• Title/Summary/Keyword: Gas-phase Analysis

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Estimation of Carbon Footprint for Production of Main Crops and Contribution Analysis of Inorganic Chemical Fertilizers (주요 농작물 생산과정에서의 탄소배출량 산정 및 무기화학비료의 기여도 분석)

  • Jung, Soon-Chul;Jeong, Jae-Woo;Huh, Jin-Ho;Lee, Deog-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1279-1285
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    • 2011
  • Korea is currently underway research to estimate carbon footprint in agriculture centered on the RDA (Rural Development Administration). This study was estimated carbon footprint for major 47 crops. In addition, contribution of inorganic chemical fertilizers, main elements for production of crops were analyzed. The carbon footprint of $5.78E+00kg\;CO_2\;eq.\;kg^{-1}$ for citrus fruit in greenhouse was highest, grape in greenhouse, sweet pepper in greenhouse, ginseng, green pepper in greenhouse were followed by $4.61E+00kg\;CO_2\;eq.\;kg^{-1}$, $4.34E+00kg\;CO_2\;eq.\;kg^{-1}$, $4.23E+00kg\;CO_2\;eq.\;kg^{-1}$, $4.04E+00kg\;CO_2\;eq.\;kg^{-1}$ respectively. Next, production phase contribution of inorganic chemical fertilizer to carbon footprint of crop 1 kg were analyzed mean value 1.88%, 9.06% for single fertilizers and complex fertilizers respectively. And use phase accounted for mean value 14.24%. Therefore, to reduce the fertilization of inorganic chemical fertilizer will be reduced $CO_2$ from crop production, also greenhouse gas emissions of agricultural sector will be reduced.

Evaluation of Decomposition Characteristics of Organochlorine Pesticides Using Thermal Method (열적방법을 활용한 유기염소계 폐농약의 분해 특성 평가)

  • Kwon, Eun-Hye;Yoon, Young-Sam;Bea, Ji-Su;Jeon, Tae-Wan;Lee, Young-Ki
    • Journal of Korea Society of Waste Management
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    • v.35 no.8
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    • pp.744-753
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    • 2018
  • The Stockholm Convention, which was adopted in Sweden in 2001 to protect human health and the environment, includes regulations for Persistent Organic Pollutant Rotors such as toxic and bioaccumulatives. Currently, there are 28 types of materials. This prohibits and limits the production, use, and manufacture of products. Korea is a member of the Convention, and it is necessary to prepare management and treatment plans to address the POP trends. Thus, we experimentally investigate whether the environmentally stable incineration is achieved when the sample is thermally treated using the Lab-scale (1 kg/hr). The target samples is pesticides in liquid phase and solid phase. In this study, organic chlorinated pesticides and their thermal characteristics were analyzed. We calculated the theoretical air volume based on the element analysis results. Because the interior of the reactor is small, more than 10 times of the air ratio was injected. The retention time was set to at least 4 seconds using a margin. The incineration temperature was $850^{\circ}C$ and $1100^{\circ}C$. Thus, we experimentally investigated whether the environmentally stable incineration was achieved when the sample was thermally treated using the Lab-scale (1 kg/hr). We analyzed five types of exhaust gas; the 02 concentration was high, but the CO amount decreased. Complete combustion is difficult because of the small size of the furnace due to the nature of Lab-scale. The organic chlorine-containing pesticide had an average decomposition rate of 99.9935%. Considering the decomposition rates of organic chlorine-containing pesticide in this study, the incineration treatment at over 2 ton/hour, which is typical for a conventional incinerator, is possible. Considering the occurrence of dioxins and unintentional persistent organic pollutants, it can operate at more than $1,100^{\circ}C$.

Phytochemical analysis of Panax species: a review

  • Yang, Yuangui;Ju, Zhengcai;Yang, Yingbo;Zhang, Yanhai;Yang, Li;Wang, Zhengtao
    • Journal of Ginseng Research
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    • v.45 no.1
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    • pp.1-21
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    • 2021
  • Panax species have gained numerous attentions because of their various biological effects on cardiovascular, kidney, reproductive diseases known for a long time. Recently, advanced analytical methods including thin layer chromatography, high-performance thin layer chromatography, gas chromatography, high-performance liquid chromatography, ultra-high performance liquid chromatography with tandem ultraviolet, diode array detector, evaporative light scattering detector, and mass detector, two-dimensional high-performance liquid chromatography, high speed counter-current chromatography, high speed centrifugal partition chromatography, micellar electrokinetic chromatography, high-performance anion-exchange chromatography, ambient ionization mass spectrometry, molecularly imprinted polymer, enzyme immunoassay, 1H-NMR, and infrared spectroscopy have been used to identify and evaluate chemical constituents in Panax species. Moreover, Soxhlet extraction, heat reflux extraction, ultrasonic extraction, solid phase extraction, microwave-assisted extraction, pressurized liquid extraction, enzyme-assisted extraction, acceleration solvent extraction, matrix solid phase dispersion extraction, and pulsed electric field are discussed. In this review, a total of 219 articles published from 1980 to 2018 are investigated. Panax species including P. notoginseng, P. quinquefolius, sand P. ginseng in the raw and processed forms from different parts, geographical origins, and growing times are studied. Furthermore, the potential biomarkers are screened through the previous articles. It is expected that the review can provide a fundamental for further studies.

A Study on Future Changes of Sea Surface Temperature and Ocean Currents in Northwest Pacific through CMIP6 Model Analysis (CMIP6 모형 결과 분석을 통한 북서태평양 해면수온과 해류의 미래변화에 대한 고찰)

  • JEONG, SUYEON;CHOI, SO HYEON;KIM, YOUNG HO
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.26 no.4
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    • pp.291-306
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    • 2021
  • From the climate change scenario experiments of 21 models participating in Coupled Climate Model Inter-comparison Project Phase 6, future changes of sea surface temperature (SST) and Kuroshio in the Northwest Pacific were analyzed. The spatial feature of SST change was found to be related to the change of the current speed and spatial distribution of Kuroshio. To investigate the relationship between the change in latitude of the Kuroshio extension region, which flows along the boundary between the subtropical gyre and the subarctic gyre in the North Pacific, and the large-scale atmospheric circulation due to global warming, the zero-windstress curl line for each climate change experiment from 9 out of 21 models were compared. As the atmospheric radiative forcing increases due to the increase of greenhouse gases, it was confirmed that the zero-windstress curl line moves northward, which is consistent with the observation. These results indicate that as the Hadley Circulation expands to the north due to global warming, the warming of the mid-latitudes to which the Korean Peninsula belongs may be accelerated. The volume transport and temperature of the Tsushima Warm Current flowing into the East Sea through the Korea Strait also increased as the atmospheric radiative forcing increased.

Characterization of transparent Sb-doped $SnO_2$ conducting films by XPS analysis (XPS를 이용한 Sb-doped $SnO_2$ 투명전도막의 특성 분석)

  • 임태영;김창열;심광보;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.13 no.5
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    • pp.254-259
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    • 2003
  • In the fabrication process of transparent conducting thin films of the ATO (antimony-doped tin oxide) on a soda lime glass substrate by a sol-gel dip coating method, the effects of the $SiO_2$ buffer layer formed on the substrate and $N_2$ annealing treatment were investigated by XPS (X-ray photoelectron spectroscopy) analysis. Optical transmittance and electrical resistivity of the 400 nm-thick ATO thin films which were deposited on $SiO_2$ buffer layer/soda lime glass and then annealed under nitrogen atmosphere were 84 % and $5.0\times 10^{-3}\Omega \textrm{cm}$ respectively. The XPS analysis confirmed that a $SiO_2$ buffer layer inhibited Na ion diffusion from the substrate, resulting in prohibiting the formation of a secondary phase such as $Na_2SnO_3$ and SnO and increasing Sb ion concentration and ratio of $Sb^{5+}/Sb^{3+}$ in the film. And it was also found that $N_2$ annealing treatment leads to the reduction of $Sn^{4+}$as well as $Sb^{5+}$ however the reduction of $Sn^{4+}$ is more effective and therefore consequently results in decrease in the electrical resistivity to produce an excellent electrical properties of the film.

Comparison Analysis of Aromatic Compounds in the Aromatic Rice Germplasm by Gas Chromatography and Mass Spectrometry (Gas Chromatography-Mass Spectrometry에 의한 향미 유전자원의 방향성 화합물 비교분석)

  • Kim, Jeong-Soon;Cho, Jum-Rae;Gwag, Jae-Gyun;Kim, Tae-San;Ahn, Sang-Nag;Lee, Sok-Young
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.54 no.1
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    • pp.88-103
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    • 2009
  • The volatile and semi-volatile compounds of 5 accessions of domestic scented and 25 accessions of introduced scented were extracted by solid phase microextraction (SPME) and analyzed by gas chromatographymass spectrum (GC-MS). A total of 156 volatile and semivolatile compounds were identified from 30 accessions of aromatic rice, including 32 alcohols, 25 acids, 25 ketones, 21 hydrocarbon, 18 esters, 16 aldehydes, 4 ethers, 5 amines, 2 phenols, 2 bases, and 8 miscellaneous compounds. By UPGMA/Neighbor-join tree analysis, the thirty accessions of aromatic rice could be classified into seven groups according to the major odor or aroma compounds. Group I included indica type of Basmati varieties. Group II and Group IV included japonica type introduced scented. Group III consisted only Hyangmibyeo1ho in domestic scented. Group V and Group VII included indica type of Basmati and non-Basmati varities. Group VI included four of domestic scented of seven accessions excepted Basmati6129, Basmati 6311, and Seratus Malam.

Distribution of Persistent Organic Pollutants (POPs) in Different Sizes of Particles in the Ambient Air of the Pyeongteak Area (평택지역 대기 중 먼지 입경별 잔류성유기오염물질 분포특성 연구)

  • Kim, Dong-Gi;Woo, Jung-Sik;Kim, Yong-Jun;Jung, Hye-Eun;Park, Ju-Eun;Cho, Duck-Hee;Moon, Hee-Chun;Oh, Jo-Gyo
    • Journal of Environmental Health Sciences
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    • v.46 no.2
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    • pp.192-203
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    • 2020
  • Objectives: The concentration distributions of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), dioxin-like polychlorinated biphenlys (dl-PCBs), and polycyclic aromatic hydrocarbons (PAHs) in fine particles were investigated to provide basic data on POP behavior and composition analysis. Methods: The concentrations of PCDD/Fs, dl-PCBs, and PAHs by particle size were evaluated for TSP, PM10, and PM2.5. Also, fine dust component analysis and factor analysis were performed to identify the source of PCDD/Fs. Results: The particle size distribution was found to account for 24.3% of >10 ㎛, 14.5% of 2.5-10 ㎛, and 61.2% of <2.5 ㎛. The average contributions of coarse particles (>2.5 ㎛) and fine particles (<2.5 ㎛) were PCDD/Fs 67%, dl-PCBs 66%, benzo (a) pyrene 83% and PAHs 84%, and the contributions of fine particles (<2.5 ㎛) were higher than coarse particles (>2.5 ㎛). However, the contributions of coarse particles increased in April to September with higher temperatures, while those of fine particles increased in February to March with lower temperatures. Conclusions: Low chlorinated (4Cl-5Cl) PCDD/Fs were more adsorbed compared to coarse particles due to the influence of pollutant migration from particulate to gas phase according to temperature rise, whereas high chlorinated (6Cl-8Cl) PCDD/Fs were more adsorbed compared to fine particles. PCDD/Fs sources were assessed to be major sources of emissions, such as incineration facilities and/or open burning.

Rice Proteomics: A Functional Analysis of the Rice Genome and Applications (프로테옴 해석에 의한 벼 게놈 기능해석과 응용)

  • Woo, Sun-Hee;Kim, Hong-Sig;Song, Berm-Heun;Lee, Chul-Won;Park, Young-Mok;Jong, Seung-Keun;Cho, Yong-Gu
    • Journal of Plant Biotechnology
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    • v.30 no.3
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    • pp.281-291
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    • 2003
  • In this review, we described the catalogues of the rice proteome which were constructed in our program, and functional characterization of some of these proteins was discussed. Mass-spectrometry is the most prevalent technique to rapidly identify a large number of proteome analysis. However, the conventional Western blotting/sequencing technique has been used in many laboratories. As a first step to efficiently construct protein cata-file in proteome analysis of major cereals, we have analyzed the N-terminal sequences of 100 rice embryo proteins and 70 wheat spike proteins separated by two-dimensional electrophoresis. Edman degradation revealed the N-terminal peptide sequences of only 31 rice proteins and 47 wheat proteins, suggesting that the rest of separated protein sports are N-terminally blocked. To efficiently determine the internal sequence of blocked proteins, we have developed a modified Cleveland peptide mapping method. Using this above method, the internal sequences of all blocked rice proteins(i, e., 69 proteins) were determined. Among these 100 rice proteins, thirty were proteins for which homologous sequence in the rice genome database could be identified. However, the rest of the proteins lacked homologous proteins. This appears to be consistent with the fact that about 45% of total rice cDNA have been deposited in the EMBL database. Also, the major proteins involved in the growth and development of rice can be identified using the proteome approach. Some of these proteins, including a calcium-binding protein that tuned out to be calreticulin, gibberellin-binding protein, which is ribulose-1.5-bisphosphate carboxylase/oxygense active in rice, and leginsulin-binding protein in soybean have functions in the signal transduction pathway. Proteomics is well suited not only to determine interaction between pairs of proteins, but also to identify multisubunit complexes. Currently, a protein-protein interaction database for plant proteins(http://genome.c.kanazawa-u.ac.jp/Y2H)could be a very useful tool for the plant research community. Also, the information thus obtained from the plant proteome would be helpful in predicting the function of the unknown proteins and would be useful be in the plant molecular breeding.

The Analysis of Elasto-Plastic Thermal Stresses for Welding Part in Double Capstan Drum (더블 캡스턴 드럼의 용접부에 대한 탄소성 열응력해석)

  • 김옥삼
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.36 no.4
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    • pp.329-336
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    • 2000
  • Welding is a important technological method in mechanical engineering. $CO_2$MAG(metal active gas) welding means that metal part in double capstan drum for the inshore and costal vessels are joined by melting(with or without a filler material) or that new material is added to a metal part by melting. The thermal stresses appear due to a non-uniform temperature field, inhomogeneous material properties, external restraint and volume changes during phase transformations. In this study analysis the elasto-plastic thermal stresses distribution of welding part in double capstan drum for the inshore and costal vessels using finite element method (FBM). Therefore it calculates the numerical value that can be applied to the optimum design of welding parts and the shapes. The significant results obtained in this study are summarized as fellows. At early stage of the cooling after welding process, the abrupt thermal stresses gradient has been shown in the vicinity of welding part. In the thermal stresses analysis due to temperature gradient and heat shocking maximum stress was occurred of welding part and stresses were distributed from 54MPa~48MPa.

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Design and Analysis of a Mooring System for an Offshore Platform in the Concept Design Phase (해양플랜트 개념설계 단계에서의 계류계 초기 설계 및 해석)

  • Sungjun Jung;Byeongwon Park;Jaehwan Jung;Seunghoon Oh;Jongchun Park
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.29 no.2
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    • pp.248-253
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    • 2023
  • Most offshore platforms utilize chain mooring systems for position keeping. However, information regarding related design modification processes is scarce in literature. This study focuses on the floating liquefied natural gas (LNG) bunkering terminal (FLBT) as the target of shore platform and analyzes the corresponding initial mooring design and model tests via numerical simulations. Subsequently, based on the modified design conditions, a new mooring system design is proposed. Adjusting the main direction of the mooring line bundle according to the dominant environmental direction is found to significantly reduce the mooring design load. Even turret-moored offshore platforms are exposed to beam sea conditions, leading to high mooring tension due to motions in beam sea conditions. Collinear environmental conditions cannot be considered as design conditions. Mooring design loads occur under complex conditions of wind, waves, and currents in different environmental directions. Therefore, it is essential appropriately assign the roll damping coefficients during mooring analysis because the roll has a significant effect on mooring tension.