• Title/Summary/Keyword: Gas-Phase

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Characteristic of Size-Resolved Water-Soluble Organic Carbon in Atmospheric Aerosol Particles Observed during Daytime and Nighttime in an Urban Area (도시지역 낮.밤 대기에어로졸의 입경 별 수용성 유기탄소의 특성)

  • Park, Seung Shik;Shin, Dong Myung
    • Particle and aerosol research
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    • v.9 no.1
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    • pp.7-21
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    • 2013
  • Twelve-hour size-resolved atmospheric aerosols were measured to determine size distributions of water-soluble organic carbon(WSOC) during daytime and nighttime, and to investigate sources and formation pathways of WSOC in individual particle size classes. Mass, WSOC, ${NO_3}^-$, $K^+$, and $Cl^-$ at day and night showed mostly bimodal size distributions, peaking at the size range of $0.32-0.55{\mu}m$(condensation mode) and $3.1-6.2{\mu}m$(coarse mode), respectively, with a predominant condensation mode and a minor coarse mode. While ${NH_4}^+$ and ${SO_4}^{2-}$ showed unimodal size distributions which peaked between 0.32 and $0.55{\mu}m$. WSOC was enriched into nuclei mode particles(< $0.1{\mu}m$) based on the WSOC-to-mass and WSOC-to-water soluble species ratios. The sources and formation mechanisms of WSOC were inferred in reference to the size distribution characteristics of inorganic species(${SO_4}^{2-}$, ${NO_3}^-$, $K^+$, $Ca^{2+}$, $Na^+$, and $Cl^-$) and carbon monoxide. Nuclei mode WSOC was likely associated with primary combustion sources during daytime and nighttime. Among significant sources contributing to the condensation mode WSOC were homogeneous gas-phase oxidation of VOCs, primary combustion emissions, and fresh(or slightly aged) biomass burning aerosols. The droplet mode WSOC could be attributed to aqueous oxidation of VOCs in clouds, cloud-processed biomass burning aerosols, and small contributions from primary combustion sources. From the correlations between WSOC and soil-related particles, and between WSOC and sea-salt particles, it is suggested that the coarse mode WSOC during daytime is likely to condense on the soil-related particles($K^+$ and $Ca^{2+}$), while the WSOC in the coarse fraction during nighttime is likely associated with the sea-salt particles($Na^+$).

Steady-State/Transient Performance Simulation of the Propulsion System for the Canard Rotor Wing UAV during Flight Mode Transition

  • Kong, Changduk;Kang, Myoungcheol;Ki, Jayoung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.513-520
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    • 2004
  • A steady-state/transient performance simulation model was newly developed for the propulsion system of the CRW (Canard Rotor Wing) type UAV (Unmanned Aerial Vehicle) during flight mode transition. The CRW type UAV has a new concept RPV (Remotely Piloted Vehicle) which can fly at two flight modes such as the take-off/landing and low speed forward flight mode using the rotary wing driven by engine bypass exhaust gas and the high speed forward flight mode using the stopped wing and main engine thrust. The propulsion system of the CRW type UAV consists of the main engine system and the duct system. The flight vehicle may generally select a proper type and specific engine with acceptable thrust level to meet the flight mission in the propulsion system design phase. In this study, a turbojet engine with one spool was selected by decision of the vehicle system designer, and the duct system is composed of main duct, rotor duct, master valve, rotor tip-jet nozzles, and variable area main nozzle. In order to establish the safe flight mode transition region of the propulsion system, steady-state and transient performance simulation should be needed. Using this simulation model, the optimal fuel flow schedules were obtained to keep the proper surge margin and the turbine inlet temperature limitation through steady-state and transient performance estimation. Furthermore, these analysis results will be used to the control optimization of the propulsion system, later. In the transient performance model, ICV (Inter-Component Volume) model was used. The performance analysis using the developed models was performed at various flight conditions and fuel flow schedules, and these results could set the safe flight mode transition region to satisfy the turbine inlet temperature overshoot limitation as well as the compressor surge margin. Because the engine performance simulation results without the duct system were well agreed with the engine manufacturer's data and the analysis results using a commercial program, it was confirmed that the validity of the proposed performance model was verified. However, the propulsion system performance model including the duct system will be compared with experimental measuring data, later.

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A Study on Combustion and Emission Characteristics of Diesel-DME Blended Fuels in D.I Compression-Ignition Engine (직접분사식 압축착화엔진에서 Diesel-DME 혼합연료의 연소 및 배기특성에 관한 연구)

  • Jeong, Jaehoon;Lim, Ocktaeck;Jeon, Jong Up;Lee, Sangwook;Pyo, Youngduck;Lee, Youngjae;Suh, Hocheol
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.530-537
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    • 2012
  • This work experimentally investigates that Diesel-DME blended fuel influences combustion characteristics and emissions (NOx, CO, HC, smoke) in a single-cylinder DI diesel engine. Diesel is used as a main fuel and DME is blended for the use of its quick evaporating characteristics. Diesel and DME are blended by the method of weight ratio. Weight ratios for Diesel and DME are 95:5 and 90:10 respectively and the both ratios have been used altogether in blended fuel. The experiments are conducted in this study single cylinder engine is equipped with common rail and injection pressure is 700 bar at 1200 rpm. The amount of injected fuels is adjusted to obtain the fixed input calorie value as 972.2 J/cycle in order to compare with the fuel conditions. DME is compressed to 15 bar by using nitrogen gas thus it can be maintained the liquid phase. In this study, different system compared others paper is common rail system, also there is combustion and emission about compared DME and diesel fuel. It is expected to be utilized about blended fuel.

A Study on the Microwave Electric-Field Focusing Waveguide Systems for Driving Plasma Visible Light (플라즈마 가시광 구동을 위한 초고주파 전계 집속형 도파관 시스템에 관한 연구)

  • Jeon, Hoo-Dong;Park, Eui-Joon
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.3
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    • pp.303-312
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    • 2009
  • In this study, a waveguide system for focusing the electric field is presented to emit the microwave-driven plasma visible light. This system consists of a magnetron for the microwave power supply, the waveguide section for power propagation, and the mesh-type cavity reactor. The quartz bulb containing a dose of sulfur powder and buffer gas Ar is located in the reactor, and forced by the strongly concentrated electric field for generating and exciting the sulfur plasma. That is, the conductor tips are loaded on each inner wall of the waveguide and the reactor, and then the plasma bulb is positioned between the tips, hence focusing the strong electric field on the bulb. Furthermore the waveguide section is designed for minimizing the degradations of matching characteristics according to the variations of the electrical conductivities of plasma at the transitory phase for plasma generation, hence providing the stable operation. Finally, the 2.45 GHz aluminum waveguide system is constructed, and then experiments for emitting the visible light are performed by using 400 W-class magnetron, showing the validity of designed system.

Crystal Structure and Photoluminescence of Domestic Natural Alkaline Feldspar (국산 천연알카리 장석의 결정구조와 Photoluminescence)

  • Choi, Jin-Ho;Cheon, Chae-Il;Kim, Jeong-Seog
    • Journal of the Korean Ceramic Society
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    • v.44 no.5 s.300
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    • pp.155-159
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    • 2007
  • Blue light-emitting phosphors having the excitation spectrum range of the medium-long ultraviolet ($280nm{\sim}400nm$) have been prepared by solid state reaction method. As a starting material the natural alkaline feldspar powder produced from the domestic mine field in Buyeo, Chungnam-do. The photoluminescence characteristics and crystal structures have been analyzed for the phosphor samples. The powder mixture of the natural alkaline feldspar and the rare-earth oxide was calcined at $800{\sim}1000^{\circ}C\;for\;3{\sim}4h$ in air. The calcined samples we fully ground at room temperature and then heat-treated in the mild reducing gas atmosphere of $5%H_2-95%N_2$ mixture at $1100{\sim}1150^{\circ}C\;for\;3{\sim}4h$. The natural alkaline feldspar material consists of the monoclinic orthoclase ($KAlSi_3O_8$) and the triclinic albite ($NaAlSi_3O_8$) phases. At the $0.5wt%Eu_2O_3$ addition the PL spectrum showed the maximum intensity and with further increase of $Eu_2O_3$ the PL intensity decreased. The albite phase disappeared in the $Eu_2O_3$ doped phosphors. The effect of the co-doped activator on the PL characteristics have been also discussed.

Effect of Moisture in a Vacuum Chamber on the Deposition of c-BN Thin Film using an Unbalanced Magnetron Sputtering Method (비대칭 마그네트론 스퍼터링 방법에 의한 질화붕소막의 증착시 반응실내의 초기 수분이 입방정질화붕소 박막의 형성에 미치는 영향)

  • Lee, Eun-Sook;Park, Jong-Keuk;Lee, Wook-Seong;Seong, Tae-Yeon;Baik, Young-Joon
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.620-624
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    • 2012
  • The role of moisture remaining inside the deposition chamber during the formation of the cubic boron nitride (c-BN) phase in BN film was investigated. BN films were deposited by an unbalanced magnetron sputtering (UBM) method. Single-crystal (001) Si wafers were used as substrates. A hexagonal boron nitride (h-BN) target was used as a sputter target which was connected to a 13.56 MHz radiofrequency electric power source at 400 W. The substrate was biased at -60 V using a 200 kHz high-frequency power supply. The deposition pressure was 0.27 Pa with a flow of Ar 18 sccm - $N_2$ 2 sccm mixed gas. The inside of the deposition chamber was maintained at a moisture level of 65% during the initial stage. The effects of the evacuation time, duration time of heating the substrate holder at $250^{\circ}C$ as well as the plasma treatment on the inside chamber wall on the formation of c-BN were studied. The effects of heating as well as the plasma treatment very effectively eliminated the moisture adsorbed on the chamber wall. A pre-deposition condition for the stable and repeatable deposition of c-BN is suggested.

Quality Properties of Pear Vinegars with High-Acidity under Different Fermentation Conditions (고산도 배식초 제조 시 발효조건에 따른 품질특성)

  • Jo, Deokjo;Lee, Hye-Jin;Jeong, Yong-Jin;Yeo, Soo-Hwan;Kwon, Joong-Ho
    • Korean Journal of Food Science and Technology
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    • v.46 no.4
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    • pp.418-424
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    • 2014
  • High-acidity vinegar was manufactured using pear concentrate by fed-batch fermentation without additional nutrients, and the physicochemical properties and volatile components were investigated at different fermentation stages (Stages 1-4) and at various initial alcohol concentrations (IAC; 6-9%). The levels of reducing sugar, free amino acids, total phenolic content, total flavonoid content, and radical scavenging ability increased slightly during Stage 4 (high-acidity vinegar), which was affected by alcohol feeding. The contents of approximately 20 types of volatile compounds differed between the moderate- and high-acidity vinegar samples, as determined by solid-phase microextraction/gas chromatography-mass spectroscopy. The level of acetic acid in high-acidity vinegar increased according to the initial alcoholic content applied. The high-acidity vinegar produced by fed-batch culture at an IAC of 6-7% showed improved physicochemical and volatile properties as compared to the moderate-acidity vinegar.

Influence of α-SiC Seed Addition on Spark Plasma Sintering of β-SiC with Al-B-C: Microstructural Development (Al-B-C 조제 β-SiC의 스파크 플라즈마 소결에 미치는 α-SiC seed 첨가 영향: 미세 구조 변화)

  • Cho, Kyeong-Sik;Lee, Hyun-Kwuon;Lee, Sang-Woo
    • Journal of Powder Materials
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    • v.17 no.1
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    • pp.13-22
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    • 2010
  • The unique features of spark plasma sintering process are the possibilities of a very fast heating rate and a short holding time to obtain fully dense materials. $\beta$-SiC powder with 0, 2, 6, 10 wt% of $\alpha$-SiC particles (seeds) and 4 wt% of Al-B-C (sintering aids) were spark plasma sintered at $1700-1850^{\circ}C$ for 10 min. The heating rate, applied pressure and sintering atmosphere were kept at $100^{\circ}C/min$, 40 MPa and a flowing Ar gas (500 CC/min). Microstructural development of SiC as function of seed content and temperature during spark plasma sintering was investigated quantitatively and statistically using image analysis. Quantitative image analyses on the sintered SiC ceramics were conducted on the grain size, aspect ratio and grain size distribution of SiC. The microstructure of SiC sintered up to $1700^{\circ}C$ consisted of equiaxed grains. In contrast, the growth of large elongated SiC grains in small matrix grains was shown in sintered bodies at $1750^{\circ}C$ and the plate-like grains interlocking microstructure had been developed by increasing sintering temperature. The introduction of $\alpha$-SiC seeds into $\beta$-SiC accelerated the grain growth of elongated grains during sintering, resulting in the plate-like grains interlocking microstructure. In the $\alpha$-SiC seeds added in $\beta$-SiC, the rate of grain growth decreased with $\alpha$-SiC seed content, however, bulk density and aspect ratio of grains in sintered body increased.

Separation and Characterization of Spikelet Proteins at Young Microspore Stage in Rice

  • Woo, Sun-Hee;Kim, Tae-Seon;Cho, Seong-Woo;Ahn, Jung-Gu;Chung, Keun-Yook;Lee, Byung-Moo;Cho, Yong-Gu;Kim, Hong-Sig;Song, Beom-Heon;Lee, Chul-Won;Jong, Seung-Keun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.1
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    • pp.66-72
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    • 2006
  • Spikelet proteins expressed at the young microspore stage in rice were separated and analysed by two-dimensional polyacrylamide gel electrophoresis (2DE). The separated proteins were electro blotted onto a polyvinylidene difluoride (PVDF) membrane, and 50 proteins were analyzed by a gas-phase protein sequencer. The N-terminal amino acid sequences of 20 out of 50 proteins were determined. N-terminal regions of the remaining proteins could not be sequenced because of blocking. The internal amino acid sequences of proteins were determined by sequence analysis of peptides obtained by the Cleveland peptide mapping method. Results revealed the presence of the photosynthetic apparatus at rice young microspore stage. Major proteins identified in this study could be used as a marker for various studies on physiological stresses.

The Characteristics of a Superposed Discharge Type Ozonizer Using Vacuum Discharge Tube (진공 방전관을 이용한 고농도 중첩방전형 오존발생기의 특성)

  • Song, Hyun-Jig;Lee, Chang-Ho
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.5
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    • pp.60-67
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    • 2005
  • The superposed discharge type ozonizer of high ozone concentration using vacuum discharge tube has been designed and manufactured. It consists of three electrodes(central electrode, internal electrode, and external electrode) and one discharge gap(discharge gap between internal electrode and external electrode), is a superposed silent discharge type ozonizer for which the AC high voltages applied to the central electrode within discharge tube and the internal electrode has a $180{[^\circ]}$ phase difference and for which the external electrode is a ground. Ozone is generated by overlapping silent discharge between central electrode and external electrode, and silent discharge between internal electrode and external electrode. At the moment, discharge characteristics and ozone generation characteristics were investigated in accordance with vacuum of discharge tube, discharge power of ozonizer, and quantity of supplied oxygen gas. In consequence, high ozone concentration can be obtained 8840[ppm].