• 제목/요약/키워드: Glass

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Recent Developments in Reducing Bulkiness of CRT Glass Bulbs

  • Sugawara, Tsunehiko;Shimizu, Naoya;Murakami, Toshide
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.359-363
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    • 2002
  • Several innovations for reducing the bulkiness of glass bulbs for flat and large CRTs have been made and further technologies are being developed by using material and structural approaches. The integrated glass technology based on these innovations will provide a lightweight shallow glass bulb for the realization of a half- depth CRT.

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아산 명암리 밖지므레 유적 출토 유리구슬의 화학적 특성 (Chemical Characteristic of Glass Beads Excavated from Bakjimeure Site in Asan, Korea)

  • 김나영;김규호
    • 보존과학회지
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    • 제28권3호
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    • pp.205-216
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    • 2012
  • 아산 밖지므레 유적 마한 분묘에서 출토된 유리 65점은 포타쉬유리군이 13점, 소다유리군이 52점으로 소다유리군이 우세하게 나타났다. 색상별로 세분하면, 감청색 유리는 포타쉬유리군과 소다유리군이 공반되는 반면 자색 유리는 포타쉬유리군이고 적색, 벽색, 녹색, 금박유리는 소다유리군으로 나타났다. 감청색 유리는 안정제의 함량이 낮은 LCA계이고 이중에 소다유리는 MgO와 $K_2O$ 함량이 낮은 LMK형으로 천연탄산소다가 원료로 사용된 것으로 판단된다. 적색 유리는 균질한 유리가 LCA-B계/HMK형이고 불균질한 유리가 HCLA계/LMK형으로 각각 해양 식물 재와 천연탄산소다가 사용되었을 가능성이 있다. 벽색과 녹색 유리는 환옥이 LCA-A계/LMHK형이고 연주옥이 LCA-B계/HMK형으로 형태에 따라 차이를 보인다. 금박구슬은 19.9~22.6K의 순도를 갖는 금박과 HCLA계/LMK형의 소다유리로 제작되었다. 즉, 아산 밖지므레 유적 유리구슬 대부분은 백제시대 타 유적에서 확인되는 유리 조성과 유사성이 높은 편이나 벽색 및 녹색 연주옥과 일부 적색 환옥은 다른 화학 조성을 보이므로 원료에 차이가 있음을 알 수 있다. 이와 같은 특성은 고대유리의 교역 체계 이해를 위한 중요한 단서를 제공할 것으로 기대된다.

Lead free, Low temperature sealing materials for soda lime glass substrates in Plasma Display Panel (PDP)

  • Lee, Heon-Seok;Hwang, Jong-Hee;Lim, Tae-Young;Kim, Yoon-Hee;Lee, Suk-Hwa;Kim, Il-Won;Lee, Jong-Koo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.373-376
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    • 2008
  • New glass compositions for lead free, low temperature sealing glass frit was examined in $ZnO-V_2O_5-P_2O_5$ glass system which can be used sealing material for PDP to be made of soda lime glass substrates. Among many glass compositions, KFS-C glass showed low glass transition point (Tg) and good fluidity and adhesion characteristics when it was tested by flow button method at low temperature of $420^{\circ}C$. Its Tg was $317^{\circ}C$ and thermal expansion coefficient (CTE) was $70{\times}10^{-7}/K$. The glass frit was mixed with an organic vehicle to make a paste and it was dispensed and sealed with soda lime glass substrates at $420^{\circ}C$ for 10min. Sealed glass panels also showed good adhesion strength even sealed at low temperature of $420^{\circ}C$.

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A Comparison in Characteristics of Chemical Composition of Glass Vessels Excavated from Neungsalli Temple in Buyeo, Korea, from Baekje Period

  • Koh, Min Jeong;Kang, Hyung Tae;Kim, Na Young;Kim, Gyu Ho
    • Bulletin of the Korean Chemical Society
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    • 제33권12호
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    • pp.4173-4179
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    • 2012
  • From Neungsalli Temple located in Buyeo, ancient glass vessel fragments were discovered along with hundreds of glass beads. In this research, we used SEM-EDS to analyze glass vessel fragments and beads excavated from Neungsalli Temple. Then, we analyzed their chemical composition and examined their characteristics. In particular, we investigated a relationship between glass vessels from Neungsalli temple and Hwangnamdaechong (South tomb). The result of our experiment showed that the glass artifacts from Neungsalli temple were all soda glass. To be specific, the vessel fragments were soda-lime glass and spherical beads were high-alumina soda glass. Then, we compared glass vessel fragments from Neungsalli temple to glass vessels excavated from Hwangnamdaechong. Glass vessels from both sites turned out to be soda lime glass. We classified them further based on raw material used for soda - natron and marine plant ash.

석탄폐석을 이용한 소다라임계 컬러유리의 광학적 특성 (Optical Properties of Soda-lime Color Glass Fabricated by Using Refused Coal Ore)

  • 임태영;정상수;황종희;김진호;김정국
    • 한국재료학회지
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    • 제20권10호
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    • pp.524-534
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    • 2010
  • Glass was fabricated using refused coal ore obtained from the Dogye coal mine in Samcheok. We additionally used soda ash and calcium carbonate to make a glass with the chemical composition of soda-lime glass, and we also used white, brown, and green glass cullet to make various kinds of colored glass. Transparent glass was fabricated by melting batch materials including refused coal ore at $1550^{\circ}C$ for 1 hr in an electrical furnace. The light transmittance and color chromaticity were measured by a UV/VIS/NIR spectrometer. Transparent glass with a light transmittance of over 80% was fabricated using normal refused coal ore and white glass cullet. Various kinds of colored glass with a light transmittance of 30-80% were fabricated using refused coal ore and brown or green glass cullet. The light transmittance of the mixed color glass samples, fabricated using normal refused coal ore and brown glass cullet and green glass cullet, indicated 30-47%, a relatively low value, in the condition of a cullet ratio of 20-50%. The characteristics of the color chromaticity of the glass samples were indicated in a chromaticity diagram by x-coordinates, y-coordinates, Y (lightness). The values of x-coordinates and y-coordinates were moved with a regular directional property according to the kind and amount of glass cullet. Therefore, we concluded that refused coal ore can be used for raw materials of color glass products like art glass and glass tile.

폐 유리의 가수 분해반응에 의한 발포유리의 제조(I) - 폐유리의 가수분해 반응 - (Production of Foamed Glass by Using Hydrolysis of Waste Glass (I) - Hydrolysis of Waste Glass -)

  • 이철태;이홍길
    • 공업화학
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    • 제16권4호
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    • pp.519-526
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    • 2005
  • 소다석회 조성의 폐 유리를 발포유리의 원료로 활용하기 위해 폐유리의 가수분해를 시도하였다. 소다석회유리 조성으로 만들어진 판유리 및 병 유리 등은 공히 가압 하에서 증기상의 물 또는 액체상의 물에 의해 효율적으로 가수분해가 진행되었다. 최적의 가수분해의 조건은 공히 $250^{\circ}C$, 2 h이었으며 이 조건하에 얻어진 수화유리의 함수율은 발포유리의 원료유리로서 발포화가 가능한 7.85~10.04%였다. 수식제인 Na성분은 액상의 물에 의한 가수 분해에 효율적이며 유시시료에 대한 중량비로서 0.04첨가 시 가장 높은 함수율을 지닌 수화유리가 얻어졌다.

직물형 유리섬유/에폭시 프리프레그로 피막된 판유리의 강구 충격 파괴 거동 (Steel-Ball-Impact fracture Behavior of Soda-Lime Glass Plates Bonded with Glass Fabric/Epoxy Prepreg)

  • 김형구;최낙삼
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2000년도 춘계학술발표대회 논문집
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    • pp.20-25
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    • 2000
  • In order to study the impact fracture behavior of brittle materials, a steel-ball-impact experiment was Performed. Five kinds of materials were used in this study : soda-lime glass plates, glass/epoxy prepreg-one layer-bonded and unbonded glass plates, glass/epoxy prepreg-three layers-bonded and unbonded glass plates. Fracture patterns, the maximum stress and absorbed fracture energy were observed according to various impact velocities 40-120m/s. With increasing impact velocity, ring crack, cone crack, radial crack and lateral crack took place in the interior of glass plates. The generation of such cracks was largely reduced with glass/epoxy prepreg coating. Consequently, it is thought that the characteristics of the dynamic Impact fracture behavior could be evaluated using the absorbed fracture energy and the maximum stress measured at the back surface of glass plates.

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인산염계 다공질 결정화 유리에 관한 연구 (A Study on the Porous Glass-Ceramics in the Phosphate System)

  • 박용완;현부성;김태호
    • 한국세라믹학회지
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    • 제32권7호
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    • pp.858-864
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    • 1995
  • A porous glass-ceramics body was prepared in the phosphate system. The glass composition of 47.2CaO-22.2TiO2-30.6P2O5 (mol%) containing a few weight percent of ZrO2 was suitable for a mother glass of a porous glass-ceramics. The dense glass-ceramics body was made by a two-step heat treatment of the mother glass. The crystalline phases of the glass-ceramics were $\beta$-Ca3(PO4)2 and CaTi4(PO4)6. The $\beta$-Ca3(PO4)2 phase could be selectively leached out with HCl solution and thus a crystalline $\beta$-Ca3(PO4)2 skeleton was remained. The dimension and shape of the porous glass-ceramics were nearly the same as the those of the first formed glass. The specific surface area and average proe radius of the porous glass-ceramics were 19$m^2$/g and 22 nm, respectively.

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유리병 경량화 지수를 이용한 유리병 포장용기 분석 (Analysis of Glass Bottle using Glass Bottle Lightness Index)

  • 김선종;장시훈;김기태;이유석;박수일
    • 한국포장학회지
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    • 제19권2호
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    • pp.109-115
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    • 2013
  • 국내 유리병 포장의 개선 방향을 제시하기 위하여 유리병 경량화 지수를 이용하여 유리병 재질 사용 원천 감량을 위한 적정 기준을 설정하였다. 제품의 구분은 사용목적과 사용시간에 따라 일회용병과 다회에 걸쳐 장기간 두고 쓰는 반복사용병(returnable bottle) 및 장기보관 사용 일회용 유리병으로 구분하여 설정하였다. 재사용병의 대부분은 권고기준을 충족하고 있는 것으로 나타났으나 해외 제품의 경우 같은 품목임에도 지수가 최적기준에 준하는 수치를 보여 현저하게 낮은 지수를 보였다. 일회용 유리병 중 소용량 드링크류 유리병은 권고기준을 충족하지 못하여 감량할 필요성이 있는 품목군으로 판단된다. 반면 일회용 유리병 중 180 ml 주스류에 해당되는 품목은 평균적으로 권고기준에 가까운 지수를 보였다. 분석 결과, 해외 제품에 비해 국내 제품의 유리병 경량화 지수가 커 상대적으로 무거운 유리병을 사용하고 있는 것으로 나타나 경량화를 위한 노력이 필요하다고 판단된다. 일본의 경우 일본 유리병 재활용 촉진 협의회를 중심으로 유리병 경량화 지수를 이용하여 유리병의 친환경성을 평가하고 있다. 국내에서 업계의 자발적인 감량화 노력을 유도하는 협의회 구성이 필요하며 경량병 사용시 불이익 발생하지 않는 기술력을 확보해야 한다.

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Expansion Properties of Mortar Using Waste Glass and Industrial By-Products

  • Park, Seung-Bum;Lee, Bong-Chun
    • International Journal of Concrete Structures and Materials
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    • 제18권2E호
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    • pp.125-132
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    • 2006
  • Waste glass has been increasingly used in industrial applications. One shortcoming in the utilization of waste glass for concrete production is that it can cause the concrete to be weakened and cracked due to its expansion by alkali-silica reaction(ASR). This study analyzed the ASR expansion and strength properties of concrete in terms of waste glass color(amber and emerald-green), and industrial by-products(ground granulated blast-furnace slag, fly ash). Specifically, the role of industrial by-products content in reducing the ASR expansion caused by waste glass was analyzed in detail. In addition, the feasibility of using ground glass for its pozzolanic property was also analyzed. The research result revealed that the pessimum size for waste glass was $2.5{\sim}1.2mm$ regardless of the color of waste glass. Moreover, it was found that the smaller the waste glass is than the size of $2.5{\sim}1.2mm$, the less expansion of ASR was. Additionally, the use of waste glass in combination with industrial by-products had an effect of reducing the expansion and strength loss caused by ASR between the alkali in the cement paste and the silica in the waste glass. Finally, ground glass less than 0.075 mm was deemed to be applicable as a pozzolanic material.