• Title/Summary/Keyword: Gas-phase Analysis

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DISTRIBUTIONS OF DENSITY, TEMPERATURE AND ABUNDANCES IN THE ORION NEBULA

  • Kim, Dong-Woo;Hong, Seung-Soo
    • Journal of The Korean Astronomical Society
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    • v.15 no.1
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    • pp.9-18
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    • 1982
  • To derive the distributions of electron density, temperature and gas-phase metal abundances within the Orion Nebula, we have performed a non-LTE analysis to the radio observations of hydrogen recombination lines and continuum flux over the frequency range from 0.1GHz to 100GHz. We have explicitly included the thermal balance condition in our analysis, hence our derived distributions have their internal consistencies. This enables us to derive the radial distribution of Oxygen and Nitrogen. The gas-phase concentrations of these cooling agents show about the solar values at the very central part of the nebula, then, decrease slowly outward, and finally become about one quarter of the solar values in the outer extended envelope. Such an outward decrease is interpreted as an outward increase of dust concentrations in the Orion.

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KSLV-I Plume Analysis Part III for the launch pad flame deflector performance (발사대 화염유도로 해석을 위한 KSLV-I 플룸 해석 3)

  • Hwang, Do-Keun;Nam, Jung-Won;Kim, Seong-Lyong;Kang, Sun-Il;Kim, Dae-Rae;Ra, Seung-Ho
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.375-378
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    • 2010
  • Hot and high speed plume exhausted during KSLV-I flight test is cooled down by an amount of water ejected from 'gas deflector cooling system' of launch complex to reduce the effects on the launch vehicle and launch complex. In this study, simplified axisymmetric computational calculation with 2-phase is carried out to analysis the water injection effects on flow field.

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Extraction Methods of Organic Components from Rubber Composites and Analysis of the Extract Using Gas Chromatography/Mass Spectrometry

  • Chae, Eunji;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.188-200
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    • 2019
  • Rubber articles contain various organic additives such as antidegradants, curing agents, and processing aids. It is important to extract and analyze these organic additives. In this paper, various extraction methods of organic additives present in rubber composites were introduced (solvent extraction, Soxhlet extraction, headspace extraction, and solid-phase microextraction), and the extracts were characterized using gas chromatography/mass spectrometry (GC/MS). Solvent and Soxhlet extractions are easy-to-perform and commonly used methods. Efficiency of solvent extraction varies according to the type of solvent used and the extraction conditions. Soxhlet extraction requires a large volume of solvent. Headspace sampling is suitable for extracting volatile organic compounds, while solid-phase extraction is suitable for extracting specific chemicals. GC/MS is generally used for characterizing the extract of a rubber composite because most components of the extract are volatile and have low molecular weights. Identification methods of chemical structures of the components separated by GC column were also introduced.

Numerical Analysis of Flow Characteristics in an Injection Tubing during Supercritical CO2 Injection: Application of Demonstration-scale CO2 Storage Project in the Pohang Basin, Korea (초임계 상태의 CO2 주입시 주입관내 유동 특성의 수치해석적 연구: 포항분지 중소규모 CO2 지중저장 실증 사업에 적용)

  • Jung, Woodong;Sung, Wonmo;Han, Jeongmin;Song, Youngsoo;Wang, Jihoon
    • Journal of the Korean Institute of Gas
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    • v.26 no.4
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    • pp.9-17
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    • 2022
  • This paper is the continuation of our previous paper, which we refer to as numerical analysis of phase behavior and flow properties in an injection tubing during gas phase CO2 injection. Our study in this paper show the results during supercritcal CO2 injection under the same project. Geological CO2 storage technology is one of the most effective method to decrease climate change due to high injectivity and storage capacity and economics. A demonstration-scale CO2 storage project was performed in a deep aquifer in the Pohang basin, Korea for a technological development in a large-scale CO2 storage project. A problem to consider in the early stage design of the project was to analyze CO2 phase change and flow characteristics during CO2 injection. To solve this problem, injection conditions were decided by calculating injection rate, pressure, temperature, and thermodynamic properties. For this research, we simulated and numerically analyzed CO2 phase change from liquid to supercritical phase and flow characteristics in injection tubing using OLGA program. Our results provide discharge pressure and temperature conditions of CO2 injection combined with a pressure of an aquifer.

Measuring Nano-Width of Wave Fronts in Combustion: a Numerical Approach (연소시 발생하는 파면의 나노 사이즈 두께 측정: 수치적 접근)

  • Yoh, Jai-Ick
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.20-27
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    • 2005
  • I consider the structure of steady wave system which is admitted by the continuum equations for materials that undergo phase transformations with exothermic chemical reaction. In particular, the dynamic phase front structures between liquid and gas phases, and solid and liquid phases are computationally investigated. Based on the one-dimensional continuum shock structure analysis, the present approach can estimate the nano-width of waves that are present in combustion. For illustration purpose, n-heptane is used in the evaporation and condensation analysis and HMX is used in the melting and freezing analysis of energetic materials of interest. On-going effort includes extension of this idea to include broad range of liquid and solid fuels, such as rocket propellants.

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Identification of Two-Phase Flow Patterns in a Inclined Duct Based upon a Statistical Analysis of Instantaneous Pressure Drop (순간압력강하치의 통계적 해석을 통한 경사관내 2상유동양식의 판별)

  • Lee, S.C.;Lee, J.P.;Kim, J.Y.
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.17 no.5
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    • pp.590-597
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    • 1988
  • Characteristics of flow regime transitions in inclined upwards gas-liquid two-phase flow have been investigated based upon a statistical analysis of instantaneous pressure drop curves through an orifice. The probability density functions of the curves indicate distinct patterns depending upon two-phase flow regime, which are very similar to those of horizontal two-phase. The dimensionless intensity of fluctuations of the pressure drops sharply change as the flow transitions such as plug-slug, pseudo slug-slug and annular-slug take place. The effects of inclination angle on the flow regime transitions have been also investigated. The results show that the method to identify the flow pattern based upon the statistical analysis of instantaneous pressure drops is suitable for inclined flow as well as horizontal flow.

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Limit Cycle Analysis Of Attitude Control System Using Thruster Under Time Delay Effect (시간지연을 갖는 추력기 자세제어시스템의 Limit Cycle 분석)

  • 안재명;노웅래;정호락;최형돈
    • 제어로봇시스템학회:학술대회논문집
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    • 2000.10a
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    • pp.3-3
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    • 2000
  • Limit cycle analysis of attitude control system using gas jet thrusters is performed. Schmitt-Trigger and PD control laws are applied and solenoid valve time delay is considered. Phase plane method is used for calculation of characteristics of limit cycle. Important characteristics of resultant limit cycle such as frequency, amplitude, maximum rate, and duty ratio could be expressed analytically by proposed method.

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INFLUENCE of SHS-CATALYSTS PHASE STRUCTURE on FORMING PRODUCTS of PARTIAL METHANE OXIDATION

  • Mironenko, A.V.;Rahmetkaliev, K.N.;Mansurov, Z.A.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.278-283
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    • 2000
  • The activity of catalysts obtained by self-propagating high temperature synthesis in reaction of partial methane oxidation at atmospheric pressure was investigated. Basing on the compared results of X-ray analysis and gas chromatography analysis of reaction products, the dependence of compounds formation on the phase concentrations in the studied catalyst samples was found.

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Determination of Acaricides in Honey by Solid-Phase Extraction and Gas Chromatography / Mass Spectrometry

  • Hong, Joo-Yeon;Jung, Ok-Sang;Ryoo, Jae-Jeong;Hong, Jong-Ki
    • Bulletin of the Korean Chemical Society
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    • v.30 no.1
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    • pp.61-66
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    • 2009
  • An analytical method based on solid-phase extraction and gas chromatography / mass spectrometry has been developed for measurement of acaricides (amitraz, bromopropylate, coumaphos, cymiazole, and tetradifon) in honey sample. In the stability test of acaricides in honey, amitraz underwent a rapid degradation into 2,4-dimethylaniline (DMA), 2,4-dimethylphenylformamide (DMPF), and N-(2,4-dimethylphenyl)-N'-methylformamidine (DMPMF), whileas other acaricides were found to be stable even for over three months. Extraction of five acaricides from 5g of honey sample was carried out by liquid-liquid extraction using 20mL of ethylacetate. For purification, Florisil-SPE cartridge with elution of 5mL of n-hexane/ acetone (55:45, v/v) was found to remove interferences effectively. Quantification was performed using gas chromatography / mass spectrometry in the selected ion monitoring mode. Spiking experiments were carried out to determine the recovery, precision, and limits of detection (LODs) of the method. The overall recovery values from honey spiked at 0.02 and 0.20 ${\mu}g/g$ levels, respectively, were found to be greater than 75% for all acaricides. The method detection limits for acaricides were ranged from 0.1 to 3 ppb. The developed method in this study was applied for the monitoring of acaricides in honey products collected from urban markets in Korea.

GREENHOUSE GAS EMISSIONS FROM ONSITE EQUIPMENT USAGE IN ROAD CONSTRUCTION

  • Byungil Kim;Hyounkyu Lee;Hyoungbae Park;Hyoungkwan Kim
    • International conference on construction engineering and project management
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    • 2011.02a
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    • pp.286-291
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    • 2011
  • Onsite usage of construction equipment accounts for a 6.8% of air pollution in Korea. The high concentration of carbon dioxide in such emissions impact not only climate change, but also people's health. However, greenhouse gas emissions from onsite equipment usage have not yet been fully investigated. This study presents a comparative analysis on how much greenhouse gas is generated by various equipment types used in different construction activities. Two ongoing cases which involve a typical road construction project in Korea were selected for the comparison purpose. Greenhouse gas emissions from each onsite equipment usage of the different activities were estimated on the ground of design documents. The estimates were compared and analyzed to derive the main sources of greenhouse gas emissions. The result showed that earthwork constituted the largest part-more than 90%-among work types. Dump truck, bulldozer, and loader were major sources for such emissions. The study results are expected to be used as a basis for reduction of greenhouse gas emission from onsite equipment usage.

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