• Title/Summary/Keyword: Glycol

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Treatment of Polyester Weight Loss Wastewater Using Strains Degrading Ethylene Glycol and Terephthalic Acid (Ethylene Glycol과 Terephthalic Acid 분해균주를 이용한 감량가공폐수처리)

  • 서승교
    • Journal of Environmental Health Sciences
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    • v.27 no.3
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    • pp.43-48
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    • 2001
  • Terephthalic acid and ethylene glycol resulting form the weight-reduction process of polyester make trouble in the operation of activated sludge process. Also, polyester weight loss wastewater shows high pH, high organic strength and wide variation of organic loading. Therefore, this study was conducted in order to improve treatment efficiency by activated sludge process with Pseudomonas sp degrading components of polyester weight loss wastewater. The CO $D_{Mn}$ and BO $S_{5}$ of the waste wastewater were 560~3,000 mg/$\ell$ and 8000~3,000 mg/$\ell$, respectively. pH was 11.8~12.3. COD removal efficiency by activated sludge-coagulation process with Pseudomonas sp was 94.1~95.8% for 35 hr of hydraulic retention time. Total organic carbon removal efficiency was 97.1%. Ethylene glycol and terephthalic acid in the wastewater were completely degraded during 32 hr of hydraulic retention time.e.

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Synthesis of Poly-$N^5$-(3-hydroxypropyl glutamine)/Poly (ethylene glycol)block Copolymer Hydrogel and Its Application to the Artificial Skin (Poly-$N^5$-(3-hydroxypropyl glutamine)/Poly (ethylene glycol)block copolymer hydrogel의 합성과 인공피부에의 응용)

  • 조종수;오상봉
    • Journal of Biomedical Engineering Research
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    • v.12 no.1
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    • pp.57-62
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    • 1991
  • ABA type block copolymers composed of poly($\gamma-benzyl$ L-glutamate) (PBLG) as the A component and poly (ethylene glycol) as the B component were obtained by polymerization of $\gamma-benzyl$ L-gletamate N -carboxyanhydride, initiated by amino groups at both ends of poly(ethylene glycol) . From circular dichroism measurements in ethylene dichloride solution as well as from infrared spectTa measurements in solid state, it was found that the polypep- tide block exists in the a-helical conformation, as in PBLG homopolymer. $Poly-N^5$ (3-hydroxypropyl glutamine) (PHPG)/poly(ethylene glycol)block copolymer hydrogel was obtained by the treatment of PBLG/PBG block copolymer with the mixture of 3-ammine-1-propanol and diamlnooctane. The water content of PHPG/PEG block copolymer hydrogel was about 80wt% when the concentration of crosslinking agent was below 5 mole % per polymer.

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Effect of Glycols and Catalysts on Cotton Fabrics Treated with Glyoxal

  • Lee, Eui-So;Kim, Seung-Il
    • Fibers and Polymers
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    • v.5 no.3
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    • pp.230-233
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    • 2004
  • The optimum conditions for durable press treatment of cotton fabrics using glyoxal as a nonformaldehyde crosslinking agent were investigated. Crosslinking reaction was conducted in the presence of different catalysts such as aluminum sulfate, magnesium chloride, or magnesium chloride-citric acid mixture at various mole ratios of catalyst to glyoxal. Aluminum sulfate was proven the most effective one among those used. Glycol addition into a glyoxal padding bath increased the wrinkle recovery angle(WRA) and whiteness of treated fabrics. The optimum mole ratio of glycol to glyoxal was 1:1. Diethylene glycol addition produced better overall performance to the glyoxal-crosslinked fabric compared to ethylene glycol addition.

Synthesis of block copolymer of polystyrene and polyethylene glycol methyl ether methacrylate(PEGMA) by ATRP (atom transfer radical polymerization) (ATRP(atom transfer radical polymerization)에 의한 polystyrene과 poly ethylene glycol methyl ether methacrylate(PEGMA)의 블록 공중합체의 합성)

  • Kim, Sang-Hern
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.3
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    • pp.306-316
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    • 2009
  • In this study, block copolymer of polystyrene and polyethylene glycol methyl ether methacrylate(PEGMA) by ATRP(atom transfer radical polymerization) method was synthesized. 4 arm-molecule which contained halogen atom was synthesized for an initiator. With 4 arm-molecule monodispered polystyrene were synthesized by ATRP method. The molecular change of synthesized monodispersed polystyrene with respect to time was investigated and living polymer characteristic was confirmed. Block copolymer of polystyrene and polyethylene glycol methyl ether methacrylate(PEGMA) was synthesized by ATRP with macroinitiator which was synthesized from the monodispersed polystyrene(Mn=12000). The molecular weight of obtained PS-b-PEGMA was 22,000.

Formation of PEG/Dextran Aqueous Two-Phase System for Starch Hydrolysis Using $\alpha$-Amylase ($\alpha$-Amylase로 전분 가수분해를 위한 PEG/Dextran 수성 2상계 구성)

  • 박병춘;임동준
    • Microbiology and Biotechnology Letters
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    • v.20 no.2
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    • pp.190-195
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    • 1992
  • In the polyethylene glycol/dextran aqueous two-phase systems, volume ratio was increased and partition coefficient was decreased with the increase of potyethylene glycol molecular weight and concentration. However the volume ratio was decreased and the partition coefficient was increased with the increase of dextran molecular weight. On the other hand, the volume ratio and the partition coefficient were decreased with the increase of dextran concentration. Continuous enzymatic hydrolysis of soluble starch with $\alpha$-amylase which was produced by Bacillus amyloliquefaciens IF0 14141 was investigated in polyethylene glycol/dextran aqueous two-phase systems. Nonreacted soluble starch and $\alpha$-amylase were reused in these systems. $\alpha$-Amylase activity was maintained more than 100 hrs by recycling of $\alpha$-amylase from bottom of settler to reactor.

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Effects of Various Kinds and Concentrations of Cryoprotectants on Viabilities of Ultrarapidly Frozen 4-cell Mouse Embryos and Morulae (생쥐 4세포기 및 상실배기 수정란의 초급속동결에 있어서 동결보호제의 종류와 농도가 생존성에 미치는 영향)

  • 임준호;신상태;강만종;한용만;이경광
    • Journal of Embryo Transfer
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    • v.11 no.1
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    • pp.35-40
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    • 1996
  • This study was carried out to select the best cryoprotectant and to establish optimal concentration of the cryoprotectant in ultrarapid freezing of mouse 4-cell embryos and morulae, respectively. We investigated survival of ultrarapid frozen embryos according to various cryoprotectants such as glycerol, ethylene glycol, propylene glycol and dimethyl sulfoxide (DMSO). Suvival of the embryos frozen at different concentrations (3.0, 4.0 and 5.0 M) of indivisual cryoprotectant was also tested. Preimplantation developmental rate (96.3%, 83/86) of 4-cell mouse embryos treated with 4.0 M ethylene glycol after ultrarapid freezing and thawing was higher than those of other cryoprotectants (glycerol, propylene glycol and DMSO). In the ultrarapid freezing of mouse morulae, the highest developmental rate (98.8%, 89 /90) of the embryos to blastocysts was shown in the group of 5.0 M glycerol. Thus, these results demonstrate that 4.0 M ethylene glycol and 5.0 M glycerol are optimal for ultrarapid freezing of 4-cell mouse embryos and morulae, respectively.

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Analysis of Thermodynamic Design Data for Cooling of Double -Effect Absorption System of Solar Energy using LiBr - water and Ethylene Glycol Mixture (흡수액으로 에틸렌글리콜이 혼합되고 태양열을 이용한 이중효용 흡수식 시스템의 냉방 특성해석)

  • Won, Seung-Ho;Park, Sang-Il
    • Journal of the Korean Solar Energy Society
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    • v.23 no.4
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    • pp.45-54
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    • 2003
  • For cooling of double effect absorption heat pump system of solar heating source, analysis of thermodynamic design data has been done to find the property of Libr-water + ethylene Glycol mixture for working fluid by computer simulation. Derived thermodynamic design data, enthalpy based coefficient of performance and flow ratio for possible combinations of operating temperature for water - LiBr and Ethylene Glycol mixture ($H_2O$ : CHO ratio 10:1 by mole) by computer simulation are done. The obtained results, COP and mass flow ratio of the water - lithium bromide - ethylene glycol system, are compared with data for the water-Libr pair solution.

Analysis of Thermodynamic Design Data for Heating of Double - Effect Solar Absorption System using LiBr - water and Ethylene Glycol Mixture (에틸렌글리콜 혼합액을 사용하고, 태양열을 보조열원으로 하는 이중효용 흡수식 시스템의 난방 특성해석)

  • Won, S.H.
    • Journal of the Korean Solar Energy Society
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    • v.22 no.4
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    • pp.51-61
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    • 2002
  • Analysis of thermodynamic design data of double effect solar absorption heat pump system for heating has been done to find the property of Libr-water + ethylene Glycol mixture for working fluid by computer simulation. Derived thermodynamic design data. enthalpy based coefficient of performance and flow ratio for possible combinations of operating temperature for water - LiBr and Ethylene Glycol mixture (H2O: CHO ratio 10:1 by mole) by computer simulation. The obtained results, COP and mass flow ratio of the water-lithium bromide-ethylene glycol system, are compared with data for the water-Libr pair solution.

Local Structure Study of Liquid Phase Ethylene Glycol and 1,3-propanediol through Density Functional Theory

  • Nam, Seungsoo;Sim, Eunji
    • Proceeding of EDISON Challenge
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    • 2016.03a
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    • pp.140-146
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    • 2016
  • Using density functional Theory, we studied local structure of liquid ethylene glycol and 1,3-propanediol. For both liquid, making intramolecular hydrogen bonding is not preferred, because relative energy between with and without intramolecular hydrogen bond is only -1.95kcal/mol, which is far less than intermolecular hydrogen bonding energy, about -7.5kcal/mol. Also, hydrogen bond induce polarization of hydroxyl group and make $2^{nd}$ hydrogen bond more stronger. This effect was small in intramolecular hydrogen bond of ethylene glycol. When considering energy per hydrogen bond, making only one intermolecular hydrogen bond for ethylene glycol pair is energetically favored, while two intermolecular hydrogen bond can be formed in 1,3-propanediol pair.

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A Study on Electrochemical Properties of Acrylate-based Gel Polymer Electrolyte with Ethylene Oxide Group (Ethylene Oxide기를 갖는 Acrylate계 Gel Polymer Electrolyte의 전기화학적 특성에 관한 연구)

  • Kim, Hyun-Soo;Shin, Jung-Han;Moon, Seong-In;Oh, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.6
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    • pp.608-614
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    • 2004
  • The gel polymer electrolyte was prepared by radical polymerization using tetra(ethylene glycol) diacrylate and tri(ethylene glycol) dimethacrylate to investigate affect of the number of ethylene oxide. The gel polymer electrolyte showed good electrochemical stability up to 4.5 V vs. Li/Li and high ionic conductivity at various temperatures. The lithium-ion polymer batteries with the gel polymer electrolyte, tetra(ethylene glycol) diacrylate- and tri(ethylene glycol) dimethacrylate-based, also represented good electrochemical performances such as rate capability, low-temperature performances and cycleability. However, the cell with tri(ethylene glycol) dimethacrylate, which has three ethylene oxide, showed better electrochemical performance.