• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.10 no.1
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• pp.58-73
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• 2000

Objectives : This study was performed to evaluate BTEX exposure to gas station service attendants and the critical affect of benzene and MtBE airborne concentration. Methods : the degree of exposure to airborne BTEX and MtBE was examined in the service attendants at seven gas stations across the country during a summer season. The TWAs(time-weighted averages) of atmospheric concentration of substances in personal and area samples, were calculated. The component ratio of BTEX and MtBE in the samples of bulk gasoline from each station studied was also measured. Results : The airborne concentrations of BTEX and MtBE showed a lognormal distribution and The TWA concentrations of benzene in personal samples from each station were 0.089 ppm - 0.18 ppm, and those of toluene were 0.097 ppm - 0.2 ppm. The average TWA concentrations of xylene and ethyl benzene was 0.03 ppm and 0.001 ppm, respectively. The TWA concentrations of MtBE were 0.4 ppm - 1.3 ppm. The volume concentrations of MtBE, toluene, ethyl benzene and xylene in the bulk gasoline samples were 3 - 7.4 %, 3 - 12 %, 0.64 % and 1.5 - 10 %, respectively. Conclusions : The benzene concentration was detected to exceed the ACGIH threshold benzene level of 0.5 ppm, in one of 74 personal and area samples. MtBE, a substitute for aromatic compounds such as benzene in gasoline, was found to bring about a greater chance of exposure to carcinogen, due to its high vapor pressure and carcinogenicity.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.29 no.3 s.234
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• pp.356-367
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• 2005

The spray characteristics of DISI injector have a great role in gasoline engine efficiency and emission. Thus, many researchers have studied to investigate the spray characteristics of swirl and slit injectors that are used in a DISI engine. In this study, we tried to provide spray parameters, which affect on the spray characteristics such as injection pressure, ambient pressure and ambient temperature. In addition, we calculated $t_{b}\;and\;t_{c}$ to investigate the break up mechanism of test injectors and obtained $C_{v}$ to evaluate the spray characteristics. As the ambient pressure increases in case of slit injector, $C_{v}$ decreases. The laser-induced exciplex fluorescence (LIEF) technique, which is based on spectrally resolved two-color fluorescent emissions, has applied to measure the liquid and vapor phases for on evaporating spray simultaneously. The TMPD/naphthalene proposed by Melton is used as a dophant to detect exciplex signal. The temporal and spatial distribution of liquid and vapor phases during the mixture formation process was measured by this technique. In the LIEF technique, the vapor phase is detected by the monomer fluorescence while the liquid phase is tracked by the exciplex fluorescence. From this experiment, we found that the spray area of the vapor phase is increased with elapsed time after injection and the area of liquid is decreased when the ambient pressure is 0.1MPa. However, the area tends to increase until the end of injection when the ambient pressure is 1.0MPa.

• Korean Chemical Engineering Research
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• v.43 no.3
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• pp.387-392
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• 2005

Recently, dimethyl carbonate (DMC) is considered as an alternative of MTBE (methyl tert-butyl ether), additive for non-leaded gasoline with their fast biodegradation rate and low toxicity. DMC is usually synthesized so far by oxidative carbonylation of methanol, and recently developed synthetic process is also started with methanol. Since the phase equilibria of the system, consisted of DMC and methanol or other reaction products on different temperature and pressure is necessary for the optimum separation process design and operation. However the reported phase equilibria and physical properties for DMC mixtures in the Dortmund Data Bank (DDB; thermodynamic property data bank) are quite rare. Besides, infinitely dilute properties are not found. In this work, isothermal vapor-liquid equilibria at 333.15 K for methanol+DMC binary system and mixing properties, excess molar volume and viscosity deviation at 298.15 K are directly measured and correlated. Additionally, infinitely dilute activity coefficient of methanol in the DMC solvent at three different temperatures are measured and compared with predicted values using modified UNIFAC (Dortmund).

• Transactions of the Korean Society of Automotive Engineers
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• v.11 no.1
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• pp.87-94
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• 2003

Recently, LPLi(Liquied-Phase LPG injection) system is studied for the new stringent emission regulations. But , there are some problems to be solved such as injector tip icing and fuel leakage for LPLi system development. In this paper, the icing problem near injector tip which leads to difficulty of accurate A/F control was studied and reported. Icing of injector tip and port wall was observed at all the cases in this study regardless of injection duration and angle, air humidity change. The spray angle of LPLi was observed approximately two times wider than that of Gasoline injection. This makes the LPLi spray collide with intake port around injector tip. Temperature of the wetted area was decreased and icing of water vapor contained in intake air because of evaporation of the fuel film. The ice of the injector tip and port wall is also affected by the materials related to heat transfer.

• Fire Science and Engineering
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• v.10 no.1
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• pp.3-9
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• 1996

Electrostatic charge is generated in large scale or high speed processes dealing with materials with large resistance, or under complicated condition. Fire and explosion often occur due to electrostatic charge accumulated in flammable gases, vapor, liquids and powder. It is usually very difficult to verify the cause of accidents as well as the prevention. In this study, it is shown that the needle electrode needs the electrode gap from 1.8mm to 3.8mm, sphere electrode and plate electrodes need the electrode gap of 1.9mmfor the minimum ignition energy. The sphere electrode and the plate electrode requires 12.8mJ and 3.2mJ of minimum ignition energy respectively with the electrode gap of 1.1mm. The ignition voltage rises to very large value as the ground resistance increases.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2001.05a
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• pp.75-90
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• 2001

For the purpose of helping development of a GDI(Gasoline Direct Injection) engine, the in-cylinder phenomena, such as the spray behaviors and fuel distributions, unburned fuel, and flame characteristics were investigated in a single cylinder GDI engine. The GDI engine was equipped with a swirl type electronic injector and SCV(Swirl Control Valve). PLIF(Planar Laser Induced Fluorescence) system with KrF Excimer laser was used for the measurements of the fuel distributions. The effects of the injector specifications, such as the spray cone angle and the offset angle on the fuel distributions and combustion characteristics were investigated. As a result, it was found that the injected fuel spray collided with the bottom of the bowl and moved upward along the exhaust side wall of the piston bowl. This fuel vapor played a important role in the instance of spark ignition. The injector specifications has a great influence on the flame characteristics.

• Proceedings of the Membrane Society of Korea Conference
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• 2004.05a
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• pp.98-101
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• 2004

Utilization of biomass resources has considerable contribution to the reduction of carbon dioxide emission. Ethanol is one of the biomass products and is used as an additive to gasoline in several countries. Conventional process to produce ethanol involves energy-intensive azeotropic distillation. Pervaporation (PV) or vapor permeation (VP) is considered to be an alternative separation process to the conventional process.(omitted)

• Journal of Advanced Marine Engineering and Technology
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• v.35 no.5
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• pp.566-575
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• 2011

Since LPG (Liquefied petroleum gas) fuel supply system has an advantage of low emission characteristics, many studies have been conducted. In spite of the advantage of LPG supply system, a higher vapor pressure and lower viscosity than diesel or gasoline fuel may cause unstable running of fuel pump by the deterioration in lubrication performance and chemical reaction with rubber parts than that of diesel and gasoline fuel. Therefore its physical properties can cause the deterioration of durability. In this research, we developed an external type LPG pump which has the advantage of the price competitiveness and the convenient maintenance for LPLi system. The experiments were carried out in order to assess characteristics of the external type fuel pump at different fuel composition and temperature. As a result, there aren't any differences between internal and external type pump performance. It is observed that the same level of efficiency was maintained for both pumps as flow rate was increased with higher fuel temperature and more contents of propane in the fuel. And the pressure difference in LPLi system is maintained at constant with the various fuel compositions and temperatures due to their own characteristics of fuel supply system.

• Journal of the Korean Institute of Gas
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• v.12 no.2
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• pp.12-17
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• 2008

The In recent years, the need for more fuel-efficient and lower-emission vehicles has driven the technical development of alternative fuels such as LPG (Liquefied Petroleum Gas) which is able to meet the limits of better emission levels without many modifications to current engine design. LPG has a high vapor pressure and lower viscosity and surface tension than diesel and gasoline fuels. These different fuel characteristics make it difficult to directly apply the conventional gasoline or diesel fuel pump. In this study, experiments are performed to get initial performance and efficiency of the fuel pump under different condition of the temperature and composition of fuel. The characteristics of vane type fuel pump were investigated to access the applicability on LPLi engine.

• International Journal of Automotive Technology
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• v.5 no.4
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• pp.221-238
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• 2004

Wall interactions of direct injection spray were investigated using laser-sheet imaging, shadowgraphy, wetted footprint and phase Doppler interferometry techniques. A narrow-cone high-pressure swirl injector is used to inject iso-octane fuel onto a plate, which has three different impact angles inside a pressurized chamber. Heated air and plate conditions were compared with unheated cases. Injection interval was also varied in the heated case to compare dry- and wet- wall impingement behaviors. High-speed macroscopic Mie-scattering images showed that presence of wall and air temperature has only minor effect on the bulk spray structure and penetration speed for the narrow-cone injector tested. The overall bulk motions of the spray plume and its spatial position at a given time are basically unaffected until a few millimeters before impacting the wall. The surface properties of the impact surface, such as the temperature, the presence of a preexisting liquid film also have a small effect on the amount of wetting or the wetted footprint; however, they have strong influence on what occurs just after impact or after a film is formed. The shadowgraph in particular shows that the plate temperature has a significant effect on vapor phase propagation. Generally, 10-20% faster horizontal vapor phase propagation is observed along the wall at elevated temperature condition. For impingement onto a preexisting film, more splash and evaporation were also observed. Contrary to some preconceptions, there is no significant splashing and droplet rebounding from surfaces that are interposed in the path of the DI gasoline spray, especially for the oblique impact angle cases. There also appears to be a dense spray front consists of large sac spray droplets in the oblique impact angle cases. The bulk of the spray is not impacted on the surface, but rather is deflected by it The microscopic details as depicted by phase Doppler measurements show that the outcome of the droplet impaction events can be significantly influenced. Only droplets at the spray front have high enough Weber numbers for wall impact to wet, splash or rebound. Using the sign of vertical velocity, the time-resolved downward droplets and upward droplets are compared. The Weber number of upward moving droplets, which seldom exceeds unity, also decreases as the impact angle decreases, as the droplets tend to impact less and move along the wall in the deflected spray plume.