion, the bending strength and the fracture toughness were increased. Dispersion of 6-${\mu}{\textrm}{m}$ MO did not increase the strength but improved the fracture toughness a little. The toughening mechanisms of Al_2O_3$-Mo composites are thought to be the crack deflection and microcracking mechanisms.

  • PDF

Green and Hard Machining Characteristics of Zirconia-alumina Composites for Dental Implant (치과 임플란트용 지르코니아-알루미나 복합체의 생 가공 및 경 가공 특성)

  • Lim, Hyung-Bong;Tang, Dongxu;Lee, Ki-Ju;Cho, Won-Seung
    • Journal of the Korean Ceramic Society
    • /
    • v.48 no.2
    • /
    • pp.152-159
    • /
    • 2011
  • The green and hard machining characteristics of dental ceramics are of great interest to dental industry. The green bodies of TZP/$Al_2O_3$ composites were prepared by the cold isostatic pressing, and machined on the CNC lathe using PCD (polycrystalline diamond) insert under various machining conditions. With increasing nose radius of PCD insert, surface roughness initially increased due to increased cutting resistance, but decreased by the onset of sliding fracture. The lowest surface roughness was obtained at spindle speed of 1,300 rpm and lowest feed rate. Hard bodies were prepared by pressureless sintering the machined green bodies at several temperatures. The grinding test for sintered hard body was conducted using electroplated diamond bur with different grit sizes. During grinding, grain pull out in the composite was occurred due to thermal expansion mismatch between the alumina and zirconia. The strength of the composite decreased with alumina contents, due to increased surface roughness and high monoclinic phase transformed during grinding process. The final polished samples represented high strength by the elimination of a phase transformation layer.

Effect of milling on the electrical properties of Ba(Fe1/2Ta1/2)O3 ceramic

  • Mahto, Uttam K.;Roy, Sumit K.;Chaudhuri, S.;Prasad, K.
    • Advances in materials Research
    • /
    • v.5 no.3
    • /
    • pp.181-192
    • /
    • 2016
  • In this work effect of high energy milling on the structural and electrical properties of $Ba(Fe_{1/2}Ta_{1/2})O_3$ (BFT) ceramic synthesized using standard solid-state reaction method were investigated. X-ray diffraction studies indicated that the unit cell structure for all the samples to be hexagonal (space group: P3m1). FTIR spectra also confirmed the formation of BFT without any new phase. The milled (10 h) BFT ceramic showed the formation of small grain sizes (<$2{\mu}m$) which is beneficial for dielectric applications in high density integrated devices. Besides, the milled (10 h) BFT ceramic sample exhibited superior dielectric properties (enhancement in ${\varepsilon}^{\prime}-value$ and reduction in $tg{\delta}-value$) compared to un-milled one. Impedance analysis indicated the negative temperature coefficient of resistance (NTCR) character. The correlated barrier hopping model (jump relaxation type) is found to successfully explain the mechanism of charge transport in present ceramic samples.

Quality Improvement of Concrete Depending on the Mixing of Fine Aggregates Different Compositions and Grain Sizes (성분 및 입도분포가 다른 잔골재의 혼합에 의한 콘크리트의 품질향상)

  • Kim, Young-Hee;Park, Min-Yong;Kim, Jung-Bin;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2012.05a
    • /
    • pp.77-79
    • /
    • 2012
  • This study is to assess the differences between concrete having only one of fine aggregates such as crushed fine aggregates, sea sand and blast furnace slag in it and concrete having mixture of two kinds of those fine aggregates in it in order to find out how to deal with the lack of some aggregates. The findings are as follows. In terms of slump, the concrete containing sea sand and blast furnace slag has very low slump values while the concrete having the mixture of crushed fine aggregate and the other fine aggregates showed better workability. In terms of compressive strength, the concrete containing the mixture of two kinds of aggregates showed higher compressive strength. Accordingly, it is likely that the concrete containing the mixture of crushed fine aggregate, sea sand and blast furnace slag is better than the concrete with only one kind of fine aggregates in terms of the usability.

  • PDF

Dielectric Properties of $BaTiO_3$ System Ceramics for Microwave Phased Shifter (위상 변위기용 $BaTiO_3$계 세라믹의 유전특성)

  • Lee, Sung-Gap;Park, Sang-Man;Park, In-Gil;Lim, Sung-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2002.05c
    • /
    • pp.79-82
    • /
    • 2002
  • $(Ba_{0.6-x}Sr_{0.4}Ca_x)TiO_3$ + ywt% MgO (x=0.10, 0.15, 0.20, y=0.0~3.0) ceramics were fabricated by the conventional solid-state reaction, and their structural and dielectric properties were investigated with variation of composition ratio and MgO doping content. A second phase, representative of MgO, appears in 3wt% MgO-doped BSCT specimens. Average grain sizes decreased with increasing amounts of MgO, and the BSCT(40/40/20) specimens doped with 3wt% MgO showed a value of $9.3{\mu}m$. The Curie temperature and relative dielectric constant at room temperature were decreased with increasing MgO doping content and Ca composition ratio. The relative dielectric constant was non-linearly decreased as the field strength is increased. The tunability was increased with decreasing a Ca content and the BSCT(50/40/10) specimen doped with 1.0wt% MgO content showed the highest value of 6.4% at 5kV/cm.

  • PDF

Electrochemistry Characteristics of $Li_4Ti_5O_{12}$ Anode Electrode for Li-ion Battery (리튬전지용 $Li_4Ti_5O_{12}$ 음극전극의 전기화학적 특성)

  • Oh, Mi-Hyun;Kim, Han-Joo;Kim, Young-Jae;Son, Won-Keun;Lim, Kee-Joe;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2005.11a
    • /
    • pp.340-341
    • /
    • 2005
  • Lithium titanium oxide as anode material for energy storage prepared by novel synthesis method. $Li_4Ti_5O_{12}$ based spinel-framework structures are of great interest material for lithium-ion batteries. We describe here $Li_4Ti_5O_{12}$ a zero-strain insertion material was prepared by novel sol-gel method and by high energy ball milling (HEBM) of precursor to from nanocrystalline phases. According to the X-ray diffraction and scanning electron microscopy analysis, uniformly distributed $Li_4Ti_5O_{12}$ particles with grain sizes of 100nm were synthesized. Lithium cells, consisting of $Li_4Ti_5O_{12}$ anode and lithium cathode showed the 173 mAh/g in the range of 1.0 $\sim$ 3.0 V. Furthermore, the crystalline structure of $Li_4Ti_5O_{12}$ didn't transfer during the lithium intercalation and deintercalation process.

  • PDF

OPTIMAL SPUTTERING CONDITIONS FOR HIGH-DENSITY MAGNETIC RECORDING MEDIA BY FTS

  • Noda, Kohki;Kawanabe, Takashi;Naoe, Masahiko
    • Journal of the Korean institute of surface engineering
    • /
    • v.29 no.6
    • /
    • pp.824-828
    • /
    • 1996
  • Co-based alloy thin films ddeposited by fcing targets sputtering(FTS) were investigated for use in high-density magnetic recording media to determine how their magnetic properties are dependent on the sputtering conditions, and thus to find appropriate parameters that allow the sputtering and thin films to meet the specificiations for magnetic properties. FTS can discharge at lower working gas pressure than other sputtering methods such as dcmagnetron sputteing because the plasma is sufficiently confined by a magnetic field applied perpendicular to both of the target planes, which results in plasma-free substrates. Co-Cr-Ta films were deposited by FTS on glass and silicon substrates at substrate temperature between room temperature and $350^{\circ}C$, and at argon gas pressure between 0.1 and 10mTorr. The films were also deposited on polyimide tapes at substrate temperature of $130^{\circ}C$ and argon gas pressure of 1 mTorr. The effective advantages of Ta as an additional element were investigated, using the same films on the tapes. As a result of the experiment, it was found that better magnetic properties were obtained in the ranges of higher temperature and lower argon gas pressure with background pressure in thr range of $1.5 \times 10^{-6}$ Torr. Ta addition at 2 to 4 atomic percent almost havled the Co-Cr grain sizes, indicating that Ta addition at an appropriate atomic percent is effective for improving the microstructure and characteristics of Co-Cr films.

  • PDF