• 한국산업보건학회지
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• 제11권3호
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• pp.249-253
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• 2001

The purpose of this study is the development of the simple and precise sampling and analysis method of methyl isocyanate(MIC) in the work place as their secondary aliphatic amine derivatives by gas chromatography with flame ionization detector. The urea derivatives are quantitatively and simultaneously derived from MIC with secondary aliphatic amines such as dipropylamine(DPA), dibutylamine(DBA), and dipentylamine (DAA) in methylene chloride. The method is based on sampling glass tube in XAD-2 resin which is coated with secondary aliphatic amines. The samples are desorbed by $2m{\ell}$ methylene chloride and analysed using gas chromatography with flame ionization detector(GC/FID). In the results, the detection limit of the overall procedure and reliable quantity are $0.020-0.027{\mu}g$($1.347-1.740{\mu}g/m^3$(0.529-0.684 ppb) based on a 15 L air volume) MIC per sample. The average desorption efficiencies are 97.96 - 101.23 %. The results of versus storage time are high and stable recovery rates.

• 대한임베디드공학회논문지
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• 제11권5호
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• pp.299-304
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• 2016

As public interest in air quality and environment problem is increasing, many researches are being carried out the gas measurement system. Especially, Non-dispersive infrared (NDIR) measurements using Beer-Lambert gas sensing principle with very high selectivity and long life time are noted for reliable method. It is possible to detect various gases such as carbon dioxide (CO2), carbon monoxide (CO), and nitrogen dioxide (NO2), but many researches are mostly concentrated on CO2 sensor. The multi-gas measuring instrument is high price and unwieldy, therefore it is not suitable for wide area required numerous instrument. So we study the NDIR multi-gas measurement system for air quality based on wireless sensor network, and experiment the realized measurement system.

• 한국안전학회지
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• 제32권5호
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• pp.168-178
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• 2017

In order to prevent major and chemical accidents, some of the plants which would like to install and operate hazard chemicals handling facilities must submit Off-site Consequence Analysis due to recent arisen leak accidents since 2015. A lot of chemical industrials choose gas detectors as mitigation equipment to early detect gas vapor. The way of placement of gas detectors has two methods; Code-based Design(CBD) and Performance-based Design. The CBD has principles for gas detectors to be installed with consideration for the place that is expected to accumulate gas, and the leak locations according to legal standards and technical guidelines, and has a possibility to be unable to detect by these rules to locate gas detectors by vapor density information. The PBD has two methods; a Geographic Method and Scenario based Method. The Scenario-based Method has been suggested to make up for the Geographic Coverage Method. This Scenario-based Method draw the best optimum placement of gas detectors by considering leak locations, leak speed information, leak directions and etc. However, the domestic placement guidelines just refers to the CBD. Therefore, this study is to compare existing placement location of gas detectors by the domestic CBD with placement locations, coverages and the number of gas detectors in accordance with the Scenario-based Method. Also this study has measures for early detecting interest of Vapor Cloud and suitable placement of gas detectors to prevent chemical accidents. The Phast software was selected to simulate vapor cloud dispersion to predict the consequence. There are two cases; an accident hole size of leak(8 mm) from API which is the highst accident hole size less than 24.5 mm, and a normal leak hole size from KOSHA Guide (1.8 mm). Detect3D was also selected to locate gas detectors efficiently and compare CBD results and PBD results. Currently, domestic methods of gas detectors do not consider any risk, but just depend on domestic code methods which lead to placement of gas detectors not to make personnels recognize tolerable or intolerable risks. The results of the Scenario-based Method, however, analyze the leak estimated range by simulating leak dispersion, and then it is able to tell tolerable risks. Thus it is considered that individuals will be able to place gas detectors reasonably by making objectives and roles flexibly according to situations in a specific plant.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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• pp.323-324
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• 2005

To found out the degradation characteristic of transformer insulation, insulation materials and electrodes are deposited into transformer oil. They used to heated and make flashover. Due to the thermal and electrical stress added to insulation materials, the density of carbon dioxide and hydrogen included in transformer oil was increased. The gas density can measured by using the gas density detection equipment of gas sensor and air circulation method.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.1
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• pp.207-210
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• 2004

In oil-filled equipment such as transformers, partial discharge or local overheating will make insulating material(oil, kraft paper, proclain and wood) be stressed and generate many sort of gases($CO,\;CO_2,\;H_2,\;C_2H_4$) which are dissolved in transformer oil. The ratio of this gas can make diagnostic tecchniques of the lifetime of transfomer so, it is important to monitoring $H_2$ gas continuously. This paper developes a system of detecting about $H_2$ gas by using $H_2$ gas sensor, and we describe operation and performance of this system

• 설비공학논문집
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• 제18권8호
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• pp.672-677
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• 2006

The steady cooling characteristics of a cryochamber for infrared (IR) detector have been investigated analytically, considering radiation shields. The thermal modeling considers the conduction heat transfer through cold finger, the gaseous conduction due to out-gassing, and the radiation heat transfer. The cooling load of the cryochamber is obtained by using a fin equation. The results obtained indicate that the gaseous conduction plays an important role in determining the steady cooling load. The steady cooling load is increased as the gas pressure is increased. It is also found that the cooling load is substantially decreased with a radiation shield. The most thermal load of a cryochamber occurs through the cold finger.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 춘계학술대회 논문집
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• pp.31-35
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• 2004

We propose driving method of Ultraviolet sensor for fire alarms using pulse width modulation that used to fire detector with sensor of private-use detectable light energy as ultraviolet in energy of electromagnetic-wave type radiate from flame, when combustible burn with contain carbon,. Ultraviolet sensor is UV Tron using gas multiplication effect to current discharge and photoelectric effect of metal. To have high sensibility and to gain proper output voltage, it has high responsive performance. This research designed driving circuit with UV sensors and proposed method of false alarm reduced to resemble fire. the result propers the prevention and extinction of fire technique degree, certificated operation of detector.

• 분석과학
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• 제25권6호
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• pp.382-387
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• 2012

산화에틸렌($C_2H_4O$, Ethylene oxide, EtO)은 에탄올아민 같은 공업적으로 중요한 물질이나 에틸렌 글리콜의 생산 원료 또는 살균제로 이용되는 물질이다. 산화에틸렌은 불화탄화수소를 분사제 또는 바탕가스로 하여 액화혼합가스로 제조되어 열에 약한 의료기기나 저장시설의 소독에 널리 사용되고 있다. 액화혼합가스의 생산 및 사용 시 품질관리 및 안전관리를 위해 각 성분의 몰분율을 정확히 측정할 필요가 있다. 휘발성 액체시료 중 각 기체성분들은 증기압이나 끓는점 등과 같이 물리 화학적 성질이 다르므로 몰분율 측정 시 실린더 내부의 상층에 평형을 이루고 있는 기체시료 또는 하층의 기화되지 않은 액체시료를 직접 측정기기에 주입하는 방법에 따라 측정 결과가 다를 수 있다. 본 연구에서는 액화혼합가스를 액체 또는 기체 상태로 주입할 수 있는 새로운 온라인 시료도입장치를 고안하고 GC/AED (gas chromatograph-atomic emission detector)를 사용하여 산화에틸렌과 불화탄화수소 액화혼합가스를 측정하였으며 AED의 검출특성, 기기에 주입 시 시료의 상태, 측정파장에 따른 측정결과의 정확성 및 반복성을 조사하였다.

• 한국가스학회지
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• 제21권5호
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• pp.1-8
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• 2017

현재 산업현장의 가스 안전관리는 접촉식은 LDAR(Leak Detection and Repair), 비접촉식은 레이저 메탄검지기와 IR 카메라를 사용하고 있다. LDAR 방식은 전체 관리를 하는데 많은 인력과 소요시간이 들고, 관리자가 측정을 위해 가까이 접근해야 하므로 안전의 위협을 받을 수 있어 비접촉식이 더 효율적이다. 비접촉식에서 IR(infrared)을 이용한 가스 측정 방안에 대한 연구가 주목받고 있다. 산업 가스 중 메탄가스를 활용하여 측정 거리에 따라 가스 분출량을 변화시켜 OGI(optical gas image)를 촬영하였다. 본 논문은 가스의 배경온도차이가 OGI 의 선명도에 미치는 영향을 확인하기 위한 실험이다. OGI를 통해 가스의 구름모형을 정확하고, 선명하게 보기 위하여 배경온도 조절판을 제작하였다. 배경온도 조절판을 통해 배경온도와 대기온도 차이가 ${\Delta}T0^{\circ}C$일 때 보다 ${\Delta}T-6^{\circ}C$ 차이의 낮은 온도 조건으로 OGI 촬영을 한 결과가 육안을 확인하였을 때 더 선명한 차이가 나타났다. 선명도 차이의 객관성을 부여하기 위하여 추가로 MATLAB 의 RGB 분석법으로 확인한 결과, ${\Delta}T$가 $-6^{\circ}C$ 일 경우 RGB 값의 수치가 약 20% 낮게 나왔다. 배경온도가 대기온도보다 $-6^{\circ}C$ 낮을 때 더 선명하게 보이는 것은 총 복사법칙으로 설명이 가능하다. 가스의 배경온도가 대기온도에 비해 낮게 될 때 OGI 렌즈로 들어오는 가스의 복사에너지가 증가되어 가스가 더 선명하게 보이게 된다.

• Archives of Pharmacal Research
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• 제27권1호
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• pp.25-30
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• 2004

Combinatorial homoserine lactone mixtures and individual products were obtained from the methionine-functionalized resin in solid-phase synthesis. The four-step process consisting of a coupling step of an N-Fmoc-L-methionine, deprotection of N-Fmoc group, N-coupling with a carboxylic acid, and cleavage reaction through a polymer supported strategy is described. Gas chromatography-mass selective detector (GC-MSD) techniques provide the most powerful methods for identifying both the combinatorial mixtures and individual products.