• 한국전기전자재료학회논문지
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• 제18권6호
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• pp.560-570
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• 2005

In this paper, a microelectrode away DNA chip was fabricated on glass slide using photolithography technology. Several probe DNAs consisting of mercaptohexyl moiety at their 5' end were immobilized on the gold electrodes by DNA arrayer utilizing the affinity between gold and sulfu. Then target DNAs were hybridized and reacted with Hoechst 33258, which is a DNA minor groove binder and electrochemically active dye. Cyclic voltammetry in 5mA ferricyanide/ferrocyanide solution at 100 mV/s confirmed the immobilization of probe DNA on the gold electrodes. Linear sweep voltammetry or cyclic voltammetry showed a difference between target DNA and control DNA in the anodic peak current values. It was derived from Hoechst 33258 concentrated at the electrode surface through association with formed hybrid. It suggested that this DNA chip could recognize the sequence specific genes. It suggested that multichannel electrochemical DNA microarray is useful to develop a portable device for clinical gene diagnostic system.

• 한국초전도저온공학회:학술대회논문집
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• 한국초전도저온공학회 2000년도 KIASC Conference 2000 / 2000년도 학술대회 논문집
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• pp.139-142
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• 2000

We fabricated resistive superconducting fault current limiters based on $YBa_{2}Cu_{3}O_{7}$ thin films and investigated position dependence of quench progress. The $YBa_{2}Cu_{3}O_{7}$ film was coated insitu with a gold layer and patterned into 1 mm wide meander lines by photolithography. The limiters were tested with simulated fault currents. Quench progress depended significantly on the position in the limiter with respect to electrodes. The limiters quenched fastest at the part farthest from the electrodes. the limiters quenched fastest at the part farthest from the electrodes and slowest next to the electrodes. This phenomenon was more prominent near the minimum quench current. At high fault current the quench started simultaneously on all parts of the limiters and the subsequent progress of quench depended only weakly on the position. The heat transfer from limiter meander lines to electrodes explains these results.

• Journal of Electrochemical Science and Technology
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• 제8권1호
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• pp.25-34
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• 2017

Concurrent electrocatalysis and sensing of hydrazine, sulfite ions, and nitrite ions in a mixture were studied using electrodes modified by electrodeposited Au nanostructures (NSs). The ${\beta}$-cyclodextrin-mixed silicate sol-gel composite was drop-casted on the electrode surface and nucleation guided by ${\beta}$-cyclodextrin occurred, followed by the electrodeposition of Au NSs. The additive, ${\beta}$-cyclodextrin, played an evident role as a structure-directing agent; thus, small raspberry-like Au NSs were obtained. The modified electrodes were characterized by surface characterization techniques and electrochemical methods. The Au NSs-modified electrodes effciently electrocatalyzed the oxidation of toxic molecules such as hydrazine and sulfite and nitrite ions even in the absence of any other electron transfer mediator or enzyme immobilization. Well-resolved oxidation peaks along with decreased overpotentials were noticed during the electrooxidation process. The fabricated Au nanostructured electrode clearly distinguished the electrooxidation peaks of each of the three analytes from their mixture.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제36회 동계학술대회 초록집
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• pp.103.2-103.2
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• 2009

• Bulletin of the Korean Chemical Society
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• 제15권3호
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• pp.190-191
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• 1994

• 전기화학회지
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• 제10권1호
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• pp.1-6
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• 2007

금 나노 입자를 회합시킨 흑연전극 표면에 mercaptopropionic acid(mpa)를 사용하여 자기조립 단층막(self-assembled monolayer: SAMs)을 생성시키고 이어서 도파민(dopa)과의 짝지움 반응을 통하여 Gr(Au)/mpa-dopa형의 수식된 전극을 제작하여 NADH의 전기촉매 산화반응에 적용하였다. 이 수식 전극이 전자전달반응속도와 반응과정에 대하여 연구하였다. 전극 표면에 고정된 도파민이 NADH와 이차반응 속도상수는 회전 전극법으로 0.1 M 인산염 완충용액(pH=7.0)에서 결정하였으며 그 값이 $5.06{\times}10^5M^{-1}s^{-1}$였고, $EC_{cat}$ 및 전자전달이 지배적인 과정이었다. 그러나 반응초기 즉, $10^{-3}s$ 이내에서는 이 전극에서 확산에 영향을 받으며 그 때 확산계수는 $4.64{\times}10^{-4}cm^2s^{-1}$이다.

• 한국진공학회지
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• 제9권4호
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• pp.379-381
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• 2000

Organic materials have potential advantages to be utilized as semiconductors in field effect transistors and light emmiting diodes. Gold, Aluminium, Silver, Chromium and Indium are used by electrodes. Gold is ohmic contact and the others are schottky contact. In this study, Pentacene and various electrode materials were deposited by Organic Molecular Beam Deposition (OMBD) and vacuum evaporation respectively. Those films were photolithographically patterned for measurements. These devices showed no degration after a 15 days of storage in laboratory environment.

• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2005년도 생물공학의 동향(XVI)
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• pp.88-92
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• 2005

Aptamer is the single-stranded oligonucleotide which binds to various target molecules such as proteins, peptides, lipids and small organic molecules with high affinity and specificity. DNA aptamers specific for the $17{\beta}-estradiol$ were selected by SELEX (Systematic Evolution of Ligands by EXponential enrichment) process from a random DNA library. These DNA aptamers have a high affinity to $17{\beta}-estradiol$ as an endocrine disrupting chemical. Nanowell and $200{\mu}m$ gold electrode were used as substrate for DNA aptamer immobilization and electrochemical analysis. Especially, nanowell gold electrode was fabricated by e-beam lithography. The size of single nanowell is 130nm and 40,000 nanowells were deposited on one gold electrode. The immobilization method was based on the interaction between the biotinylated aptamer and streptavidin deposited on gold electrode previously. Immobilization procedure was optimized by surface plasma resonance (SPR) and electrochemical analysis. After the immobilization of DNA aptamer on streptavidin modified gold electrode, $17{\beta}-estradiol$ solution was treated on aptamer immobilized gold electrode. The current of gold electrode was decreased by the binding of $17{\beta}-estradiol$ to DNA aptamer immobilized on gold electrode. However, in negative control experiments of 1-aminoanthraquinone and 2-methoxynaphthalene, the current was rarely decreased. And more sensitive data was obtained from nanowell gold electrode comparing with $200{\mu}m$ gold electrode.

• 전기전자학회논문지
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• 제23권4호
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• pp.1122-1127
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• 2019

본 연구에서는 인체의 생체임피던스는 임상 및 생물학적 조직의 병적 및 생리적 상태를 모니터링 하여 많은 정보를 획득 가능하다. 생체임피던측정용 4 전극법시스템은 2개의 전극은 생체의 전위차를 측정하였고, 다른 두 전극은 전류를 흘러주는 전극으로 사용하였다. 새롭게 개발된 건식 Gold 전극은 1 Hz에서 50 kHz 까지 임피던스를 측정하였으며, 재현성 있는 결과를 얻었다. 건식전극의 임피던스 측정값을 검증하기 위해서 생체전극피부등가회로를 이용하여 피팅을 실시하였고 모델링을 통해서 실효성을 증명하였다. 고정 전극형태는 측정 시 부착되는 전극의 위치가 일정하므로 안정적인 측정값을 얻을 수 있어서 오류를 최소화할 수 있다.

• Journal of Photoscience
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• 제11권1호
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• pp.1-6
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• 2004

Molecular assembling is one of the current interests in the field of bottom-up nanotechnology. Self-assembled monolayers of sulfur-containing molecules or supramolecular assemblies via surface sol-gel processes formed on conductive supports are chemically robust and can be easily fabricated without sophisticated instruments. We have fabricated various types of molecular assemblies consisting of donor-acceptor pairs on the surfaces of gold and indium-tin-oxide electrodes. Build-up of three-dimensional multi structures consisting of thiol dyes and gold nanoparticles also has been successful. These assemblies showed clear photocurrent responses in photoelectro-chemical cells. In this article, we will describe recent progress on photoelectric conversion using molecular assemblies especially focused on our research results.