• 한국막학회:학술대회논문집
• /
• 한국막학회 1996년도 춘계 총회 및 학술발표회
• /
• pp.55-56
• /
• 1996

Heterophase polymer system has been attractive for a potential applicability to gas separation membrane material. It has been known that there is a trade-off between gas permeability and its selectivity in common polymers. Therefore, the heterophase polymer can be an alternative for a gas separation membrane material because its transport properties can be readily controlled by blending of two different polymers. The transport properties of immiscible polymer blends strongly depend upon the intrinsic transport properties of corresponding polymers. Another important factor to determine the transport properties is their morphology: volume fraction, size and shape of dispersed phase. Although the effect of the volume fraction of the dispersed phase on the transport properties has been widely investigated, the size and shape effects have been paid attention very much. In an immiscible polymer blend of two polymers, its morphology is primarily controlled by its volume fraction of dispersed phase. Therefore, the effect of the size of the dispersed phase can be hardly seen. Therefore, a block copolymer has been commonly employed to control their morphology when each block is miscible with one or the other phase. In this work, gas transport properties will be measured by varying the morphology of the heterophase polymer membrane. The transport properties will be interpreted in terms of their morphology. The effect of the volume fraction of the PI phase and, in particular, its size effect will be investigated experimentally and theoretically.

• 한국막학회:학술대회논문집
• /
• 한국막학회 1997년도 추계 총회 및 학술발표회
• /
• pp.67-68
• /
• 1997

1. Introduction : Gas transport through dense polymeric membranes is predominantly determined by the chain packing density as well as the chain flexibility. Thus, improved permeation properties can be obtained by controlling these two factors. In this work, the introduction of bulky substituents was attempted to improve permeation properties. Polysulfone, widely used material for gas separation membrane, was the starting material of this modification. Gas transport properties of resulting modified polysulfones were examined, and the improved properties were explained by probing the change of physical properties.

• The Korean Journal of Ceramics
• /
• 제4권2호
• /
• pp.103-113
• /
• 1998

By using a gas-tight electrochemical cell, we can perform high-temperature coulometric titration and measure electronic transport properties to determine the elecronic defect structure of metal oxides. This technique reduces the time and expense required for conventional thermogravimetric measurements. The components of the gas-tight coulometric titration cell are an oxygen sensor, Pt/yttria stabilitized zirconia(YSZ)/Pt, and an encapsulated metal oxide sample. Based on cell design, both transport and thermodynamic measurements can be performed over a wide range of oxygen partial pressure ($pO_2=10^{-35}$ to 1 atm). This paper describes the high-temperature gas-tight electrochemical cells used to determine electronic defect structures and transport properties for pure and doped-oxide systems, such as YSZ, doped and pure ceria $(Ca-CeO_2 \;and\; CeO_2)$, copper oxides and copper-oxide-based ceramic superconductors, transition metal oxides, $SrFeCo_{0.5}O_x,\; and \;BaTiO_2$.

• 한국의학물리학회:학술대회논문집
• /
• 한국의학물리학회 2002년도 Proceedings
• /
• pp.285-288
• /
• 2002

In this study, we investigate electron transport properties in xenon gas by using a Monte Carlo technique for electrons with energies below 10 keV. First of all, we determine a set of electron collision cross sections with xenon by scrutinizing the cross section data taken from many publications. Then, the W value and the Fano factor for electrons in gaseous xenon are computed by the Monte Carlo simulation on the assumption that electrons undergo single collision events including elastic, excitation and ionization processes. We also evaluate the production number of excited atoms.

• 한국막학회:학술대회논문집
• /
• 한국막학회 2004년도 Proceedings of the second conference of aseanian membrane society
• /
• pp.128-131
• /
• 2004

The composite mesoporous ceramic membranes were prepared with ${\gamma}$-alumina and poly (2, 6-dimethyl-l, 4-pyphenylene oxide) (PPO) on the surface of the macroporous $\alpha$-alumina ceramic membranes and the permeation results were compared with those of the $\alpha$-alumina membrane for large-scale applications. In the results of the transport experiments, the ceramic membranes gave high gas permeances mainly due to Knudsen diffusion and surface diffusion as an additional mechanism. And, the polymer modification increased the permeances of the strongly adsorbing gas components. In this study the modifications of alumina ceramic membranes could increase the gas permeation performances especially for the strongly absorbing gas components.

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2012년도 춘계학술발표회 논문집
• /
• pp.211-212
• /
• 2012

ZnO submicron particles were grown on Au-catalyzed Si substrate by a vapor phase transport (VPT) growth process under different mixture gas ratio at growth temperature of $900^{\circ}C$. The structural and optical properties of the ZnO submicron particles were investigated by field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD), and photoluminescence (PL). The ZnO submicron particles could be clustered with the $O_2/Ar$ mixture gas ratio(%) higher than 10%, and it was mainly determined by the gas ambient. Particularly, when the $O_2/Ar$ mixture gas ratio was 30%, it was observed the ZnO submicron particles with diameters in the range of 125 to 500 nm and the narrowest full width at half maximum (FWHM) of XRD and PL spectra with $0.121^{\circ}$ and 92 meV, respectively. It was found that the structural and optical properties of the ZnO submicron particles were improved with increasing the $O_2/Ar$ mixture gas ratio through the XRD and PL spectra.

• 멤브레인
• /
• 제27권2호
• /
• pp.167-181
• /
• 2017

그래핀 기반 소재는 높은 가공성과 초박성으로 인하여 분리막 소재로서 각광받고 있다. 본 연구에서는, 스핀 코팅법을 이용하여 제조된 산화그래핀 분리막의 기체 투과 거동을 평가하였다. 산화그래핀 분리막의 구조는 산화그래핀의 크기와 산화그래핀 용액의 pH 조절을 통하여 조절될 수 있다. 산화그래핀의 크기가 작을수록 굴곡률이 작아짐에 따라 분리막의 기체 투과도 및 선택도가 증가하는 경향을 보인다. 또한 산화그래핀에서의 기체 투과 거동은 적층된 산화그래핀 사이의 채널크기에 따라 영향을 받는다. 특히 산화그래핀 분리막의 좁은 기공과 이산화탄소 선택적인 산화그래핀 자체의 특성으로 인하여 산화그래핀 분리막은 이산화탄소에 대한 높은 투과도 및 선택성을 가지며, 이는 이산화탄소 포집에 적합한 특성을 가진다. 이러한 산화그래핀 분리막의 특이한 기체 투과 거동은 흡착-촉진 확산 거동(표면 확산 기작)으로 설명될 수 있다. 본 연구를 통하여 이산화탄소 선택성 분리막 소재 설계와 슬릿 형태의 기공과 적층 구조를 가진 분리막을 통한 기체 투과 거동 연구가 활발히 이루어질 것으로 기대한다.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 2011년도 제42회 하계학술대회
• /
• pp.1544-1545
• /
• 2011

For quantitative understanding of gas discharge phenomena, we should know electron collision cross section. Processing plasma etching of semiconductor, and research are being used in the etching source $C_4F_6$ gas may be used by itself and mixed with other gases are also used. However, the molecular gas $C_4F_6$ study on the characteristics of the electron transport and the cross-sectional area of the decision is still lacking. Therefore, we understand the electron transport characteristics and analysed the electron transport coefficients. And to understand and interpret physical properties of the ionization coefficient ${\alpha}$/N, and the attachment coefficient ${\eta}$/N in $C_4F_6$ gas.

• 한국전산유체공학회:학술대회논문집
• /
• 한국전산유체공학회 2011년 춘계학술대회논문집
• /
• pp.46-53
• /
• 2011

Water is continuously produced in polymer electrolyte membrane fuel cell (PEMFC), and is transported and exhausted through polymer electrolyte membrane (PEM), catalyst layer (CL), microporous layer (MPL), and gas diffusion layer (GDL). The low operation temperatures of PEMFC lead to the condensation of water, and the condensed water hinders the transport of reactants in porous layers (MPL and GDL). Thus, water flooding is currently one of hot issues that should be solved to achieve higher performance of PEMFC. This research aims to study liquid water transport in porous layers of PEMFC by using pore-network model, while the microscale pore structure and hydrophilic/hydrophobic surface properties of GDL and MPL were fully considered.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
• /
• pp.415-415
• /
• 2012

ZnO nanostructures were synthesized by a vapor phase transport process in a single-zone furnace within a horizontal quartz tube with an inner diameter of 38 mm and a length of 485 mm. The ZnO nanostructures were grown on Au-catalyzed Si(100) substrates by using a mixture of zinc oxide and graphite powders. The growth of ZnO nanostructures was conducted at $800^{\circ}C$ for 30 min. High-purity Ar and $O_2$ gases were pushed through the quartz tube during the process at a flow rate of 100 and 10 sccm, respectively. The sequence of ON/OFF cycles of the Ar gas flow was repeated, while the $O_2$ flow is kept constant during the growth time. The Ar gas flow was ON for 1 min/cycle and that was OFF for 2 min/cycle. The structure and optical properties of the ZnO nanostructures were investigated by field-emission scanning electron microscope, X-ray diffraction, temperature-dependent photoluminescence. The preferred orientation of the ZnO nanostructures was along c-axis with hexagonal wurtzite structure.