• Title/Summary/Keyword: Gas concentration

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Effects $H_2$ carrier gas on the mechanical properties of poly 3C-SiC thin films ($H_2$ 캐리어가스가 다결정 3C-SiC 박막의 기계적 특성에 미치는 영향)

  • Han, Ki-Bong;Chung, Gwiy-Sang;Hong, Hoang Sy
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.89-90
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    • 2007
  • This paper presents the mechanical properties of 3C-SiC thin film according to 0, 7, and 10% carrier gas $(H_2)$ concentrations using Nano Indentation. When carrier gas $(H_2)$ concentration was 10%, it has been proved that the mechanical properties, elastic modulus and hardness, of 3C-SiC are the best of them. In the case of 10% carrier gas concentration, Young's modulus and Hardness were obtained as 367 GPa and 36 GPa, respectively. When the surface roughness according to $H_2$ concentrations was investigated by AFM (atomic force microscope), when $H_2$ concentration was 10%, the roughness of 3C-SiC thin was 9.92 nm, which is also the best of them. Therefore, in order to apply poly 3C-SiC thin film to MEMS applications, $H_2$ concentration's rate should increase to obtain better mechanical properties and surface roughness.

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Experimental Study on Thermal Characteristics of Heat Exchanger Modules for Multi Burner Boiler (자트로파 유(Crude Jatropha Oil)에 대한 보일러 직접 연소 특성)

  • Kang, Sae-Byul;Kim, Jong-Jin
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2934-2939
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    • 2008
  • We conducted a test of a direct burning of crude Jatropha oil (CJO) in a commercial boiler system. The fuel, crude Jatropha oil is not biodiesel which comes from transeterification process of bio oil, but it is pure plant oil. The higher heating value (HHV) of the CJO is 39.3 MJ/kg (9,380 kcal/kg) and is higher than that of a commercial heating oil, 37.9 MJ/kg. The kinematic viscosity of CJO is 36.2 mm2/s at $40^{\circ}C$ and 8.0 mm2/s at $100^{\circ}C$. The burner used in the test is a commercial burner for a commercial heatingoil and its capacity is 140 kW (120,000 kcal/h). We did a preliminary test whether the combustion is stable or not. The preliminary test was a kind of open air combustion test using the commercial burner with crude Jatropha oil. We found that the combustion can be stable if the crude Jatrophaoil temperature is higher than $90^{\circ}C$. We measured the flue gas concentration by using a gas analyzer. The NOx concentration is $80{\sim}100\;ppm$ and CO concentration is nearly 0 ppm at flue gas O2 concentration of 3.0 and 4.5%.

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Effect of temperature, $GeH_4$ gas pre-flow, gas ratio on formation of SiGe layer for strained Si (Strained Si를 만들기 위한 SiGe layer 형성에 temperature, $GeH_4$ gas pre-flow, gas ratio가 미치는 영향)

  • 안상준;이곤섭;박재근
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.60-60
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    • 2003
  • 디자인 룰에 의해 Gate Length 가 100nm 이하로 줄어듦에 따라 Gate delay 감소와 Switch speed 향상을 위해 보다 더 큰 drive current 를 요구하게 되었다. 본 연구는 dirve current 를 증가시키기 위해 고안된 Strained Si substrate 를 만들기 위한 SiGe layer 성장에 관한 연구이다. SiGe layer를 성장시킬 때 SiH$_4$ gas와 GeH$_4$ gas를 furnace에 flow시켜 Chemical 반응에 의해 Si Substrate를 성장시키는 LPCVD(low pressure chemical vapor depositio)법을 사용하였고 SIMS와 nanospec을 이용하여 박막 두께 및 Ge concentration을 측정하였고, AFM으로 surface의 roughness를 측정하였다. 본 연구에서 우리는 10,20,30,40%의 Ge concentration을 갖는 10nm 이하의 SiGe layer를 얻기 위하여 l0nm 이하의 fixed 된 두께로 SiGe layer를 성장시킬 때 temperature, GeH$_4$ gas pre-flow, SiH$_4$ 와 GeH$_4$의 gas ratio를 변화시켜 성장시킨 후 Ge 의 concentration과 실제 형성된 두께를 측정하였고, SiGe의 mole fraction의 변화에 따른 surface의 roughness 를 측정하였다. 그 결과 10 nm의 두께에서 temperature, GeH$_4$ gas pre-flow, SiH$_4$ 와 GeH$_4$ 의 gas ratio의 변화와 Ge concentration 과의 의존성을 확인 할 수 있었고, SiGe 의 mole traction이 증가하였을 때 surfcace의 roughness 가 증가함을 알 수 있었다. 이 연구 결과는 strained Si 가 가지고 있는 strained Si 내에서 n-FET 와 P-FET사이의 불균형에 대한 해결과 좀 더 발전된 형태인 fully Depleted Strained Si 제작에 기여할 것으로 보인다.

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A Rapid Preconcentration Method Using Modified GP-MSE for Sensitive Determination of Trace Semivolatile Organic Pollutants in the Gas Phase of Ambient Air

  • He, Miao;Xu, Qingjuan;Yang, Cui;Piao, Xiangfan;Kannan, Narayanan;Li, Donghao
    • Bulletin of the Korean Chemical Society
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    • v.35 no.10
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    • pp.2995-3000
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    • 2014
  • A sensitive concentration method utilising modified gas-purge microsyringe extraction (GP-MSE) was developed. Concentration (reduction in volume) to a microlitre volume was achieved. PAHs were utilised as semivolatile analytes to optimise the various parameters that affect the concentration efficiency. The injection rate and temperature were the key factors that affected the concentration efficiency. An efficient concentration (75.0-96.1%) of PAHs was obtained under the optimised conditions. The method exhibited good reproducibility (RSD values that ranged from 1.5 to 9.0%). The GP-MSE concentration method enhances the volume reduction (concentration factor), leading to a low method detection limit ($0.5-15ngL^{-1}$). Furthermore, this method offers the advantage of small-volume sampling, enabling even the detection of diurnal hourly changes in the concentration of PAHs in ambient air. Utilising this method in combination with GC-MS, the diurnal hourly flux of PAHs from the gas phase of ambient air was measured. Indeed, the proposed technique is a simple, fast, low-cost and environmentally friendly.

The Effect of Oxygen Concentration in Hot Exhaust Gas on the $NO_{x}$ Emission of Diffusion Flame in Exhaust Gas (고온 배기가스의 산소농도가 배기가스이용 확산화염의 $NO_{x}$ 발생에 미치는 영향)

  • Sohn, H.S.;Jang, S.W.;Choi, D.S.;Kim, H.Y.
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.115-120
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    • 2001
  • The present study examined the possibility of $NO_{x}$ reduction in the high temperature industrial furnaces. duct burner of gas turbine cogeneration and two-stage gas turbine combustor. The experimental study was carried out for the diffusion flame of second stage combustor with the variations of oxygen concentration and supplying rate of hot exhaust gas from first stage combustor. It also examined the flammability range and $NO_{x}$ formation of the second stage combustor in which the fuel is supplying into the mixture of oxygen hot exhaust gas from first stage combustor. The results show that the enrichment of oxygen and increase of exhaust gas lead to increase the $NO_{x}$ up to 50 ppm with 23% $O_{2}$ condition.

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The Synthesis Method of Tin Dioxide Nanoparticles by Plasma-Assisted Electrolysis Process and Gas Sensing Property

  • Kim, Tae Hyung;Song, Yoseb;Lee, Chan-Gi;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.24 no.5
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    • pp.351-356
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    • 2017
  • Tin dioxide nanoparticles are prepared using a newly developed synthesis method of plasma-assisted electrolysis. A high voltage is applied to the tin metal plate to apply a high pressure and temperature to the synthesized oxide layer on the metal surface, producing nanoparticles in a low concentration of sulfuric acid. The particle size, morphology, and size distribution is controlled by the concentration of electrolytes and frequency of the power supply. The as-prepared powder of tin dioxide nanoparticles is used to fabricate a gas sensor to investigate the potential application. The particle-based gas sensor exhibits a short response and recovery time. There is sensitivity to the reduction gas for the gas flowing at rates of 50, 250, and 500 ppm of $H_2S$ gas.

THE EFFECT OF DIETARY PROTEIN AND ALUM IN LITTER ON PERFORMANCE, NH3 GAS CONCENTRATION AND LITTER COMPOSITION IN BROILER

  • 남기홍
    • Proceedings of the Korea Society of Poultry Science Conference
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    • 2001.11a
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    • pp.86-88
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    • 2001
  • An experiment was conducted to determine how broiler performance, feces and litter concentration of N can be maintained and whether NH3 gas concentration can be reduced with reducing dietary CP, adding ALUM(AL2(SO4)3.14H20) in litter and supplementing with amino acid and vitamin D in feed. The experiment was divided into a starter period(1 to 21d) and grower period(22 to 42d), each having three different CP with 90 birds per treatment of 3 replications. The CP treatments consisted of a mean CP of 23.0(control 71), 20.4 (72) and 18.0 (73) % for starter and 21.0(control 71),19.3 (72) and 17.0 (73) % for grower, respectively, but with similar amino acid levels as the control. Alum was mixed in each treatment except control treatment with 200g in kilogram litter(rice bran) weight. Results suggested that reducing CP below control in the diets fed during 3wks and 6wks slightly increased feed gain and slightly decreased feed intake and weight gain. However, there were no significant difference among treatments. Reducing CP caused NH3 gas concentration to decline by 74.8 - 80.9% when Alum was mixed in litter(P < 0.05). Litter N concentration did not show any difference(P > 0.05) among treatments. These results suggest that dietary manipulation with adding Alum in litter show for significant reducing NH3 gas concentration while maintaining acceptable Production performance from broiler.

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A Study on Characteristics of NOx and Ozone by Plasma Reaction (Plasma반응에 의한 NOx와 Ozone의 특성에 관한 연구)

  • Choi Jae Wook;Yamaguma Mizuki;Choi Jae Jin
    • Journal of the Korean Institute of Gas
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    • v.4 no.2 s.10
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    • pp.1-6
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    • 2000
  • In this experiment, we made the plasma reactor which adhere needle electrode in order to treat safely an NOx which was included in the gas. Also we experimently investigated characteristics of equipment and inspected efficiency. As a reaction gas, by using mixture gas of $NO/N_2$ and $N_2/O_2$, we setted up initial NO concentration and gas flow rate was set at 2 ${\iota}$/min. As a reaction characteristics of NOx, when discharge input power was high, NO concentration decreased and when the oxygen concentration increased, the NO decomposition was easy and decomposition energy efficiency was high. Also in case that NO concentration increased, NO decomposition energy efficiency was high but decomposition rate was low. The characteristics of ozone, when discharge input power was high, ozone increased and when $NO/N_2$ concentration increased, the ozone decreased.

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The Explosion Characteristics of City Gas on the Change of Oxygen Concentration and Pressure (산소농도와 압력 변화에 따른 도시가스의 폭발특성)

  • Choi Jae-Wook;Lee In-Sik;Park Sung-tae
    • Journal of the Korean Institute of Gas
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    • v.9 no.1 s.26
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    • pp.38-43
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    • 2005
  • To examine the characteristics of the explosion of city gas, the concentration of oxygen was changed with the change of initial pressure. From the result of the experiment, as the concentration of oxygen was low, the explosion limit became narrow and the minimum concentration of oxygen for the explosion was $12\%$. Furthermore, As the increase of the initial pressure, explosion ranges were a little increased. And as the change of the initial pressure, the maximum explosion pressure were $6.3 kgf/cm^2{\cdot}g,\;12.7 kgf/cm^2{\cdot}g$ and the maximum pressure rising velocity were $245.63 kgf/cm^2/s,\;427.88 kgf/cm^2/s$.

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