• Transactions of the Korean Society of Mechanical Engineers B
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• v.30 no.8 s.251
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• pp.731-740
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• 2006

The solid oxide fuel cell (SOFC) is expected to be a candidate for distributed power sources in the next generation, due to its high efficiency and high-temperature waste heat utilization. In this study, the 5-cell SOFC stack was operated with pure hydrogen or reformed gas at anode side and air at cathode side. When stack was operated with diesel and methane ATR reformer, the influence of the $H_2O/C,\;O_2/C$ and GHSV on performance of stacks have been investigated. The result shows that the cell voltage was decreased with the increase of $H_2O/C$ and $O_2/C$ due to the partial pressure of fuel and water, and cell voltage was more sensitive to $O_2/C$ than $H_2O/C$. Next, the dynamic model of SOFC system included with ATR reformer was established and compared with experimental data. Based on dynamic model, the operation strategy to optimize SOFC-Reformer system was suggested and simulated.

• Bulletin of the Korean Chemical Society
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• v.23 no.8
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• pp.1149-1153
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• 2002

CH4/CO2 dry reforming was carried out to make syn gas on the Ni/Al2O3 catalysts calcined at different temperatures. The Ni/Al2O3 (850 $^{\circ}C)$ catalyst gave good activity and stability w hereas the Ni/Al2O3 $(450^{\circ}C)$ catalyst showed lower activity and stability. The NiO/Al2O3 catalyst calcined at $850^{\circ}C$ for 16 h (Ni/Al2O3 $(850^{\circ}C))$ formed the spinel structure of nickel aluminate, which was confirmed by TPR. The carbon formation rate on the Ni/Al2O3 $(850^{\circ}C)$ catalyst was very low till 20 h, and then steeply increased with reaction time without decreasing the activity for CH4 reforming. The Ni/Al2O3 $(450^{\circ}C)$ catalyst showed high carbon formation rate at the initial reaction time and then, the rate nearly stopped with continuous decreasing the activity for CH4 reforming. Even though the amount of carbon deposition on the Ni/Al2O3 $(850^{\circ}C)$ catalyst was higher than that on the Ni/Al2O3 $(450^{\circ}C)$ catalyst, the activity for CH4ing was also high, which could be attributed to the different type of the carbon formed on the catalyst surface.

• Journal of Ocean Engineering and Technology
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• v.24 no.3
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• pp.46-51
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• 2010

This paper describes the implementation of a precise underwater navigation solution using a multi-sensor fusion technique based on USBL, DVL, and IMU measurements. To implement this precise underwater navigation solution, three strategies are chosen. The first involves heading alignment angle identification to enhance the performance of a standalone dead-reckoning algorithm. In the second, the absolute position is found quickly to prevent the accumulation of integration error. The third one is the introduction of an effective outlier rejection algorithm. The performance of the developed algorithm was verified with experimental data acquired by the deep-sea ROV, Hemire, in the East-sea during a survey of a methane gas seepage area at a 1,500 m depth.

• Journal of the Korean Ceramic Society
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• v.43 no.12 s.295
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• pp.798-804
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• 2006

Co-planar type single chamber solid oxide fuel cell with patterned electrode on a surface of electrolyte has been fabricated by robo-dispensing method and microfluidic lithography. The cells were composed of NiO-GDC-Pd or NiO-SDC cermet anode, $(La_{0.7}Sr_{0.3})_{0.95}MnO_3$ cathode, and yttria stablized zirconia electrolyte. The cell performance at $900^{\circ}C$ was investigated as a function of electrode geometries, such as anode-to-cathode distance, numbers of electrode pairs. Relationship between OCV and I-V characteristics at the optimized operation condition was also studied by DC source meter under the mixed gas condition of methane, air, and nitrogen. An increase of anode-facing-cathode area leads to lower OCV due to intermixing between product gases of anode and cathode, which in turn decreases the oxygen partial pressure difference.

• Transactions of the Korean hydrogen and new energy society
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• v.29 no.5
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• pp.512-522
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• 2018

This study was conducted to investigate on the combustion characteristic with the effects of mat thickness and fuel kinds in a metal-fiber burner. The mode transition point is confirmed by the K value, which was defined as the rate of flow velocity and laminar burning velocity. The ($T^4_{sur}-T^4_{\infty}$) is highest at methane flame with 3 T thickness. Through the measurement of the unburned mixture temperature, the possibility of submerged flame in surface combustion burner was confirmed. The rapid emission of CO occurs nearby limit blow out (LBO) because of the increase of flow velocity. In case of NOx, the trend is similar with surface temperature. However, it also considered that the NOx emission is affected by residence time with flame position.

• Coupled systems mechanics
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• v.1 no.3
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• pp.285-295
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• 2012

In this paper, two types of porous burners with radial and axial flow have been modeled numerically and compared. For this purpose, governing equations were solved one-dimensionally for methane-air premix gas. The mechanism used in simulating combustion phenomenon was 15 stage reduced mechanism based on GRI3.0. In order to compare the two burners, the inlet flow rate and fuel-air ratio have been assumed equal for the two burners. The results of the study indicated that reduction in speed and increase in cross-section area in the direction of flow have a considerable influence on the behavior of radial burner in comparison to axial burner. Regarding temperature distribution inside the burner, it was observed that the two above mentioned factors can be influential in temperature of flame propagation region. Also, regarding distribution of CO and NO emission, the results indicate that the porous radial burner has lower emissions in comparison to the axial once. The output radiative heat transfer efficiency of the two burners was also compared and in this case also even the radial porous burner was found to be preferable.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.1996-2000
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• 2008

In autothermal reforming reaction, oxygen to carbon ratio (OCR) and steam to carbon ratio (SCR) are significant factors, which control temperature and carbon deposition into the reactor. The OCR is more sensitive than the SCR to affect the temperature distribution and reforming efficiency. In conventional operation, hydrocarbon fuel, steam, and oxygen was homogeneously mixed and injected into the reactor in order to get hydrogen-rich gas. The temperature was abruptly raised due to fast oxidation reaction in the former part of the reactor. Deactivation of packed catalysts can be accelerated there. In the present study, therefore, the effect of the oxygen distribution is introduced and investigated to suppress the carbon deposition and to maintain the reactor in the mild operating temperature (e.g., $700{\sim}800^{\circ}C$). In order to investigate the effect numerically, the following models are adopted; heterogeneous reaction model and two-medium model for heat balance.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.21 no.1
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• pp.41-48
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• 2009

The present study has been performed to investigate the thermal characteristics of under-ventilated compartment fire which is a typical fire condition in structures. A series of fire experiments was conducted to characterize the thermally driven flow in a 2/5 scale ISO 9705 fire compartment. Three different fuels were used in this test series, methane gas, heptane pool, and polystyrene pellets fire. In order to measure accurate temperature, double shield aspirated thermocouples reducing the effect of radiative energy exchange on temperature measurement were used in addition to bare bead thermocouples. The upper layer temperature for well ventilated fire was increased with increasing heat release rate, but it was slightly decreased for under-ventilated fire. The measured temperatures in the upper layer at the front sampling location were higher than at the rear. Thermal characteristics through the doorway were also analysed for a wide range of heat release rates. This study provides a comprehensive and quantitative assessment of fire behavior for under-ventilation condition of fire.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.19 no.6
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• pp.501-506
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• 2006

Carbon nanotubes (CNTs) were grown with a microwave plasma enhanced chemical vapor deposition (MPECVD) method, which has been regarded as one of the most promising candidates for the synthesis of CNTs due to the vertical alignment, the low temperature and the large area growth. MPECVD used methane ($CH_4$) and hydrogen ($H_2$) gas for the growth of CNTs. 10 nm thick Ni catalytic layer were deposited on the Ti coated Si substrate by RF magnetron sputtering method. In this work, the pretreatment was that the Ni catalytic layer in different microwave power (600, 700, and 800 W). After that, CNTs deposited on different pressures (8, 12, 16, and 24 Torr) and grown same microwave power (800 W). SEM (Scanning electron microscopy) images showed Ni catalytic layer diameter and density variations were dependent with their pretreatment conditions. Raman spectroscopy of CNTs shows that $I_D/I_G$ ratios and G-peak positions vary with pretreatment conditions.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.56 no.1
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• pp.1-5
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• 2007

Study on the electron transport coefficient in mixtures of CF4 and Ar, have been analyzed over a range of the reduced electric field strength between 0.1 and 350[Td] by the two-term approximation of the Boltzmann equation (BEq.) method and the Monte Carlo simulation (MCS). The calculations of electron swarm parameters require the knowledge of several collision cross-sections of electron beam. Thus, published momentum transfer, ionization, vibration, attachment, electronic excitation, and dissociation cross-sections of electrons for $CF_4$ and Ar, were used. The differences of the transport coefficients of electrons in $CF_4$ mixtures of Ar, have been explained by the deduced energy distribution functions for electrons and the complete collision cross-sections for electrons. The results of the Boltzmann equation and the Monte Carlo simulation have been compared with the data presented by several workers. The deduced transport coefficients for electrons agree reasonably well with the experimental and simulation data obtained by Nakamura and Hayashi. The energy distribution function of electrons in $CF_4-Ar$ mixtures shows the Maxwellian distribution for energy. That is, $f({\varepsilon})$ has the symmetrical shape whose axis of symmetry is a most probably energy. The proposed theoretical simulation techniques in this work will be useful to predict the fundamental process of charged particles and the breakdown properties of gas mixtures. A two-term approximation of the Boltzmann equation analysis and Monte Carlo simulation have been used to study electron transport coefficients.