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Two-dimensional modelling of uniformly doped silicene with aluminium and its electronic properties

  • Chuan, M.W.;Wong, K.L.;Hamzah, A.;Rusli, S.;Alias, N.E.;Lim, C.S.;Tan, M.L.P.
    • Advances in nano research
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    • v.9 no.2
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    • pp.105-112
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    • 2020
  • Silicene is a two-dimensional (2D) derivative of silicon (Si) arranged in honeycomb lattice. It is predicted to be compatible with the present fabrication technology. However, its gapless properties (neglecting the spin-orbiting effect) hinders its application as digital switching devices. Thus, a suitable band gap engineering technique is required. In the present work, the band structure and density of states of uniformly doped silicene are obtained using the nearest neighbour tight-binding (NNTB) model. The results show that uniform substitutional doping using aluminium (Al) has successfully induced band gap in silicene. The band structures of the presented model are in good agreement with published results in terms of the valence band and conduction band. The band gap values extracted from the presented models are 0.39 eV and 0.78 eV for uniformly doped silicene with Al at the doping concentration of 12.5% and 25% respectively. The results show that the engineered band gap values are within the range for electronic switching applications. The conclusions of this study envisage that the uniformly doped silicene with Al can be further explored and applied in the future nanoelectronic devices.

Development of a Performance Prediction Method for Centrifugal Compressor Channel Diffusers

  • Kang, Jeong-Seek;Cho, Sung-Kook;Kang, Shin-Hyoung
    • Journal of Mechanical Science and Technology
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    • v.16 no.8
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    • pp.1144-1153
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    • 2002
  • A hybrid performance prediction method is proposed in the present study. A channel diffuser is divided into four subregions: vaneless space, semi-vaneless space, channel, and channel exit region. One-dimensional compressible core flow and boundary layer calculation of each region with an incidence loss model and empirical correlation of residuary pressure recovery coefficient of a channel predict the performance of diffusers. Three channel diffusers are designed and tested for validating the developed prediction method. The pressure distributions from an impeller exit to the channel diffuser exit are measured and discussed for various operating conditions from choke to nearly surge conditions. The strong non-uniform pressure distribution which is caused by impeller-diffuser interaction is obtained over the vaneless and semi-vaneless spaces. The predicted performance shows good agreement with the measured performance of diffusers at a design condition as well as at off-design conditions.

A Model-based 3-D Pose Estimation Method from Line Correspondences of Polyhedral Objects

  • Kang, Dong-Joong;Ha, Jong-Eun
    • 제어로봇시스템학회:학술대회논문집
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    • 2003.10a
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    • pp.762-766
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    • 2003
  • In this paper, we present a new approach to solve the problem of estimating the camera 3-D location and orientation from a matched set of 3-D model and 2-D image features. An iterative least-square method is used to solve both rotation and translation simultaneously. Because conventional methods that solved for rotation first and then translation do not provide good solutions, we derive an error equation using roll-pitch-yaw angle to present the rotation matrix. To minimize the error equation, Levenberg-Marquardt algorithm is introduced with uniform sampling strategy of rotation space to avoid stuck in local minimum. Experimental results using real images are presented.

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A Study on FEM Application in PIC Plasma Simulation (PIC 플라즈마 시뮬레이션에서의 유한요소법 적용에 관한 연구)

  • Min, Woong-Kee;Kim, Hyeong-Seok;Lee, Seok-Hyun;Hahn, Song-Yop
    • Proceedings of the KIEE Conference
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    • 1996.07a
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    • pp.163-165
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    • 1996
  • In the PIC simulation of plasma, the fields are commonly calculated on uniform spatial grids using FDM. But, FDM has a difficulty in modeling a complex shaped model. FEM has a good flexibiblity in treating a complex shape, so that we calculated the field by using FEM not FDM. In this paper, the plasma between plane-to-plane electrodes was simulated using FEM and FDM. Comparing the results of those two methods told us that FEM is also valid as a calculating method in PIC plasma simulation. In order to verify the use of FEM, the discharge of rod-to-plane was simulated. There was not a little distortion of the electric field between the electrodes due to the distribution of space charges.

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Ni-P Coated Sn Powders as Anode for Lithium Secondary Batteries

  • Jo, Yong-Nam;Im, Dong-Min;Kim, Jae-Jung;Oh, Seung-M.
    • Journal of the Korean Electrochemical Society
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    • v.10 no.2
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    • pp.88-93
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    • 2007
  • Nano-sized Sn particles were coated with Ni-P layer using an electroless deposition method and their anodic performance was tested for lithium secondary batteries. Uniform coating layers were obtained, of which the thickness was controlled by varying the $Ni^{2+}$ concentration in the plating bath. It was found that the Ni-P layer plays two important roles in improving the anodic performance of Sn powder electrode. First, it prevents the inter-particle aggregation between Sn particles during the charge/discharge process. Second, it provides an electrical conduction pathway to the Sn particles, which allows an electrode fabrication without an addition of conductive carbon. A pseudo-optimized sample showed a good cyclability and high capacity ($>400mAh\;g^{-1}$) even without conductive carbon loading.

Application of machine learning in optimized distribution of dampers for structural vibration control

  • Li, Luyu;Zhao, Xuemeng
    • Earthquakes and Structures
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    • v.16 no.6
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    • pp.679-690
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    • 2019
  • This paper presents machine learning methods using Support Vector Machine (SVM) and Multilayer Perceptron (MLP) to analyze optimal damper distribution for structural vibration control. Regarding different building structures, a genetic algorithm based optimization method is used to determine optimal damper distributions that are further used as training samples. The structural features, the objective function, the number of dampers, etc. are used as input features, and the distribution of dampers is taken as an output result. In the case of a few number of damper distributions, multi-class prediction can be performed using SVM and MLP respectively. Moreover, MLP can be used for regression prediction in the case where the distribution scheme is uncountable. After suitable post-processing, good results can be obtained. Numerical results show that the proposed method can obtain the optimized damper distributions for different structures under different objective functions, which achieves better control effect than the traditional uniform distribution and greatly improves the optimization efficiency.

Nucleation and Growth of Bismuth Electrodeposition from Alkaline Electrolyte

  • Zhou, Longping;Dai, Yatang;Zhang, Huan;Jia, Yurong;Zhang, Jie;Li, Changxiong
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1541-1546
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    • 2012
  • The early stages of bismuth (Bi) electrodeposition on glass carbon electrode from alkaline electrolyte were studied by cyclic voltammetry, chronoamperometry, scanning electron microscopy, atomic force microscopy and X-ray diffraction. The CV analysis showed that the electrodeposition of Bi was determined to be quasireversible process with diffusion controlled. The current transients for Bi electrodeposition were analyzed according to the Scharifker-Hills model and the Heerman-Tarallo model. It can be concluded that the nucleation and growth mechanism was carried out under a 3D instantaneous nucleation, which was confirmed by SEM analysis. The kinetic growth parameters were obtained through a nonlinear fitting. In addition, the Bi film obtaining at -0.86 V for 1 hour was of compact and uniform surface with good smoothness, small roughness and a very high purity. The Bi film were indexed to rhombohedral crystal structure with preferred orientation of (0 1 2) planes to growth.

Adsorptive removal of Ni(II) ions from aqueous solution by PVDF/Gemini-ATP hybrid membrane

  • Zhang, Guifang;Qin, Yingxi;Lv, Chao;Liu, Xingtian;Zhao, Yiping;Chen, Li
    • Membrane and Water Treatment
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    • v.7 no.3
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    • pp.209-221
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    • 2016
  • As a highly hydrophilic fibrillar mineral in nature, attapulgite (ATP) is a promising new additive for preparation of ultrafiltration (UF) hybrid membrane. In this work, ATP particles, which were grafted with a new Gemini surfactant of Ethyl Stearate-di(octadecyl dimethyl ammonium chloride) to detach the crystal bundles to single crystal and enhance the uniform dispersion in an organic polymer matrix, were incorporated into poly(vinylidene fluoride) (PVDF) matrix, and PVDF/Gemini-ATP hybrid membranes for adsorptive removal of Ni(II) ions from aqueous solution were prepared via a phase inversion method. Chemical composition, crystalization and morphology of the modified ATP were characterized by Fourier transform infrared spectroscopy (FTIR), Transmission electron microscope (TEM) and X-ray diffraction (XRD), respectively. The morphology of the hybrid membrane was characterized by Scanning electron microscopy (SEM), the performance of permeability, hydrophilicity and adsorption of Ni(II) ions were studied, and the adsorption kinetics of the PVDF/ATP hybrid membranes were particular concerned. The results showed that the hybrid membrane displayed a good thermal stability and hydrophilicity. Comparing with PVDF membrane, the hybrid membrane possessed good adsorption capacity for Ni(II) ions, and the adsorption kinetics fit well with Lagergren second-order equation.

Analysis of Vibration for the Pre-twisted Beam Considering the Effect of Rotary Inertia Using the Transfer Matrix Mathod (전달행렬법을 이용하여 비틀림 각과 회전관성을 고려한 보의 진동해석)

  • Lee, Jung Youn
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.26 no.2
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    • pp.217-224
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    • 2016
  • In this study, a transfer matrix method (TMM) for a twisted uniform beam considering the effect of rotary inertia is developed, and the differential equation and the displacements and forces are derived from Hamilton's principle. The particular transfer matrix is derived by applying the distributed mass and transcendental function while using a local coordinate system. In addition, the results obtained from this method are independent for a number of subdivided elements, and this method can determine the exact solutions for the free vibration characteristics of a twisted uniform Rayleigh beam. To validate the accuracy of the proposed TMM, the computed results are compared with those reported in the existing literature, and the comparison results indicate notably good agreement. In addition, the method is used to investigate the effects of rotary inertia for a twisted beam.

A FAST AND ROBUST NUMERICAL METHOD FOR OPTION PRICES AND GREEKS IN A JUMP-DIFFUSION MODEL

  • JEONG, DARAE;KIM, YOUNG ROCK;LEE, SEUNGGYU;CHOI, YONGHO;LEE, WOONG-KI;SHIN, JAE-MAN;AN, HYO-RIM;HWANG, HYEONGSEOK;KIM, HJUNSEOK
    • The Pure and Applied Mathematics
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    • v.22 no.2
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    • pp.159-168
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    • 2015
  • Abstract. We propose a fast and robust finite difference method for Merton's jump diffusion model, which is a partial integro-differential equation. To speed up a computational time, we compute a matrix so that we can calculate the non-local integral term fast by a simple matrix-vector operation. Also, we use non-uniform grids to increase efficiency. We present numerical experiments such as evaluation of the option prices and Greeks to demonstrate a performance of the proposed numerical method. The computational results are in good agreements with the exact solutions of the jump-diffusion model.