Journal of the Korean Applied Science and Technology (한국응용과학기술학회지)

The Korean Society of Applied Science and Technology (한국응용과학기술학회)
권호 표지
DOI QR코드

DOI QR Code

Synthesis of block copolymer of polystyrene and polyethylene glycol methyl ether methacrylate(PEGMA) by ATRP (atom transfer radical polymerization)

ATRP(atom transfer radical polymerization)에 의한 polystyrene과 poly ethylene glycol methyl ether methacrylate(PEGMA)의 블록 공중합체의 합성

  • Kim, Sang-Hern (Department of Applied Chemistry, Hanbat National University)
  • Published : 2009.09.30
Download PDF
⟨ Previous Next ⟩

Abstract

In this study, block copolymer of polystyrene and polyethylene glycol methyl ether methacrylate(PEGMA) by ATRP(atom transfer radical polymerization) method was synthesized. 4 arm-molecule which contained halogen atom was synthesized for an initiator. With 4 arm-molecule monodispered polystyrene were synthesized by ATRP method. The molecular change of synthesized monodispersed polystyrene with respect to time was investigated and living polymer characteristic was confirmed. Block copolymer of polystyrene and polyethylene glycol methyl ether methacrylate(PEGMA) was synthesized by ATRP with macroinitiator which was synthesized from the monodispersed polystyrene(Mn=12000). The molecular weight of obtained PS-b-PEGMA was 22,000.

Keywords

References

  1. S. Munirasu and R. Dhamodharan, Very rapid copper-mediated atom transfer radical polymerization of benzyl methacrylate at ambient temperature, J. Poiym Sci. Part A: Polym Chem, 42, 1053 (2004) https://doi.org/10.1002/pola.11046
  2. L. Xue, U. S. Agarwal, and P. J. Lemstra, High Molecular Weight PMMA by A TRP, Macromolecules, 35, 8650 (2002) https://doi.org/10.1021/ma020905s
  3. j. V. Nguyen and C. W. Jones, Design, Behavior, and Recycling of Silica-Supported CuBr-Bipyridine ATRP Catalysts, Macromolecules, 37, 1190 (2004) https://doi.org/10.1021/ma0354391
  4. E. L. Brantley and G. K. Jennings, Fluorinated Polymer Films from Acylation of ATRP Surface--Initiated Poly(hydroxyethyl methacrylate), Macromolecules, 37, 1476 (2004) https://doi.org/10.1021/ma035471v
  5. W. Tang and K. Matyjaszewski, Effect of Ligand Structure on Activation Rate Constants in ATRP, Macromolecules, 39, 4953 (2006) https://doi.org/10.1021/ma0609634
  6. J. N. Kizhakkedathu, R. N. jones, and D.E. Brooks, Synthesis of Well-Defined Environmentally Responsive Polymer Brushes by Aqueous ATRP, Macromolecules, :.37, 734 (2004) https://doi.org/10.1021/ma034934u
  7. Y. Schnejder, J. D. Azpulay, R. C. Coffin, and G. C. Bazan, New Ployethylene Macroinitiators and Their Subsequent Grafting by Atom Transfer Radical Polymerization, J. Am. Chem. Soc. 130, 10464 (2008) https://doi.org/10.1021/ja803006d
  8. X. H. Dai and C. M. Dong, Synthesis, self-assembly and recognition properties of biomimetic star-shaped poly(c -caprolactone)-b-glycopolymer block copolymers, J Polym Sci. Part A: Poiym Chem, 46, 817 (2008) https://doi.org/10.1002/pola.22426
  9. H. F. Gao and K. Matyjaszewski, Arm-First Method As a Simple and General Method for Synthesis of Miktoarm Star Copolymers, J Am Chem Soc., 129, 11828 (2007) https://doi.org/10.1021/ja073690g
  10. H. Y. Hong, Y. Y. Mai, Y. F. Zhou, D. Y. Yan, and Y. Chen, Synthesis and supramolecular self-assembly of thermo sensitive amphiphilic star copolymers based on a hyperbranched polyether core, J Polym Sci. Part A: Polym Chem, 46, 668 (2008) https://doi.org/10.1002/pola.22415
  11. H. Gao, M. C. jones, P. Tewari, M. Ranger, and J. C. Leroux, Star-shaped alkylated poly(glycerol methacrylate) reverse micelles: Synthesis and evaluation of their solubilizing properties in dichloromethane, J Polym Sci. Part A: Polym Chem, 45, 2425 (2007) https://doi.org/10.1002/pola.22004
  12. L. G. Bai, L. F. Zhang, j. A. Zhu, Z. P. Cheng, and X. L. Zhu, Iron(ID)-mediated AGET A TRP of styrene using tris(3,6-dioxaheptyi)amine as a ligand, J Polym Sci. Part A: Polym Chem, 47, 2002 (2009) https://doi.org/10.1002/pola.23300
  13. S. Sinn well, M. Lammens, M. H. Stenzel, F. E. Du Prez, and C. B. Kowollik, Efficient access to multi-arm star block copolymers by a combination of A TRP and RAFT-HDA click chemistry, J Polym Sci. Part A: Polym Chem, 47, 2207 (2009) https://doi.org/10.1002/pola.23299
  14. Z. Y. Yenice, M. A. Tasdelen, A. Oral, C. Guier, and Y. Yagci, Poly(styrene-btetrahydrofuran)/ clay nanocomposites by mechanistic transformation, J Poiym Sci. Part A: Poiym Chem, 47, 2190 (2009) https://doi.org/10.1002/pola.23332
  15. R. M. Sun, G. W. Wang, C. Liu, and j. L. Huang, Preparation of comb-like copolymers with amphiphilic poly (ethylene oxide)-b-polystyrene graft chains by combination of graft from and graft onto strategies, J Polym Sci. Part A: Polym Chem, 47, 1930 (2009) https://doi.org/10.1002/pola.23302