• 한국세라믹학회지
• /
• 제27권2호
• /
• pp.288-296
• /
• 1990

Parent glasses for the experiments were prepared to be ratio of Li2O : Al2O3 : SiO2=4.5 : 25 : 70.5 as basic components, and TiO2 and ZrO2 in the mixing ratio of 1 : 1 were added as the nucleating agents, whose contents were increased in each sample. DTA, XRD, SEM, IR were observed, and thermal expansion and transmissivities were measured for the crystallized samples under the controlled heat-treatments. The transformation temperatures and the dilatometric softening temperatures in thermal expansion curves, and also the exothermic peaks in differential thermo-analytical curves were shifted to lower temperature. The crystal phase deposited through the heat-treatment was identified as ${\beta}$-quartz solid solution with XRD and IR analysis. The crystalline phases in oopactified samples were ${\beta}$-spodumene coexiting with ${\beta}$-quartz solid solution. The samples having more than 3% nucleating agents were transparent. The crystallized grain sizes were ranged 0.05 to 0.1$\mu\textrm{m}$. The crystallized transparent samples were exceeded 85% in the transmissivity.

• 한국세라믹학회지
• /
• 제45권7호
• /
• pp.401-404
• /
• 2008

Willemite ($Zn_2SiO_4$) are a wide range of applications such as a phosphor host and an important crystalline phase in glass ceramics, electrical insulators, glazes, and pigments. In this study, Willemite precursors were synthesized with zinc silicate gels from mixture of zinc nitrate solution and various sodium silicate solution by the geopolymer technique. To examine the crystallization behavior, precursors were have been monitored by the XRD. A pure willemite phase was obtained at $900^{\circ}C$. TEM investigations revealed that the sample with 50 nm particle size was obtained via heat-treated at $900^{\circ}C$ for W-3.

• 대한치과의사협회지
• /
• 제25권11호통권222호
• /
• pp.1019-1028
• /
• 1987

결손된 치질과 변색된 법랑질을 수복하기 위해 많은 재료와 술식이 개발되어왔다. 즉 silicate cement, PMMA resin, BISGMA composite resin, glass ionomer cement, porcelain등이 이용되어 왔으나 이것들은 biocompatible하지 않아 이상적인 재료는 아니다. 따라서 인간의 결손된 enamel을 수복할 수 있는 새로운 생역학적인 재료가 필요하게 되었다. 필자는 최근 관심의 대상이 되고 있는 porcelain laminate veneer system(층상 도재 전장관)에 관하여 문헌을 중심으로 고찰해 보고자 한다(국내에서는 장완식 교수께서 1987년 6월10일 보철학교실 세미나에서 video tape를 통해 소개한바 있음). 여기서는 Hobo, Iwata(1985)등이 소개한 castable apatite ceramic material을 이용한 laminate veneer술식에 관해 기술하고 내화성 모형(refractory cast)을 이용한 laminate술식과 비교 기술하고자 한다.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2002년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 일렉트렛트 및 응용기술
• /
• pp.75-78
• /
• 2002

The dielectric properties for Ni electrode multilayer ceramic chip capacitor for Y5V has been studied with $(Ba_{0.93}Ca_{0.07})_m(Ti_{0.82}Zr_{0.18})O_2+MnO_2$ 0.2wt%, $Y_2O_3$ 0.18wt%, $SiO_2$ 0.15wt%, glass frit 1 wt% composition. The m ratio in the range of 1.006 ~ 1.012 have dielectric constant 9,500 ~ 14,500 and insulation resistance 390 ~ 460 $G{\Omega}$. Using the dielectrics, nikel electrode multilayer chip capacitor with Y5V, 104Z in EIA 0603 size specific capacitance were developed.

• 한국정밀공학회지
• /
• 제18권11호
• /
• pp.132-137
• /
• 2001

Application of ceramics, carbide, ferrite has grown considerably due to their mechanical properties such as high degree hardness, chemical stability, super wear resistance. Despite these characters, the use of advanced material has not increased because of poor machinability. The application of metal bonded wheel was proposed. But it is difficult that metal bond wheel can be dressed. Recently, to solve this problem, the technology of in-process electrolytic dressing is developed. This method need wheel for electrolytic dressing, power supply and electrolyte. The aim of this study is development of CIB-D wheel for electrolytic and its evaluation of electrolytic characteristics, and achieve ultra-precision lapping of carbide, optic glass.

• 대한기계학회논문집A
• /
• 제26권1호
• /
• pp.153-159
• /
• 2002

Brittle materials such as ceramics and glasses show fragile fracture due to the low toughness and the crack sensitivity. When brittle materials are subjected to impact loading by small spheres, high contact pressure occurs to the surface of the specimen. Local damage is subsequently generated in the specimen. This local damage is a dangerous factor which gives rise to the final fracture of structures. In this research, impact damage of soda-lime glass plates by small spheres was evaluated by considering the effects of impact directions of indenter, pressure condition of specimen and residual strength after impact loading.

• 한국전기전자재료학회논문지
• /
• 제13권4호
• /
• pp.343-348
• /
• 2000

NCZF ferrites doped with B-Bi-Zn(35-25-40) glass ceramics were prepared to investigate the magnetic properties. The XRD peaks of all of samples were observed only spinel phase. As the additive increased at sintering temperature 750$^{\circ}C$ and 850$^{\circ}C$ for 3 hours, the density and shrinkage of the samples increased until 5.28 g/cm$^3$ and 20% respectively. And other samples showed constant trends having the density about 5.4g/cm$^3$. According to SEM images the growth of grain progressed rapidly at sintering temperature of 850$^{\circ}C$ for 3 hours. Increasing the additive initial permeability and complex permeability decreased. The high values of complex permeability as a function of frequency showed that NCZF doped with 3 wt%, 5wt%, samples at sintered temperature of 850$^{\circ}C$/3h and 900$^{\circ}C$/3h.

• 한국재료학회지
• /
• 제5권5호
• /
• pp.525-531
• /
• 1995

화학 조성, 열처리 온도 및 시간을 적절히 제어하여 Phlogopite-based 글라스 세라믹스를 제조한 다음 미세구조와 기계적 물성의 관계를 조사하였다. 특히 결정의 크기가 결정화도에 따른 기계적 물성 변화를 관찰하였다. 결정의 크기가 약 1-5$\mu\textrm{m}$이고결정화도가 70%인 시편에서는 $K_{IC}$ 가 1.4MPaㆍ $m^{1}$2/이고 MOR이 140MPa의 값을 얻었으며 이때의 파괴양상은 crack deflection에 의한 transgranular fracture가 주돈 기구임을 관찰하였다. 결정화도가 낮은 영역에서는 뚜렷한 기계적 물성 변화가 없었으며 결정화도가 50~70%인 영역에서 두드러진 기계적 강도 및 인성의 증가가 관찰되었다.

• 한국세라믹학회지
• /
• 제29권10호
• /
• pp.815-821
• /
• 1992

The batches having excess SiO2 to tetrasilicic mica KMg2.5 (Si4O10)F2 were melted at 1450℃. The fabricated samples were heat-treated for the nucleation and the crystallization. The crystallized samples were investigated on several properties. The tetrasilicic mica composition with excess 10 wt% SiO2 was successful both in glassifying and in crystallizing. The optimum temperatures for the nucleation and the crystallization were 680℃ and 1000-1100℃, respectively. The mica and the cristobalite crystallines were identified after heat-treatment. The properties of the samples processed appropriately were as follows, bulk density 2.64g/㎤, thermal expansion coefficient ∼80×10-7/℃, Vicker's hardness ∼105 Kgf/㎟, bending strength ∼666Kgf/㎟, dielectric constant ∼11.1, tan δ 2.5%, volume resistivity 2.35×107∼1.3×1011{{{{ OMEGA }}cm, surface roughness 6.984㎛.

• 한국반도체및디스플레이장비학회:학술대회논문집
• /
• 한국반도체및디스플레이장비학회 2004년도 춘계학술대회 발표 논문집
• /
• pp.234-239
• /
• 2004

본 연구에서는 마이크로파용 유전재료로서 널리 사용되고 있는 BNT($BaO-Nd_{2}O_{3}-TiO_{2}$)계 세라믹스를 기본조성으로 하고, 저융점의 phoshpate계 유리 프릿의 첨가를 통해 LTCC(Low Temperature Cofired Ceramic)에 적용 가능한 유전율을 가진 조성을 개발 하고자, $70P_{2}O_{5}-5B_{2}O_{3}-(25-x)BaO-xNa_{2}O$ 유리를 제조 및 특성을 평가하였다. 또한, BNT계 세라믹스에 glass frit을 5 - 15 wt% 범위에서 첨가하고, $800 - 950^{\circ}C$의 온도범위에서 소결하여 제조된 유리-세라믹 복합체의 소결특성 및 유전특성을 조사하였다.