• 한국대기환경학회지
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• 제26권3호
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• pp.318-329
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• 2010

The purpose of this study was to develop the $PM_{2.5}$ source profiles for diesel and gasoline-powered vehicles, which contained mass abundances in terms of mass fraction of $PM_{2.5}$ of chemical species. Seven diesel-powered vehicles and nine gasoline-powered vehicles were sampled from a chassis dynamometer exhaust dilution system. The species measured were water-soluble ions, elements, elemental carbon (EC), and organic carbon (OC). From this study, the large abundances of EC (54.5%), OC (26.0%), ${SO_4}^{2-}$ (1.5%), ${NO_3}^-$ (0.8%), and S (0.6%) were observed from the diesel-powered vehicle exhaust showing that carbons were dominant species. The gasoline-powered vehicle exhaust emitted large abundances of OC (38.3%), EC (4.2%), ${SO_4}^{2-}$ (3.6%), ${NH_4}^+$ (3.5%), and ${NO_3}^-$ (3.0%). The abundances of ${SO_4}^{2-}$, ${NH_4}^+$, and ${NO_3}^-$ from gasoline vehicle were greater than those of diesel vehicle. The emissions of P, S, Ca, Fe, and Zn among trace elements for the gasoline vehicle were greater than 1% of the $PM_{2.5}$ mass unlike those for the diesel vehicle. Particularly, the fraction of Zn was five times higher from the gasoline vehicle than that from the diesel vehicle. The source profiles developed in this work were intensively examined by applying chemical mass balance model.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 2005년도 추계학술대회 논문집
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• pp.93-96
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• 2005

• 한국환경과학회지
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• 제16권2호
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• pp.179-185
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• 2007

Nitrous oxide ($N_2O$) is an important trace gas in the atmosphere not only because of its large global warming potential (GWP) but also because of the role in the ozone depletion in the stratosphere. It has been known that soil is the largest natural source of $N_2O$ in global emission. However, anthropogenic sources contributing from industrial section is likely to increase with rising the energy consumption, and transportation as well. In this study, a total of 32 gasoline-powered passenger vehicles (ranging from small to large engine's displacement and also ranging from aged catalyst to new catalyst) were tested on the chassis dynamometer system in order to elucidate the characteristics of $N_2O$ emission from automobiles under different driving modes. Ten different driving modes developed by NIER were adapted for the test. The results show that the $N_2O$ emission decreases logarithmically with increase of vehicle speed over the all test vehicles ($N_2O$) emission = -0.062 Ln (vehicle speed) + $0.289,\;r^2=0.97$). It revealed that the larger engine's displacement, the more $N_2O$ emission were recorded. The correlation between $N_2O$ emission and catalyst aging was examined. It found that the vehicles with aged catalyst (odometer record more than 8,0000km) emit more $N_2O$ than those with new catalyst. Average $N_2O$ emission was $0.086{\pm}0.095\;N_2O-g/km$ (number of samples=210) for the all test vehicles over the test driving modes.

• 에너지공학
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• 제18권1호
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• pp.69-73
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• 2009

자동차로부터 배출되는 배출가스의 규제가 최근 더욱 강화되고 있다. 이러한 엄격해지는 규제는 배출가스를 줄이는 대체연료의 개발에 더욱 박차를 가하게 된다. 본 연구는 가솔린, 디젤, LPG 연료를 사용하는 동급의 자동차를 이용하여 배출가스의 특성을 분석 비교하였다. 테스트 모드로는 최근 국내와 북미 배출가스의 주행모드로 사용되는 CVS-75모드를 사용하였다. 배기 특성은 주행조건에 하에서 연구되어졌다. 사용연료인 가솔린, 디젤, LPG연료에 따라 THC, CO, NOx의 배출가스의 특성을 연구했다. 연구결과, LPG연료에 비해 가솔린자동차가 9.8%의 배출가스 감소, 디젤자동차는 12.2% 증가를 나타냈다. 또한 CVS모드에서 가솔린과 LPG는 phase 1의 냉간시동구간에서 THC와 CO는 80%이상을 나타낸다.

• 한국수소및신에너지학회논문집
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• 제15권4호
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• pp.274-282
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• 2004

This study focused on the development of high performance catalyst for autothermal reforming (ATR) of gasoline to produce hydrogen. The ATR was carried out over MgO/Al2O3 supported metal catalysts prepared under various experimental conditions. The catalysts before and after reaction were characterized by N2-physisorption, CO-chemisorption, SEM and XRD. The performance of supported multi-metal catalysts were better than that of supported mono-metal catalysts. Especially, it was observed that the conversion of iso-octane over prepared Ni/Fe/MgO/Al2O3 catalyst was 99.9 % comparable with commercial catalyst (ICI) and the selectivity of hydrogen over the prepared catalyst was 65% higher than ICI catalyst. Furthermore, it was identified that the sulfur tolerance of prepared catalyst was much better than ICI catalyst based on the ATR reaction of iso-octane containing sulfur of 100 ppm. Therefore, Ni/Fe/MgO/Al2O3 catalyst can be applied for a fuel reformer, hydrogen station and on-board reformer in furl cell powered vehicles.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2009년도 제40회 하계학술대회
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• pp.947_948
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• 2009

In an attempt to minimize the air pollution caused by CO2, $NO_X$x, and $SO_X$ and the fuel cost, the auto industries and researchers recently are looking into replacing the diesel and gasoline cars with hybrid electric vehicles, plug-in electric vehicles, or battery powered electrical vehicles. This paper reports the technical status of the primary components such as batteries, motors, power control units and auxiliary parts to be used for electric vehicles.

• Journal of Korean Society for Atmospheric Environment
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• 제24권E1호
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• pp.32-43
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• 2008

Source samples were collected to construct source profiles for 9 different source types, including soil, road dust, gasoline/diesel-powered vehicles, a municipal incinerator, industrial sources, agricultural/biomass burning, marine aerosol, and a coal-fired power plant. Seasonal profiles for 'Chinese aerosol', aerosols derived from the urban area of China, were reconstructed from seasonal $PM_{2.5}$ compositions reported in Beijing, China. Ambient $PM_{2.5}$ at a receptor site was also measured during each of the four seasons, from April 2001 to February 2002, in Seoul. The Chemical Mass Balance receptor model was applied to quantify source contributions during the study period using the estimated source profiles. Consequently, motor vehicle exhaust (33.0%), in particular 23.9% for diesel-powered vehicles, was the largest contributor affecting the $PM_{2.5}$ levels in Seoul, followed by agricultural/biomass burning (21.5%) and 'Chinese aerosol' (13.1%), indicating contributions from long-range transport. The largest contributors by season were: for spring, 'Chinese aerosol' (31.7%); for summer, motor vehicle exhaust (66.9%); and for fall and winter, agricultural/biomass burning (31.1% and 40.1%, respectively). These results show different seasonal patterns and sources affecting the $PM_{2.5}$ level in Seoul, than those previously reported for other cities in the world.

• 한국생산제조학회지
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• 제9권3호
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• pp.136-142
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• 2000

With the significant growth of the number of vehicles environmental problems is raised. NOx SOx, and PM emissions in diesel powered vehicles are larger than that in gasoline because the development of pollutants reduction techniques has not been yet achieved. So it is need to develop after-tratment or to convert into alternative fuel to satisfy emission regula-tion. Among the after-treatment systems to reduce the diesel emissions studies with diesel oxidation catalyst(DOC) are done greatly. In this study using DOC reduction efficiency with the change of temperature and catalyst loading was calculated through measurements of CO, HC, PM. and SOX.

• 에너지공학
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• 제13권2호
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• pp.161-165
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• 2004

Evaporative emissions from gasoline powered vehicles continue to be a major concern. The performance of carbon canister in evaporative emission control systems has become an important aspect of overall fuel system development and design. A vehicle's evaporative emission control system is continuously working, even when the vehicle is not running, due to generation of vapors from the fuel tank during ambient temperature variations. In this study, the effects of evaporative emissions on the engine performance were investigated. The experimental results show the effectiveness of this system for future exhaust emissions and enhanced evaporative emissions. This paper discusses the evaluation on the relationship between carbon canister condition and engine performance while engine is running.

• Journal of Electrochemical Science and Technology
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• 제6권2호
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• pp.50-58
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• 2015

There is a great deal of current interest in the development of rechargeable batteries with high energy storage capability due to an increasing demand for electric vehicles (EVs) with driving ranges comparable to those of gasoline-powered vehicles. Among various types of batteries under development, a Li-O₂ battery delivers the highest theoretical energy density; thus, it is considered a promising energy storage technology for EV applications. Despite the fact that extensive research efforts have been made in the field of Li-O₂ batteries in recent years, there are still many technical challenges to be addressed, such as low round-trip efficiency, poor reversibility, and poor power capability. In this article, we provide a short review on the fundamental electrochemistry of Li-O₂ batteries with non-aqueous electrolytes and on electrode materials that have been employed in cathodes (oxygen electrodes). The major aim of this mini-review is to highlight the physical and electrochemical origins of scientific challenges facing Li-O₂ battery technology and to overview the strategies proposed to overcome them.