• Title/Summary/Keyword: Gas-combined

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Discrimination of Ginseng Habitat by Using Instrumental Analysis Techniques

  • Sohn H. J.;Lee S. K.;Cho B. G.;Kim S. J.;Lee N. Y.;Choi D. S.;Jeong M. S.;Bae H. R.;Yang J. W.
    • Proceedings of the Ginseng society Conference
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    • 2002.10a
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    • pp.238-252
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    • 2002
  • In order to screen out indicators for the discrimination of ginseng habitat, some physical and chemical characteristics of Korean red ginsengs (94 kinds) and Chinese red ginsengs (50 kinds) were analyzed by using a rheometer, an electronic nose system, a combined technique of solid phase micro-extraction (SPME) and gas chromatograph equipped with an electron capture detector (GC/ECD), an X-ray fluorescence spectrometer (XRF), an inductively coupled plasma mass spectrometer (ICP/MS), a near infrared spectrometer (NIRs) and high performance liquid chromatography equipped with evaporative light scattering detector (HPLC/ELSD). The results are summarized as follows: (i) The rhizome strengths of Korean red ginsengs were significantly higher than those of Chinese red ginsengs. (ii) The electronic nose patterns of Korean red ginsengs were significantly different from those of Chinese red ginsengs. (iii) Some unidentified peaks were detected not in the headspace of Korean red ginsengs but in the headspace of Chinese red ginsengs when the headspace volatiles prepared by the SPME technique were analyzed by GC/ECD. (iv) Either the content ratios of K to Ca or Mn to Fe were significantly different between Korean red ginsengs and Chinese red ginsengs. (v) The reflectance ratios of NIRs wavenumbers such as $904\;cm^{-1}\;to\;1088\;cm^{-1}$ for Korean red ginsengs were significantly different from those for Chinese red ginsengs. (vi) The content ratios of ginsenoside-Rg to ginsenoside-Re of Korean red ginsengs were significantly higher than those of Chinese red ginsengs. These results indicate that the rhizome strength, the electronic nose pattern, the occurrence of ECD-sensitive headspace volatile components, the content ratios of K to Ca and Mn to Fe, the NIRs pattern and the content ratio of ginsenoside-Rg to -Re may be indicators for the discrimination of ginseng habitat.

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Analysis of Thermal Oxide Behavior with Isothermal Degradation of TBC Systems Applied to Single Crystal Superalloy (단결정 초내열합금에 적용된 열차폐코팅의 등온열화에 따른 산화물 거동분석)

  • Kim, K.;Wee, S.;Choi, J.;Kim, D.;Song, H.;Lee, J.;Seok, C.S.;Chung, E.S.;Kwon, S.H.
    • Journal of the Korean Society of Safety
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    • v.34 no.4
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    • pp.1-5
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    • 2019
  • In the field of combined cycle power generation, thermal barrier coating(TBC) protects the super-heat-resistant alloy, which forms the core component of the gas turbine, from high temperature exposure. As the turbine inlet temperature(TIT) increases, TBC is more important and durability performance is also important when considering maintenance cost and safety. Therefore, studies have been made on the fabrication method of TBC and super-heat-resistant alloy in order to improve the performance of the TBC. In recent years, due to excellent properties such as high temperature creep resistance and high temperature strength, turbine blade material have been replaced by a single crystal superalloy, however there is a lack of research on TBC applied to single crystal superalloy. In this study, to understand the isothermal degradation performance of the TBC applied to the single crystal superalloy, isothermal exposure test was conducted at various temperature to derive the delamination life. The growth curve of thermally grown oxide(TGO) layer was predicted to evaluate the isothermal degradation performance. Also, microstructural analysis was performed by scanning electron microscope(SEM) and energy dispersive X-ray spectroscopy (EDS) to determine the effect of mixed oxide formation on the delamination life.

Discriminating Eggs from Two Local Breeds Based on Fatty Acid Profile and Flavor Characteristics Combined with Classification Algorithms

  • Dong, Xiao-Guang;Gao, Li-Bing;Zhang, Hai-Jun;Wang, Jing;Qiu, Kai;Qi, Guang-Hai;Wu, Shu-Geng
    • Food Science of Animal Resources
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    • v.41 no.6
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    • pp.936-949
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    • 2021
  • This study discriminated fatty acid profile and flavor characteristics of Beijing You Chicken (BYC) as a precious local breed and Dwarf Beijing You Chicken (DBYC) eggs. Fatty acid profile and flavor characteristics were analyzed to identify differences between BYC and DBYC eggs. Four classification algorithms were used to build classification models. Arachidic acid, oleic acid (OA), eicosatrienoic acid, docosapentaenoic acid (DPA), hexadecenoic acid, monounsaturated fatty acids (MUFA), polyunsaturated fatty acids (PUFA), unsaturated fatty acids (UFA) and 35 volatile compounds had significant differences in fatty acids and volatile compounds by gas chromatography-mass spectrometry (GC-MS) (p<0.05). For fatty acid data, k-nearest neighbor (KNN) and support vector machine (SVM) got 91.7% classification accuracy. SPME-GC-MS data failed in classification models. For electronic nose data, classification accuracy of KNN, linear discriminant analysis (LDA), SVM and decision tree was all 100%. The overall results indicated that BYC and DBYC eggs could be discriminated based on electronic nose with suitable classification algorithms. This research compared the differentiation of the fatty acid profile and volatile compounds of various egg yolks. The results could be applied to evaluate egg nutrition and distinguish avian eggs.

Flow-Accelerated Corrosion Analysis for Heat Recovery Steam Generator in District Heating System (지역난방 배열 회수 보일러의 유동 가속 부식 원인 고찰)

  • Hong, Minki;Chae, Hobyung;Kim, Youngsu;Song, Min Ji;Cho, Jeongmin;Kim, Woo Cheol;Ha, Tae Baek;Lee, Soo Yeol
    • Korean Journal of Materials Research
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    • v.29 no.1
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    • pp.11-15
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    • 2019
  • Severe wall thinning is found on the tube of a low-pressure evaporator(LPEVA) module that is used for a heat recovery steam generator(HRSG) of a district heating system. Since wall thinning can lead to sudden failure or accidents that lead to shutdown of the operation, it is very important to investigate the main mechanism of the wall thinning. In this study, corrosion analysis associated with a typical flow-accelerated corrosion(FAC) is performed using the corroded tube connected to an upper header of the LPEVA. To investigate factors triggering the FAC, the morphology, composition, and phase of the corroded product of the tube are examined using optical microscopy, scanning electron microscopy combined with energy dispersive spectroscopy, and x-ray diffraction. The results show that the thinnest part of the tube is in the region where gas directly contacts, revealing the typical orange peel type of morphology frequently found in the FAC. The discovery of oxide scales containing phosphate indicates that phosphate corrosion is the main mechanism that weakens the stability of the protective magnetite film and the FAC accelerates the corrosion by generating the orange peel type of morphology.

Transport properties of polycrystalline TaNx thin films prepared by DC reactive magnetron sputtering method

  • Hwang, Tae Jong;Jung, Soon-Gil
    • Progress in Superconductivity and Cryogenics
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    • v.23 no.2
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    • pp.1-5
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    • 2021
  • We have investigated the electrical transport properties of polycrystalline tantalum nitride (TaNx) films. Various compositions of tantalum (nitride) thin films have been deposited on SiO2 substrates by reactive DC magnetron sputtering while changing the ratio of nitrogen partial pressure. The substrate temperature was maintained at 283 K during deposition. X-ray diffraction analyses indicated the presence of α-Ta and β-Ta phases in the Ta film deposited in pure argon atmosphere, while fcc-TaNx phases appeared in the sputtering gas mixture of argon and nitrogen. The N/Ta atomic ratio in the film increased ranging from 0.36 to 1.07 for nitrogen partial pressure from 7 to 20.7%. The superconducting transition temperatures of the TaNx thin films were measured to be greater than 3.86 K with a maximum of 5.34 K. The electrical resistivity of TaNx thin film was in the range of 177-577 𝜇Ωcm and increased with an increase in nitrogen content. The upper critical filed at zero temperature for a TaN0.87 thin film was estimated to exceed 11.3 T, while it showed the lowest Tc = 3.86 K among the measured superconducting TaNx thin films. We try to explain the behavior of the increase of the residual resistivity and the upper critical field for TaNx thin films with the nitrogen content by using the combined role of the intergrain Coulomb effect and disorder effect by grain boundaries.

Combined Effect of Catholyte Gap and Cell Voltage on Syngas Ratio in Continuous CO2/H2O Co-electrolysis

  • Ha, Min Gwan;Na, Youngseung;Park, Hee Young;Kim, Hyoung-Juhn;Song, Juhun;Yoo, Sung Jong;Kim, Yong-Tae;Park, Hyun S.;Jang, Jong Hyun
    • Journal of Electrochemical Science and Technology
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    • v.12 no.4
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    • pp.406-414
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    • 2021
  • Electrochemical devices are constructed for continuous syngas (CO + H2) production with controlled selectivity between CO2 and proton reduction reactions. The ratio of CO to H2, or the faradaic efficiency toward CO generation, was mechanically manipulated by adjusting the space volume between the cathode and the polymer gas separator in the device. In particular, the area added between the cathode and the ion-conducting polymer using 0.5 M KHCO3 catholyte regulated the solution acidity and proton reduction kinetics in the flow cell. The faradaic efficiency of CO production was controlled as a function of the distance between the polymer separator and cathode in addition to that manipulated by the electrode potential. Further, the electrochemical CO2 reduction device using Au NPs presented a stable operation for more than 23 h at different H2:CO production levels, demonstrating the functional stability of the flow cell utilizing the mechanical variable as an important operational factor.

Mechanical and durability of geopolymer concrete containing fibers and recycled aggregate

  • Abdelaziz Yousuf, Mohamed;Orhan, Canpolat;Mukhallad M., Al-Mashhadani
    • Computers and Concrete
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    • v.30 no.6
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    • pp.421-432
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    • 2022
  • Recently, the interminable ozone depletion and the global warming concerns has led to construction industries to seek for construction materials which are eco-friendly. Regarding this, Geopolymer Concrete (GPC) is getting great interest from researchers and scientists, since it can operate by-product waste to replace cement which can lead to the reduction of greenhouse gas emission through its production. Also, compared to ordinary concrete, geopolymer concrete belongs improved mechanical and durability properties. In spite of its positive properties, the practical use of geopolymer concrete is currently limited. This is primarily owing to the scarce structural, design and application knowledge. This study investigates the Mechanical and Durability of Geopolymer Concrete Containing Fibers and Recycled Aggregate. Mixtures of elastoplastic fiber reinforced geopolymer concrete with partial replacement of recycled coarse aggregate in different proportions of 10, 20, 30, and 40% with natural aggregate were fabricated. On the other hand, geopolymer concrete of 100% natural aggregate was prepared as a control specimen. To consider both strength and durability properties and to evaluate the combined effect of recycled coarse aggregate and elastoplastic fiber, an elastoplastic fiber with the ratio of 0.4% and 0.8% were incorporated. The highest compressive strength achieved was 35 MPa when the incorporation of recycled aggregates was 10% with the inclusion of 0.4% elastoplastic fiber. From the result, it was noticed that incorporation of 10% recycled aggregate with 0.8% of the elastoplastic fiber is the perfect combination that can give a GPC having enhanced tensile strength. When specimens exposed to freezing-thawing condition, the physical appearance, compressive strength, weight loss, and ultrasonic pulse velocity of the samples was investigated. In general, all specimens tested performed resistance to freezing thawing. the obtained results indicated that combination of recycled aggregate and elastoplastic fiber up to some extent could be achieved a geopolymer concrete that can replace conventional concrete.

A Study on Prevention of Fouling Formation by Reduction Reaction of CaSO4 in a Biomass Circulating Fluidized Bed Combustion (바이오매스 순환유동층 연소에서 CaSO4 환원반응에 의한 파울링 발생 방지 연구)

  • Seong-Ju Kim;Sung-Jin Park;Sung-Ho Jo;Se-Hwa Hong;Yong-Il Mun;Tae-Young Mun
    • New & Renewable Energy
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    • v.19 no.1
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    • pp.1-11
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    • 2023
  • A large amount of carbon monoxide (CO) is generated in circulating fluidized bed combustion, the process whereby a hot cyclone separates unburned fuel. However, calcium sulfate (CaSO4), when combined with a high CO content, can cause fouling on the surface of the steam tube installed inside the integrated recycle heat exchangers (INTREX). In this study, CaSO4 decomposition was investigated using 0.2-3.2 vol.% CO and 1-3 vol.% oxygen (O2) at 850℃ for 20 min in a lab-scale fluidized bed reactor. The results show that CaSO4 decomposes into CaS and CaO when CO gas is supplied, and SO2 emissions increase from 135 ppm to 1021 ppm with increasing CO concentration. However, the O2 supply delayed SO2 emissions because the reaction between CO and O2 is faster than that of CaSO4; nevertheless, when supplied with CaCO3, the intermediate product, SO2 was significantly released, regardless of the CO and O2 supply. In addition, agglomerated solids and yellow sulfur power were observed after solid recovery, and the reactor distributor was corroded. Consequently, a sufficient O2 supply is important and can prevent fouling formation on the INTREX surface by suppressing CaSO4 degradation.

T-S fuzzy PID control based on RCGAs for the automatic steering system of a ship (선박자동조타를 위한 RCGA기반 T-S 퍼지 PID 제어)

  • Yu-Soo LEE;Soon-Kyu HWANG;Jong-Kap AHN
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.59 no.1
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    • pp.44-54
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    • 2023
  • In this study, the second-order Nomoto's nonlinear expansion model was implemented as a Tagaki-Sugeno fuzzy model based on the heading angular velocity to design the automatic steering system of a ship considering nonlinear elements. A Tagaki-Sugeno fuzzy PID controller was designed using the applied fuzzy membership functions from the Tagaki-Sugeno fuzzy model. The linear models and fuzzy membership functions of each operating point of a given nonlinear expansion model were simultaneously tuned using a genetic algorithm. It was confirmed that the implemented Tagaki-Sugeno fuzzy model could accurately describe the given nonlinear expansion model through the Zig-Zag experiment. The optimal parameters of the sub-PID controller for each operating point of the Tagaki-Sugeno fuzzy model were searched using a genetic algorithm. The evaluation function for searching the optimal parameters considered the route extension due to course deviation and the resistance component of the ship by steering. By adding a penalty function to the evaluation function, the performance of the automatic steering system of the ship could be evaluated to track the set course without overshooting when changing the course. It was confirmed that the sub-PID controller for each operating point followed the set course to minimize the evaluation function without overshoot when changing the course. The outputs of the tuned sub-PID controllers were combined in a weighted average method using the membership functions of the Tagaki-Sugeno fuzzy model. The proposed Tagaki-Sugeno fuzzy PID controller was applied to the second-order Nomoto's nonlinear expansion model. As a result of examining the transient response characteristics for the set course change, it was confirmed that the set course tracking was satisfactorily performed.

Observational Studies on Evolved Stars Using KVN and KaVA/EAVN

  • Cho, Se-Hyung;Yun, Youngjoo;Imai, Hiroshi
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.51.1-51.1
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    • 2019
  • At the commissioning phase of KVN from 2009 to 2013, single-dish survey and monitoring observations were performed toward about 1000 evolved stars and about 60 relatively strong SiO and H2O maser sources respectively. Based on these single-dish results and VLBI feasibility test observations at K/Q/W/D bands in 2014, KVN Key Science Project (KSP) has started from 2015 and will be completed in 2019 as KSP phase I. Here we present the overview of observational studies on evolved stars using KVN. In KSP phase I, we have focused on nine KSP sources which show a successful astrometrically registered maps of SiO and H2O masers using the source frequency phase referencing method. We aim at investigating the spatial structure and dynamical effect from 43/42/86/129 GHz SiO to 22 GHz H2O maser regions associated with a stellar pulsation and development of asymmetry in circumstellar envelopes. Using the combined network KaVA (KVN+Japanese VLBI network VERA), KaVA Large Program titled on "Expanded Study on Stellar Masers: ESTEMA Phase I" was performed from 2015 to 2016. Based on ESTEMA Phase I, EAVN Large Program titled on "EAVN Synthesis of Stellar Maser Animations: ESTEMA Phase II" was also performed from 2018. The ESTEMA II project aims to publish composite animations of circumstellar H2O and SiO masers, which taken from up to 6 long-period variable stars with a variety of the pulsation periods (333-1000 days). The animations will exhibit the three-dimensional kinematics of the maser gas clumps with complexity caused by stellar pulsation-driven shock waves and anisotropy of clump ejections from the stellar surface. Adding three EAVN telescopes (Tianma 65m, Nanshan 26m and NRO 45m telescopes) with KaVA always secures the high quality of the maser image frames through the monitoring program.

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