• Title/Summary/Keyword: Germanium

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Determination of Germanium in Botanical Drugs by Flameless Atomic Absorption Spectrophotometry (흑연로 원자흡광분석법에 의한 생약중의 Germanium 함량에 관한 연구)

  • 백남호;이왕규;박만기;박정일
    • YAKHAK HOEJI
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    • v.23 no.3_4
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    • pp.141-146
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    • 1979
  • Germanium in various botanical drugs was determined by flameless atomic absorption spectro-photometry with a graphite tube atomizer. The amounts of Ge in Zingiberis Rhizoma and Angelicae Radix were $169{\mu}g/g$ and $146{\mu}g/g$, respectively. The amounts of Ge in some other drugs ranged from $70{\mu}g/g$ to $130{\mu}g/g$. There is much more Ge in botanical drugs than in foods.

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Development of Ag Nanowire Patterning Process Using Sacrificial Layer (희생층을 이용한 은 나노와이어 패터닝 공정 개발)

  • Ha, Bonhee;Jo, Sungjin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.7
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    • pp.435-439
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    • 2016
  • We developed a Ag nanowire patterning technique using a water-soluble sacrificial layer. To form a water-soluble sacrificial layer, germanium was deposited on the substrate and then water-soluble germanium oxide was simply formed by thermal oxidation of germanium using a conventional furnace. The formation of Ag nanowire patterns with various line and space arrangements was successfully demonstrated using this patterning process. The main advantage of this patterning technique is that it does not use a strong acid etchant, thereby preventing damage to the Ag nanowire during the patterning process.

A Study of Germanium Substrate Vacancy Clustering Formation using Monte Carlo Method (Monte Carlo방법을 이용한 Germanium 기판의 결공형 클러스터링 형성에 대한 연구)

  • Lee, Jun-Ha
    • Journal of the Semiconductor & Display Technology
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    • v.10 no.2
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    • pp.45-48
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    • 2011
  • In this paper, vacancy clustering formation and diffusion of germanium substrate was studied. The analysis method was adopted Monte Carlo method. At temperatures higher than melting point, fewer clusters formed, but there was less variation in the number of clusters than at lower temperatures, as the time increased. Equilibrium diffusivities in the clustering region were $10^2$ lower than those of free vacancies in the initial stage of kinetic lattice Monte Carlo simulations. They were expressed according to three temperature regimes: at temperatures above 1,100 K, at temperatures of 1,100-900 K, and at temperatures below 900 K. The effective mean migration energy, 1.1 eV, closely coincided with that of the 1.0-1.2 eV in experiments.

Analysis of Germanium in the Ore Samples by UV-Visible Spectroscopy

  • Reddy, K. Raghava;Lee, Kwang-Pill;Gopalan, Anantha Iyengar;Showkat, Ali Md;Kim, Sang-Ho;Paek, U-Hyon
    • Analytical Science and Technology
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    • v.17 no.6
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    • pp.476-480
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    • 2004
  • A simple, rapid, reproducible and selective UV-Visible spectrophotometric method has been developed for determination of germanium in a week acid medium (pH = 3.0) in the presence of mandelic acid (MA) and malachite green (MG). A single extraction in chlorobenzene was used for the analysis. The germanium-MA ion association complex exhibits an absorption maximum at ${\lambda}_{max}=618nm$ with MG as counter ion and has an apparent molar absorptivtity of $1.313{\times}10^5L\;mol^{-1}\;cm^{-1}$. The values obtained by this UV-Visible spectrophotometric method are in good agreement with the values from inductively coupled plasma-mass spectrometer analysis.

Spectrophotometric Investigation of Germanium Complex Solution with o-Chlorophenylfluorone and Determination of Trace Amounts of Germanium

  • Hong-Wen Gao;Wei-Guo Liu
    • Bulletin of the Korean Chemical Society
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    • v.21 no.11
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    • pp.1090-1094
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    • 2000
  • A reaction between germanium (Ge) and the ligand, o-chlorophenylfluorone (o-CPF) has been carried out. The reaction sensitive at pH 4.5 in the presence of triton x-100 was selective in the presence of EDTA. The spectral correction technique was ap plied to the analysis of the reaction instead of single wavelength spectrophotometry because the absorption of excess of o-CPF was not negligible. An updated determination of the properties of the Ge(IV)-o-CPF complex is given, which involved the complex ratio, stepwise absorptivity and stability constant of the complex. In present work, the results show that the complex $Ge(o-CPF)_3was$ formed and its cumulative stability constant was 1.09 ${\times}$1016 . For sample analysis, the detection limit of germanium was 0.01 mg/L, and the recoveries were between 96.4% and 102%, with relative standard deviations of less than 6.5%.

A Study on the Germanium Radiation Detector Compensated by Gamma-ray Irradiation

  • Moon, P.S.
    • Nuclear Engineering and Technology
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    • v.7 no.2
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    • pp.85-94
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    • 1975
  • The n-type germanium crystals have been irradiated by $^{60}$ Co gamma-ray with 647 Mrad at room temperature for compensation. The Ge(${\gamma}$) detectors were fabricated from the gamma-ray irradiated germanium single crystals. The detector characteristics of the Ge (${\gamma}$) detectors were comparable to those of thin Ge(Li) detectors and high purity germanium detectors. The thermal stability of the Ge (${\gamma}$) detector showed a feasibility for ambient temperature storage.

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Tin Germanium Sulfide Nanoparticles for Enhanced Performance Lithium Secondary Batteries (고성능 리튬 이차 전지를 위한 황화 주석 저마늄 (SnxGe1-xS) 나노입자 연구)

  • Cha, E.H.;Kim, Y.W.;Lim, S.A.;Lim, J.W.
    • Journal of the Korean Electrochemical Society
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    • v.18 no.1
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    • pp.31-37
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    • 2015
  • Composition-controlled ternary components chalcogenides germanium tin sulfide ($Sn_xGe_{1-x}S$) nanoparticles were synthesized by a novel gas-phase laser photolysis reaction of tetramethyl germanium, tetramethyl tin, and hydrogen sulfide mixture. Subsequent thermal annealing of as-grown amorphous nanoparticles produced the crystalline orthorhombic phase nanoparticles. All these composition-tuned nanoparticles showed excellent cycling performance of the lithium ion battery. The germanium sulfide nanoparticles exhibit a maximum capacity of 1200 mAh/g after 70 cycles. As the tin composition (x) increases, the capacity maintains better at the higher discharge/charge rate. This novel synthesis method of tin germanium sulfide nanoparticles is expected to contribute to expand their applications in high-performance energy conversion systems.

Effect of Ge(Germanium) Treatment on Rice Quality (게르마늄 처리가 쌀 품질에 미치는 영향)

  • Kim, Duk-Hee;Kim, Kwang-Ok
    • The Korean Journal of Food And Nutrition
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    • v.22 no.4
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    • pp.701-707
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    • 2009
  • This study was conducted to investigate the effects of Ge(germanium) treatment on rice quality. Rice samples were divided into the following treatment groups: control(CON: cultivated without Ge), Ge-1(cultivated with 200 kg of rough stone powder containing 1.6 mg/kg germanium per 10 ha), and Ge-2(cultivated with 500 kg of rough stone powder containing 1.6 mg/kg germanium per 10 ha). The mean total Ge level in the Ge-2 sample was 20.47 ppb. The levels of Ca and Na in the Ge-2 rice increased by 65.12 and 110.28%, respectively, when compared to the control, whereas the Zn, Mn, Fe, Mg and K content decreased by 11.44~30.50%. No significant difference in the percentage weight of C and O was observed among samples. The order of the percentage weight of P, S, and Cl was Ge-2>Ge-1>CON. The free amino acids were higher in samples from the Ge-1 and Ge-2 groups than in samples from the control. The GABA($\gamma$-aminobutyric acid) amount in the Ge-2 products was significantly high compared to other groups. The micro structure of Ge-2 showed a firmer network than the control and had a macroporous structure. Conversely, the Ge-2 products had higher scores for stickiness, hardness and overall taste when compared to the other groups. These results suggest that rice treated with rough stone powder containing germanium can be used in the production of commercially-desired functional rice.

Germanium Increases Alveolar Macrophage Engulfment of Apoptotic Neutrophils in Acute Lung Injury Induced by Endotoxin (내독소로 유도된 급성 폐 손상에서 게르마늄의 투여로 인한 호중구 세포사의 증가)

  • Cho, Hyun-Gug
    • Applied Microscopy
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    • v.35 no.4
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    • pp.84-90
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    • 2005
  • Neutrophils that influx into the alveolar spaces from circulatory bloods play a important role in pathogenesis of acute lung injury. During the acute inflammatory phase, in order to investigate the acceleration of macrophage phagocytosis to the neutrophils is able to reduce the neutrophil-derived acute lung injury, endotoxemia was induced by insufflation of lipopolysaccharide intratracheally and organic germanium was injected intraperitoneally after endotoxin treatment. At 5 h after endotoxin treatment, lung weight and BAL protein concentration are significantly increased (p<0.001) compared to sham, and that was remarkedly decreased (p<0.001, p<0.01) by injection of germanium. In addition germanium treatment resulted to decreased the number of alveolar PMNs and to increase the percentage of engulfed neutrophils by alveolar macrophages. These observations indicate that organic germanium may have a role of reduction to neutrophil-derived acute lung injury in endotoxemia.

Chest Wall Thickness Measurement of the LLNL Phantom for Ce Detectors (Ce 검출기를위한 LLNL 팬텀의가슴벽두께측정)

  • Lee, Tae-Young;Lee, Jong-Il;Chang, Si-Young
    • Journal of Radiation Protection and Research
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    • v.25 no.1
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    • pp.3-9
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    • 2000
  • The Korea Atomic Energy Research Institute acquired the Lawrence Livermore National Laboratory phantom for calibration of germanium detectors used for in vivo measurement of radionuclides deposited in human lungs. The manufacturer inscribed concentric circles as a phoswich detector positioning guides on the phantom's torso plate and its overlay plates, and provided the effective thickness of the chest wall for each plate measured at locations over the circles. However, since the germanium detectors are of different sizes, the areas considered for phoswich detectors were no. longer applicable for the locations of the germanium detectors on the phantom. Therefore, we re-evaluated the effective thickness of the phantom to determine if the manufacturer' s data are valid for germanium detectors in use for in vivo lung counting or if new values must be implemented. Differences no more than 3% in effective thickness were found between the germanium detector regions to be used at the Korea Atomic Energy Research Institute and the phoswich detector regions prescribed by the manufacturer.

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