• Title/Summary/Keyword: Gas permeability

Search Result 534, Processing Time 0.028 seconds

Evaluation of Concentration Polarization at Feed in the Permeation of VOCs/$N_2$ mixtures through PDMS membrane (VOCs/질소 혼합물 증기투과시 공급액부 경계층에서의 농도분극 분석을 위한 모델식 확립)

  • 염충균;이상학;최정환;이정민
    • Membrane Journal
    • /
    • v.11 no.2
    • /
    • pp.74-82
    • /
    • 2001
  • By using a phenomenological approach, model equations incorporating the resistance-in¬series concept were established to evaluate quantitatively concentration polarization in the boundary layer in feed adjacent to the membrane surface in the vapor permeation and separation of volatile organic compounds (VOCS)/$N_2$ mixture through po]y(dimethylsiloxane) (PDMS) membrane. The vapor permeations of various VOCS/$N_2$ mixtures through PDMS membrane were carried out at various feed flow rates. Chlorinated hydrocarbons, such as, methylene chloride, chlorofonn, 1,2-clichloroethane and 1,1,2-trichloroethane were used as organic vapor. By fitting the model equations to the experimental penneation data. the model parameters were detennined. respectively. Both the mass transfer coefficient of VOC across tbe boundary layer and concentration polarization modulus as a measure of the extent of concentration polarization were eitimated Quantitatively by the mooe1 equations with the determined model parameters. From the analysis on the detennined model parameters, the boundary layer resistance due to the concentration polarization of VOCs component was found to be more significant when the condensability of voe was greater. This study seeks to emphasize the importance of the boundary resistance on the vapor penneation of the vapor/gas mixtures with high permeability and high selectivity towards the minor component VOC.

  • PDF

Water Vapor Permeability of SiO2 Oxidative Thin Film by CVD (CVD로 제작된 SiO2 산화막의 투습특성)

  • Lee, Boong-Joo;Shin, Hyun-Yong
    • The Journal of the Korea institute of electronic communication sciences
    • /
    • v.5 no.1
    • /
    • pp.81-87
    • /
    • 2010
  • In this paper, we have fabricated $SiO_2$ oxidation thin films by HDP-CVD(high density plasma-chemical vapor deposition) method for passivation layer or barrier layer of OLED(organic light emitting diode). We have control and estimate the deposition rate and relative index characteristics with process parameters and get optimized conditions. They are gas flow rate($SiH_4:O_2$=30:60[sccm]), 70 [mm] distance from source to substrate and no-bias. The WVTR(water vapor transmission rate) is 2.2 [$g/m^2$_day]. Therefore fabricated thin film can not be applied as passivation layer or barrier layer of OLED.

Micropropagation of Sweetpotato (Ipomoea batatas) in a novel $CO_2$-Enriched Vessel

  • Silva Jaime A. Teixeira da;Giang Dam Thi Thanh;Tanaka Michio
    • Journal of Plant Biotechnology
    • /
    • v.7 no.1
    • /
    • pp.67-74
    • /
    • 2005
  • To overcome various disadvantages of conventional cul-ture vessels for micropropagation, a novel disposable vessel, the 'Vitron', made of a multi-layered $OTP^{(R)}$ film and supported by a polypropylene frame, was developed. The film possesses superior properties such as: high light transmittance, low water vapor transmittance and thermal stability and in particular, high gas-permeability. Single nodal explants, which were excised from the multiple shoots derived from shoot-tip culture, were cultured in Vitron and polycarbonate vessels on $3\%$ sugar-containing agar on MS medium and placed at 3000 ppm $CO_2$-enrichment at a low photosynthetic photon flux density (PPFD) ($45{\mu}mol\;m^{-2}\;s^{-1}$). The in vitro and ex vitro growth, and the net photosynthetic rate of in vitro and ex vitro plantlets were significantly enhanced in the Vitron compared to those cultured in a polycarbonate vessel. Explants that were cultured on the same MS medium under low PPFD at various $CO_2$ concentrations were also cultured at 3000 ppm $CO_2$- enrichment at various PPFD: 30, 45, 60, 75 and $90{\mu}mol\;m^{-2}\;s^{-1}$. The best in vitro and ex vitro growth obtained for 3000 ppm $CO_2$-enrichment at $75{\mu}mol\;m^{-2}\;s^{-1}$ PPFD. The novel Vitron vessel, when placed under the two conditions, may replace conventional culture vessels for the successful micropropagation of sweetpotato.

Soft Magnetic Property of Ternary Fe-9.8Si-6.0Al Alloy Using by Recycling Fe-Si Electrical Steel Sheet Scrap (Fe-Si 전기강판 폐스크랩을 이용한 3원계 Fe-9.8Si-6.0Al 합금의 연자성 특성)

  • Hong, Won Sik;Yang, Hyoung Woo;Park, Ji-Yeon;Oh, Chulmin;Lee, Woo Sung;Kim, Seung Gyeom;Han, Sang Jo;Shim, Geum Taek;Kim, Hwi-Jun
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.24 no.1
    • /
    • pp.1-8
    • /
    • 2017
  • Fe-9.8Si-6.0Al mother alloy was manufactured using by Fe-3.5Si recycled scrap and Si powder. And then, soft magnetic alloy powder of $D_{50}$ size and sphere type were prepared by gas atomization process. To obtain the soft magnetic powder of a high aspect ratio, in the first, we conducted the ball milling process for 8 hours. And heat treatment was performed under $650^{\circ}C$, 2 hours and $N_2$ atmosphere condition for reducing the residual stress of the powder. Based on these process, we made around $50{\mu}m$ diameter Fe-9.8Si-6.0Al powder, which morphology and shape was a similar to the commercial Fe-Si-Al powder. Finally, the soft magnetic sheets were prepared by tape casting process using by those powders. The permeability of the tape casting sheet was measured, and we confirmed the possibility of reusing to the soft magnetic materials of Fe-Si electric sheet scrap.

Studies on the Cracking of Nitrocellulose Clear Lacquer Coasted Films on Solid Woods of Quercus acutissima and Betula platyphylla var. japonica (상수리나무와 자작나무 소재(素材)에 대한 Nitrocellulose Clear Lacquer 도막(塗膜)의 할열(割裂)에 관(關)한 연구(硏究))

  • Kim, Hyun-Joong;Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
    • /
    • v.17 no.1
    • /
    • pp.55-68
    • /
    • 1989
  • This experiment was carried out to investigate the crack of coated Nitrocellulose Lacquer on flatand edge-grained boards of Quercus acutissima, ring-porous wood, and Betula platyphylla var. japonica, diffuse-porous wood, by variations of moisture contents at 7, 13 and 21%. Cold check system was used as an accelerating method for crack development, in which one cycle of the system consisted of 10 replications of each unit cycle, $60^{\circ}C$ for 4hr followdd by $-20^{\circ}C$ for 4hr. The analysis of Nitrocellulose Lacquer characteristics was made by means of water permeation measurement, F.T.I.R. spectroscopy, N.M.R. spectroscopy, gel permeation chromatography, gas chromatography, and D.S.C. The results obtained were as follows: 1. The number of cracks increased with the increasing moisture content of board. 2. The crack of coated film on flat-grained board was fewer in number than on edge-grained board. 3. The crack occurred in Quercus acutissima was more numerous on edge-grained board but less frequent on flat-grained board compared with that in Betula platyphylla var. japonica, respectively. 4. The cold crack vertically developed to the grain both in Quercus acutissima and Betula platyphylla var. japonica. 5. Water permeability in intermediate coated film was lower than in under and top coated film, but the difference was not confirmed between under and top coated film.

  • PDF

Study of Development of Selective Removal Adsorption Ion Exchange Resin Materials for Fabricated with Chemical-biological Cloth by QFD (QFD 기법을 이용한 특정 유해가스 노출제어 이온선택성 보호복 소재개발연구)

  • Song, Hwa Seon;Koo, Il Seob;Kim, In Sik
    • Journal of Korean Society for Quality Management
    • /
    • v.43 no.3
    • /
    • pp.359-372
    • /
    • 2015
  • Purpose: Through studying the expert's and non-experts panel responses to the questions regarding the attributes of chemical-biological protection cloth quality in terms of the levels of customer demand and technical factors has been studied. We are applied to a QFD matrix with find out the relationship between the selective removal efficiency of chemical-biological cloth and the guidelines of technical approach. Methods: We fabricated several composite of ion-exchange resins with selectively permeable performance designed to facilities water vapor transport and selective adsorption of the harmful gases. With these materials, we characterized on the selectively permeable performance to identify ion-exchange resin with chemical-biological protective cloth. Results: Results showed that ion exchange materials possessed performance with selectively efficiencies as NH3, SOx, NOx and HCl gas. The selective adsorption amount of ammonia and hydrogen gases were $90-80{\mu}g/g$ with TRILITE SCR-BH sulfonated ion exchange resin. The PP non-woven/ion exchange resin adsorbent materials possessed performance with water vapor permeability were 1,100-1,350 g/m2/day, it's was two times high value compare with activated carbon. With these materials, we characterized selectively removal efficiency to identify new ion-exchange material with chemical-biological protective capability. Conclusion: This study shows that a QFD aids in deciding with of the adsorption parameters to optimized with chemical-biological protection cloth manufacturing.

백판지 Varnish Coating적성 개선에 대한 연구

  • 곽상효;황명동;이경현;박광만;이순용
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
    • /
    • 2001.04a
    • /
    • pp.79-79
    • /
    • 2001
  • 백판지는 포장용기로 사용되기 때문에 인쇄적성 이외에 다양한 후가공적성이 요구 된다. V Varnish Coating도 이러한 후가공적성 중의 하나로서 국내 인쇄소에서는 기계 코팅으로 불리 우며, 목적은 표면에 고분자수지 피막을 입힘으로써 인쇄물의 광택을 높여서 상품가치를 높이고 수운침투와 같은 외부환경의 변화로부터 상품을 안전하게 보관하기 위함이다. arnish C Coating은 인쇄기의 마지막 Unit에서 인쇄와 동일한 방식으로 진행되는데, 코팅액의 배합은 인쇄소와 인쇄물에 따라 상이하다. 본 연구는 Varnish Coating(OI하 기계코팅) 광택향상을 통 한 품질개선 목적으로 수행되었다. 기계 코팅의 특 성 을 파 악 하 기 위 해 서 Gas Chromatography / Mass Spectrometer와 FT -IR Sp e ectrometer를 사용하여 성문운석을 실시해본 결과 코팅액으로 사용되는 광택바니스는 아크 랄과 페놀수지를 툴루엔 계열의 용매에 녹인 용액이고, 흐$\mid$석제로 쓰이는 인쇄바니스는 스티 렌수지를 동일한 용매에 녹인 용액으로 조사되었다. 기계코팅광택 저하현상의 원인파악을 위해서 도공층의 공극구조를 Mercury Porosimeter를 이용하여 파악한 결과 기공의 부피가 상 대적으로 크게 나타났다. 위의 결과를 토대로 기계코팅광택 저하는 코팅액이 과도한 기공부피를 갖는 도공층 내부 로 대부분 홉수되고 표면에 적은 양만이 잔류하기 때문으로 판단하고 해결방안은 도공층의 기공부피를 줄이는 쪽으로 정하였다. Mayor Coater와 QC를 이용하여 Coating Color Formula t tion 번경실힘을 진행하여 도공지 물성을 분석하였다. 그 결과 Double Coating의 Top Color에 서 강력한 상호작용을 하는 Protein과 콜레이를 감량 하고 경질탄산칼숨을 배제하여 기공의 부피를 줄인 경우 기계코팅광택 향상효과가 두드러지게 나타났다. 이러한 Lab 실험을 바탕으로 결정된 Color Formulation에 대한 현장실험을 진행하였고 Lab 평가 및 실인쇄 평가 결과 원하는 수준의 기계코팅광택 향상을 얻을 수 있었다. 몇 차례의 현장실험과 Long-Run Test한 제품들에 대한 물성을 문석한 결과 기계코팅굉택은 인쇄 광택과 같은 경향을 나타냈으며 실협실적으로 간단하게 측정되는 물성 중에서 Air Permeability와 강한 음의 상관관계롤 보였다.

  • PDF

Changes in postharvest quality of Pleurotus eryngii treated with different shelf temperature and browning inhibitors (큰느타리버섯 유통온도 및 갈변억제처리에 따른 품질 변화)

  • Lee, Yun-Hae;Jeoung, Yun-Kyeoung;Baek, Il-Sun;Lee, Han-Bum;Chi, Jeong-Hyun;Jhune, Chang-Sung
    • Journal of Mushroom
    • /
    • v.11 no.4
    • /
    • pp.297-302
    • /
    • 2013
  • Pleurotus eryngii is one of the main export items in Korean mushroom industry. Whole mushrooms were packed with 30 um polypropylene anti-fog film without trimming. The range of package weight and oxygen permeability of film were 400 g and 2000 $c/m^2$, 24 h,atm, respectively. The anti-browning treatments were sprayed by 0.5%(w/w) solution of Sporix Sporix(Sodium polyphosphate and $ClO_2$ gas The weight loss ratio was increased with increasing shelf period and temperature. There were no big differences in weight loss ratio according to browning inhibitors. In case of $ClO_2$ treatment, the hardness and lightness of stem was showed higher than other treatment for shelf period. As results of freshness, the optimum browning inhibitor of P. eryngii was $ClO_2$ treatment and the shelf life was extended 36days at $10{\sim}15^{\circ}C$.

Compounding and Test of Gasket Rubber for Fuel Cell Stack Application (연료전지 스택 가스켓용 고무재료의 제조와 평가)

  • Hur, Byung-Ki;Kang, Dong-Gug;Kim, Hye-Young;Seo, Kwan-Ho;Park, Lee-Soon
    • Elastomers and Composites
    • /
    • v.42 no.4
    • /
    • pp.232-237
    • /
    • 2007
  • We examined the properties of compound and made compound of the optimum state using the properties of each material to evaluate suitability of FKM, VMQ, EPDM, NBR with gasket for fuel cell which is in general use with the material of gasket. It could be found from the compound made with setting the optimum state that NBR is worse than FKM in the chemical property of matter for a long term, and VMQ is worse than FKM in the elution of a metal ion, and EPDM is worse than FKM in the permeability of gas. As a result of leak evaluation of gasket for fuel cell with using FKM, it appeared leak in short time when contracting pressure is getting lower and sealing pressure is getting higher. And as a result of the life prediction with using Arrhenius model, we could predict that it is possible to continuously drive for 60,000 hours.

Hierarchical 5A Zeolite-Containing Carbon Molecular Sieve Membranes for O2/N2 Separation (산소/질소 분리를 위한 다층구조 제올라이트 5A를 함유한 탄소분자체 분리막 제조)

  • Li, Wen;Chuah, Chong Yang;Bae, Tae-Hyun
    • Membrane Journal
    • /
    • v.30 no.4
    • /
    • pp.260-268
    • /
    • 2020
  • Mixed-matrix carbon molecular sieve membranes containing conventional and hierarchically structured 5A were synthesized for application in oxygen (O2)/nitrogen (N2) separation. In general, incorporating 5A fillers into porous carbon matrices dramatically increased the permeability of the membrane with a marginal decrease in selectivity, resulting in very attractive O2/N2 separation performances. Hierarchical zeolite 5A, which contains both microporous and mesoporous domains, improved the separation performance further, indicating that the mesopores in the zeolite can serve as an additional path for rapid gas diffusion without sacrificing O2/N2 selectivity substantially. This facile strategy successfully and cost-effectively pushed the performance close to the Robeson upper bound. It produced high performance membranes based on Matrimid® 5218 polyimide and zeolite 5A, which are inexpensive commercial products.