Kang, Su Yeon;Kim, So Yeon;Cheong, Seong Ihl;Seo, Chang Hee;Park, Hun Whee;Rhim, Ji Won
Membrane Journal
/
v.23
no.4
/
pp.283-289
/
2013
Poly(vinyl alcohol) (PVA) coating solution containing glutaraldehyde (GA) and maleic anhydride (MA) as crosslinking agents was coated onto hydrolyzed poly acrylonitrile (PAN) hollow fiber membranes. The permselectivities of the resulting composite membranes prepared varying the reaction temperature and the concentration of the crosslinking agents were tested for 90 wt% ethanol aqueous mixtures by the pervaporation technique at $60^{\circ}C$. In general, the flux decreased while the selectivity increased for the increases of the reaction temperature and the crosslinking concentration. In case of GA as a crosslinking, the flux $165g/m^2hr$ and the separation factor 81 were obtained at GA 11 wt% and the reaction temperature $120^{\circ}C$. And for the case of MA, the flux $174g/m^2hr$ and the separation factor 73 were obtained at MA 11 wt% and the reaction temperature $120^{\circ}C$.
Park, In-Sick;Ahn, Sang-Hyun;Chung, Jae-Man;Kang, Yun-Ho;Lee, Hai-Poong;Seo, Gwi-Moon;Hong, Young-Ki;Kim, Ho-Hyun;Kim, Jin-Tack
The Journal of Dong Guk Oriental Medicine
/
v.7
no.2
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pp.97-105
/
1999
Hepatic tissues of ICR mouse were intraperitoneally injeced with Colpomenia bullosa(CB) Extract after Triton WR-1339(TX) injection were observed to investigate the antihyperlipermic effect of CB extract for hyperlipidemic hepatic tissue caused by destruction of lipid metabolism. The hepatic tissues were obtained at hour-24, 48, and 72 after TX injection with CB extract treatment. And then these specimen were fixed in 10% neutral buffer solution and were cryocut. The tissue stained by H&E for general morphology and sudan black B for lipid distribution. The increase of hepatocyte havinig meshlike cytoplasm were shown in all hepatic lobules after TX injection and the hepatic plates were disappeared in the region of meshlike hepatocyte aggregation. But the hepatocyte having meshlike cytoplasm were disappeared and hapatic plate were rearranged in CB extract injected mouse. The number of blue black colored lipid drop in hepatic cytoplasm of mouse injected with TX were increased and the size of lipid drop were enlarged. But the number of lipid drop in hepatic cytoplasm of mouse treated CB extract were decreased and the size of lipid drop were diminished. As results indicated that the accumulation of lipid drop caused by TX injection were mitigated by the antihyperlipidermic effect of CB extract.
Seabed may undergo large excess pore water pressure in the case of long duration of high wave loading. This excess pore water pressure may reduce effective stress and, consequently, the seabed may liquefy. Thus, it is necessary to develop a numerical technique which can precisely evaluate the dynamic response of seabed due to wave action. In this study, a new numerical technique named mixed model (2D NIT & FLIP models) was proposed. The dynamic wave pressure and water flow velocity acting on the boundary between seabed and the wave field was estimated using 2D-NIT model. This result was used as input data in FLIP program for investigation of dynamic response of seabed. To secure the reliability of the mixed model, the numerical analysis results of the mixed model were compared with Yamamoto's solution and Chang's experiment results. The comparison results indicated that there were some differences between them, but the general trend of the effective stress increment and the excess pore water pressure along the depth of seabed was similar to each other. Thus, this study clearly supports the plausibility of the numerical analysis of the mixed model.
This study aimed to establish the optimum culture conditions for Mozzarella cheese by using Streptococcus macedonicus LC743, a strain selected for its immunomodulatory activity. For process optimization, 1.0% and 2.0% strain was inoculated and incubated at $32^{\circ}C$ and $35^{\circ}C$, respectively. The general components, bacterial count, total solids, yields, and immunomodulatory activity of the Mozzarella cheese were investigated. When the strain was inoculated at 2.0% and incubated at $32^{\circ}C$, the product quality and immunomodulatory activity was optimal and required minimal processing time. Therefore, 2.0% of S. macedonicus LC743 starter culture was added to milk at $32^{\circ}C$, after pasteurization at $63^{\circ}C$ for 30 min, and agitated for 4~5 min after addition of $230{\mu}L/kg$ of rennet. Curd was made by setting the milk 25~35 min after addition of 0.01~0.02% calcium chloride. The curd was cut at 0.1~0.12% acidity (81 min later) and after heating the cheese to up to $43^{\circ}C$. Whey was removed at an acidity of 0.17~0.18% by agitation for 53 min. Next, cheddaring for 210 min up to an acidity of 0.6~0.65%, stretching at $72{\sim}75^{\circ}C$, and molding at $65{\sim}70^{\circ}C$ were performed, and the product was allowed to cool down to $5^{\circ}C$. Salting was done with a solution of $18{\sim}20^{\circ}B{\acute{e}}$ at $12^{\circ}C$ for 20 min and drying occurred at 80~90% relative humidity at $10^{\circ}C$ for 2~3 days.
A concept test was administered to college students and teachers to identify their understanding of chemical equilibrium and equilibrium shift. The subjects were 53 freshmen in the General Chemistry class, 28 juniors in the Physical Chemistry class and 26 seniors from a university and 10 high school teachers in Seoul. Test items include the calculations of partial pressure and concentration of the gas in the mixture, the equilibrium constant cal-culation and the prediction of equilibrium shift when an inert gas is added to the gaseous reaction system, and the equilibrium concentration calculation and the prediction of equilibrium shift when water or common ion is added to the weak acid solution. The test was focused to identify whether the subjects can predict equilibrium shift using the reaction quotient change for the situations in which Le Chatelier principle is difficult to apply. The results showed that the achievements of teachers and juniors were significantly higher than those of freshmen and seniors. Many stu-dents had difficulties in predicting equilibrium shift using the reaction quotient while they could calculate partial pres-sure and concentration for the same situation. It means they are lack of conceptual understanding of chemical equilibrium shift.
Kim, Mu-Nui;Kim, Won-Gee;Lee, Seung-Mok;Yang, Jae-Kyu
Journal of Korean Society of Environmental Engineers
/
v.31
no.9
/
pp.735-742
/
2009
The bone of spinal animals has a hydroxylapatite ($Ca_{10}(PO_4)_6(OH)_2$, HAp) structure which is well known as an excellent inorganic ion exchanger for various heavy metal ions in solutions. In this study, the reusability of cow-bone, pig-bone and fish-bone as a potential material for the removal of heavy metals in solutions was evaluated from the removal of Cu(II) ion in batch tests. The surface properties of three bones, calcined at different temperatures, were measured with SEM, XRD, FT-IR analyses. From the SEM analysis, a clear development of heterogeneity as well as pores having small diameter was observed as the calcination temperature increased. The results of X-ray diffraction analysis showed well developed crystallinity on the surface of calcined bones obtained at higher temperatures, suggesting a transform of amorphous type to crystalline type. Fourier transform infrared (FT-IR) analysis showed disappearance of water molecule on the surface of HAp and organic functional groups of the HAp with increasing the calcination temperatures. Cu(II) removal in the control test was below 15%. By the way, additional 40% increase of Cu(II) removal was observed in the presence of calcined bones. For three bones, Cu(II) removal was decreased as the calcined temperature increased. Cu(II) removal was increased as the solution pH increased due to a favorable condition for the cation exchange as well as precipitation.
Journal of Korean Society of Environmental Engineers
/
v.27
no.1
/
pp.36-42
/
2005
This study examined the feasibility of producing sulfuric acid and ammonia water from ammonium sulfate solution using two-compartment electrodialysis with a bipolar membrane (EDBM). Electrodialysis experiments were carried out with 20 wt% ammonium sulfate at different current densities and sulfuric acid concentrations in a concentrate compartment. The current efficiency increased with the current density from 25 to $100\;mA/cm^2$. Nevertheless, the efficiency was relatively low compared with that of general desalting electrodialysis, owing to the diffusion of sulfuric acid from the concentrate compartment to the diluate. The diffusion rate through the anion exchange membrane increased with the sulfuric acid concentration in the concentrate compartment, which decreased the current efficiency. Conversely, the electrical resistance decreased with increasing current density owing to the Joulian heat generated during water dissociation in the transition region of the bipolar membrane under a high electric field. From the experimental results, we concluded that operating at a higher current density is effective from the perspective of current efficiency and electrical resistance when producing sulfuric acid and ammonia water from ammonium sulfate using a two-compartment EDBM process. Further studies on the effects of increasing the sulfuric acid concentration on current efficiency are required to apply the EDBM process practically.
The rapid increase in cases of insect resistance to insecticides indicates that the contribution of present chemical control practices inevitably leads to exhaustion of available insecticide resources against key insect species. Now the problem of insecticide resistance exists worldwide among insects and mites affecting field crops and animals including human beings, ranging from minimal or absent in some developing countries, where use of insecticides has been low, to extremely severe in many developed countries. Since the occurrence of insect resistance to insecticides was firstly recognized in 1908, the increase in recent decades has been almost linear and now the number of species of insects and acarines in which resistant strains have evolved have been increased to a total of 432. Of these, $261(60\%)$ are agricultural importance and $171(40\%)$ of medical/veterinary importance. The phenomenon of insecticide resistance is asserting itself as the greatest challenge to effective chemical control of many important insect pests. Resistance of insects to insecticides has a history of nearly 80 years, but its greatest increase and its strongest impact have occurred during the last 40 years following the discovery and extensive use of synthetic organic insecticides and acaricides. The impact of resistance should be considered not only in terms of greater cost of pest control due to increased dosages and number of applications but also in terms of the ecological disruption of pest-beneficial species density relationships, the loss of investment in the development of the insecticides concerned, and socio-economic disruption in agricultural communities. Despite its grave economic consequences, the phenomenon of insecticide resistance has received surprisingly little attention in Korea. Since the study of insecticides started firstly in 1963, many entomologists have been concerned with this study. According to their results, some of the rice pests and some of the mites on orchard trees, for example, have developed worrisome level of resistance in several areas of this peninsula. With many arthropods, considerable advances in the developed countries have been made in the study of the biochemical and physiological mechanisms of resistance. Progress involves the biochemical characteristics of specific defense mechanisms, their genetics, interactions, and their quantitative and qualitative contribution to resistance. But their studies arc still inadequately known and relatively little have been contributed in terms of unique schemes of population management in achieving satisfactory pest control. It is apparent that there is no easy solution to resistance as a general phenomenon. For future challenging to effective control of insect pests which are resistant to the insecticides concerned, new insecticide groups with distinctly novel mode of action are urgently needed. It is clear, however, that a great understanding of the factors which govern the intensity of selection of field population for resistance could lead to far more permanently successive use of chemicals within the framework of integrated pest management than heretofore practiced.
Over the past few decades, considerable numbers of studies on the durability of concrete have been carried out extensively. A lot of improvements have been achieved especially in both measuring techniques as well as modeling of ionic flows. However, the majority of these researches have been performed on sound uncracked concrete, although most of in-situ concrete structures have more or less micro-cracks. It is only recent approach that the attention has shifted towards the influence of cracks and crack width on the penetration of chloride into concrete. The penetration of chlorides into concrete through the cracks can make a significant harmful effect on reinforcement corrosion. On the other hand, a general acceptable crack width of 0.3 mm has been recognized for keeping the serviceability of concrete structures in accordance with a lot of codes. However, there seems to be rare established description to explain the critical crack width in terms of the durability of concrete. To make a bad situation worse, there is little agreement on critical crack width among a few of literatures for this issue. Critical crack width is still controversial problem. Nevertheless, since the critical crack width is important key for healthy assessment of concrete structures exposed to marine environment, it should be established. The objective of this study is to define a critical crack width. The critical crack width in this study is designed for a threshold crack width, which contributes to the first variation of chloride diffusion coefficient in responsive to the existence of cracks. A simple solution is formulated to realize the quantifiable parameter, chloride diffusion coefficient for only cracked zone excluding sound concrete. From the examination on the trend of chloride diffusion coefficient of only cracked zone for various crack widths, a critical crack width is founded out.
KSCE Journal of Civil and Environmental Engineering Research
/
v.3
no.4
/
pp.95-107
/
1983
The general purpose programs are in their fixed algorithm and theory of mechanics which can not be altered without painful program modifications. Users are usually guided by user's manual for data input. The several symbolic manipulation programs for structural analysis are introduced recently. These programs allow users to include a wide class of solution algorithm and to specify, by means of some symbolic manipulation, a combination of analytical steps to suit a particular problem. As they can solve a single domain problem, a large computer is usually needed. The scope of this study is to develop an efficient symbolic manipulation program with space beam element, plate bending element and eigen value routines. The incorporated Substructure capability and generation capability of finite element characteristic arrays (e.g., stiffness matrix, mass matrix) enables users to analyse multidomain problem with small computer. The program consists of modulized independent processors, each having its own specific function and is easily modified, eliminated and added. The processors are efficiently handling data by the Data base approach which is the concept of integrated program network(IPN).
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