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http://dx.doi.org/10.12925/jkocs.2009.26.3.9

Synthesis of block copolymer of polystyrene and polyethylene glycol methyl ether methacrylate(PEGMA) by ATRP (atom transfer radical polymerization)  

Kim, Sang-Hern (Department of Applied Chemistry, Hanbat National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.26, no.3, 2009 , pp. 306-316 More about this Journal
Abstract
In this study, block copolymer of polystyrene and polyethylene glycol methyl ether methacrylate(PEGMA) by ATRP(atom transfer radical polymerization) method was synthesized. 4 arm-molecule which contained halogen atom was synthesized for an initiator. With 4 arm-molecule monodispered polystyrene were synthesized by ATRP method. The molecular change of synthesized monodispersed polystyrene with respect to time was investigated and living polymer characteristic was confirmed. Block copolymer of polystyrene and polyethylene glycol methyl ether methacrylate(PEGMA) was synthesized by ATRP with macroinitiator which was synthesized from the monodispersed polystyrene(Mn=12000). The molecular weight of obtained PS-b-PEGMA was 22,000.
Keywords
block copolymer of polystyrene and polyethylene glycol methyl ether methacrylate(PEGMA); ATRP(atom transfer radical polymerization); 4-arm initiator; macroinitiator;
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