• 제목/요약/키워드: Gas-phase Combustion

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燃料油 燃燒에 미치는 有機金屬鹽의 助燃效果 (Combustibility Improving Effect of Organometallic Salt for Fuel Oil)

  • 강용식
    • 대한화학회지
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    • 제15권6호
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    • pp.330-347
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    • 1971
  • Catalytic effects of metallic salts on the combustion of diesel fuel oil have been studied. In the case of organometallic salt, the active species are the metallic oxides resulted from combustion of the salts. The oxides act only on the residual solid carbon produced from the fuel oil combustion. The catalytic activity can be explained with the semiconductor theory just as in the case of the gas phase reaction. The chemical rate constant of the combustion of carbon, the soot from diesel fuel oil, is found to be $k_c=1.1{\times}10^4\;exp$ (-16,600/T) below $800^{\circ}K$. By addition of metallic oxides, the rate constant increases remarkably. This work has substantiated the belief that the effect of the metallic salts on the fuel oil combustion can conveniently be studied by checking directly the effect of the corresponding metallic oxide on the soot carbon.

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산화제 과잉 예연소기 냉각 성능 수치 해석 (Numerical Analysis on Cooling Characteristics of Oxidizer-Rich Preburner)

  • 이선미;하성업;이수용
    • 한국추진공학회지
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    • 제17권3호
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    • pp.67-75
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    • 2013
  • 케로신-액체산소 로켓 엔진에 적용되는 산화제 과잉 예연소기의 냉각 성능 확인을 위한 수치 해석을 수행하였다. 예연소기 1차 연소구역을 상사하기 위하여 분사기 배열에 따른 혼합비를 바탕으로 연소가스 물성치를 계산하였고, 냉각제로서 채널을 흐르는 산소의 물성치는 실제기체 조건에 대하여 적용하였으며, 1차 연소구역과 냉각제로 쓰인 액체산소의 혼합과정은 다상혼합모델을 적용하였다. 수치 해석으로 계산된 결과를 연소시험과 비교하였으며, 이를 통하여 재생냉각 채널과 연소실에서의 물성 등을 정량적으로 파악할 수 있었다.

DME 예혼합 압축 착화 엔진에서 밸브 양정과 개폐시기가 내부 배기가스 재순환과 연소에 미치는 영향 (Effect of Valve Lift and Timing on Internal Exhaust Gas Recirculation and Combustion in DME Homogeneous Charge Compression Ignition Engine)

  • 장진영;배충식
    • 한국자동차공학회논문집
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    • 제17권4호
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    • pp.93-100
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    • 2009
  • Intake/exhaust valve timing and exhaust cam lift were changed to control the internal exhaust gas recirculation (IEGR) and combustion phase of homogeneous charge compression ignition (HCCI) engine. To measure the IEGR rate, in-cylinder gas was sampled during from intake valve close to before ignition start. The lower exhaust cam made shorter valve event than higher exhaust cam and made IEGR increase because of trapping the exhaust gas. IEGR rate was more affected by exhaust valve timing than intake valve timing and increased as exhaust valve timing advanced. In-cylinder pressure was increased near top dead center due to early close of exhaust valve. Ignition timing was more affected by intake valve timing than exhaust valve timing in case of exhaust valve lift 8.4 mm, while ignition timing was affected by both intake and exhaust valve timing in case of exhaust valve 2.5 mm. Burn duration with exhaust valve lift 2.5 mm was longer than other case due to higher IEGR rate. The fuel conversion efficiency with higher exhaust valve lift was higher than that with lower exhaust valve lift. The late exhaust and intake maximum open point (MOP) made the fuel conversion efficiency improve.

제철 소결기 배드 내 연소 및 열전달 모델링;인자 변화에 의한 계산 결과 평가 (Modeling of Combustion and Heat transfer in the Iron Ore Sintering Bed;Evaluation of the Calculation Results for Various Cases)

  • 양원;류창국;최상민
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2002년도 제24회 KOSCO SYMPOSIUM 논문집
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    • pp.171-178
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    • 2002
  • Numerical simulations of the condition in the iron ore sintering bed are performed for various parameters. The sintering bed is modelled as an unsteady one-dimensional progress of solid material, containing cokes and iron ore. Bed temperature, solid mass and gas species distributions are predicted for various parameters of moisture contents, cokes contents and air suction rates, along with the various particle diameters of the solid for sensitivity analysis. Calculation results show that influences of these parameters on the bed condition should be carefully evaluated for achievement of the self-sustaining combustion without the high temperature section, which can cause the excessive melting in the bed. It suggests that the model should be extended to consider the bed structural change and multiple solid phase, which can treat the inerts and fuel particles separately.

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희체가스 가중합산모델을 적용한 미분탄 연소의 해석 (Modeling of a Pulverized Coal Combustion With Applying WSGGM)

  • 유명종;백승욱
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1999년도 제19회 KOSCO SYMPOSIUM 논문집
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    • pp.155-163
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    • 1999
  • A numerical study for simulating a swirling pulverized coal combustion in axisymmetric geometry is done here by applying the weighted sum of gray gases model (WSGGM) approach with the discrete ordinate method (DOM) to model the radiative heat transfer equation. In the radiative transfer equation, the same polynomial equation and coefficients for weighting factors as those for gas are adopted for the coal/char particles as a function of partial pressure and particle temperature. The Eulerian balance equations for mass, momentum, energy, and species mass fractions are adopted with the standard ${\kappa}-{\varepsilon}$ turbulence model, whereas the Lagrangian approach is used for the particulate phase for soot. The eddydissipation model is employed for the reaction rate for gaseous mixture, and the single-step first-order reaction model for the devolatilization process for coal. By comparing the numerical results with experimental ones, the models used here are confirmed and found to be one of good alternatives for simulating the combustion as well as radiative characteristics.

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초과엔탈피 화염의 점근 해석 (An Asymptotic Analysis of Excess Enthalpy Flame)

  • 이대근
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
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    • pp.135-137
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    • 2014
  • Excess enthalpy flame propagating an porous inert medium, which recirculate exhaust heat to the upstream cold mixture, is theoretically analyzed. Using the activation-energy asymptotics, the flame structure is divided into the thin reaction and the gas-phase preheat zone, as is traditionally done. Ahead and behind of the two, there exist an outer preheat zone, where heat is convectively transferred from solid to gas, and a downstream re-equilibrium zone, where thermal equilibrium between phases is established. Asymptotic solutions of species and energy equations in each zone are obtained and then matched to each other, and finally the mass burning rate is obtained as a function of the flame propagation velocity with respect to the solid phase and physical properties of gas and solid.

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축방향 직접화염 가열방식 로터리킬른 성능모형 (Performance analysis modeling of axial direction direct flame rotary kiln reactors)

  • 한택진;최상민
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2013년도 제46회 KOSCO SYMPOSIUM 초록집
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    • pp.59-60
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    • 2013
  • Rotary kiln furnace is one of the most widely used gas-solid reactors in the industrial field. Although the rotary kiln is a versatile system and has different size, approach to the reactor modeling can be generalized in terms of flow motion of the solid and gas phase, heat transfer and chemical reactions on purpose. In this paper, a performance analysis example case of axial direction direct flame rotary kiln is introduced.

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비정상 증발디젤분무의 측정과 그 응용해석 (Advanced Analysis and Measurement of the Unsteady Evaporative Diesel Spray)

  • 염정국;박종상;김시범;정성식;하종률
    • 대한기계학회논문집B
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    • 제32권7호
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    • pp.529-535
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    • 2008
  • The characteristics of combustion process in an internal combustion engine are affected by the mixing process between injected fuel and ambient gas. Therefore, it is necessary to understand the mixture formation process of diesel spray. In this study, the spray structure was visualized by the exciplex fluorescence method, which can provide the simultaneous 2-D images of vapor and liquid phase in inner spray. For accurate investigation, the liquid-phase images were recorded with a 35mm still camera and CCD camera. Consequentially, it could be confirmed that the high-concentration vapor phase is formed in the region of spray tip and the edge of the liquid phase where droplets exist in the evaporating diesel spray, and the formed vapor is spread by diffusion. Also, the distribution of vapor is determined by the motion of droplets that exist in the edge of the liquid phase and the spray-tip region.

유한체적법에 의한 복잡한 형상을 갖는 3차원 가스터빈 연속기내의 복사열 전달 해석 (Prediction of Radiative Heat Transfer in a Three-Dimensional Gas Turbine Combustor with the Finite-Volume Method)

  • 김만영;백승욱
    • 대한기계학회논문집B
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    • 제20권8호
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    • pp.2681-2692
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    • 1996
  • The finite-volume method for radiation in a three-dimensional non-orthogonal gas turbine combustion chamber with absorbing, emitting and anisotropically scattering medium is presented. The governing radiative transfer equation and its discretization equation using the step scheme are examined, while geometric relations which transform the Cartesian coordinate to a general body-fitted coordinate are provided to close the finite-volume formulation. The scattering phase function is modeled by a Legendre polynomial series. After a benchmark solution for three-dimensional rectangular combustor is obtained to validate the present formulation, a problem in three-dimensional non-orthogonal gas turbine combustor is investigated by changing such parameters as scattering albedo, scattering phase function and optical thickness. Heat flux in case of isotropic scattering is the same as that of non-scattering with specified heat generation in the medium. Forward scattering is found to produce higher radiative heat flux at hot and cold wall than backward scattering and optical thickness is also shown to play an important role in the problem. Results show that finite-volume method for radiation works well in orthogonal and non-orthogonal systems.

자동차 터보충전기 터빈휠용 경량 고내열 주조 Ni기 초합금의 개발 (Development of New Ni-based Cast Superalloy with Low Density and High Temperature Capability for Turbine Wheel in Automotive Turbocharger)

  • 오키 유우타로;스미 요시노리;코야나기 요시히코
    • 한국주조공학회지
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    • 제42권6호
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    • pp.392-397
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    • 2022
  • In order to compliant the stringent exhaust emission regulations, higher fuel efficiency and cleaner exhaust gas in combustion engines have been required. To improve combustion efficiency, an exhaust gas temperature is increasing, therefore higher temperature resistance is required for components in exhaust system, especially turbine wheel in turbocharger. IN100 looks quite attractive candidate as it has high temperature properties with low density, however it has low castability due to poor ductility at high temperature. In this study, the balance of Al and Ti composition was optimized from the base alloy IN100 to improve the high temperature ductility by expanding the γ single phase region below the solidification temperature, while obtaining the high temperature strength by maintaining the volume fraction of γ' phase equivalent to IN100 around 1000℃. Furthermore, the high temperature creep rupture life increased by adding a small amount of Ta. The alloy developed in this study has high castability, low density and high specific strength at high temperature.