• 멤브레인
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• 제20권2호
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• pp.106-112
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• 2010

본 연구에서는 poly(phenylene oxide) (PPO)의 막 표면에 100 ppm의 농도를 갖는 불소가스를 접촉시켜 표면불소화하였다. 표면 개질된 막의 특성을 알아보기 위하여 표면접촉각, XPS, 기체투과 실험을 수행하였다. 표면특성 분석 결과 불소처리 시간이 증가함에 따라 막 표면에 $-CF_2$, $-CF_3$의 perfluoro group의 결합으로 인해 막의 소수성이 증가함을 알 수 있었다. 기체투과 측정으로부터 불소화시간이 증가함에 따라 기체에 대한 투과도는 감소하였으며, 불소노출이 60분 경과한 막의 경우 질소 33%, 산소 23%, 이산화탄소 3%의 감소율을 나타내었다. 선택도의 경우 질소 대비 산소의 경우 3.92로부터 4.47로, 이산화탄소에 대한 질소의 경우 18.09에서 25.4로 증가함을 얻었다.

• 한국수소및신에너지학회논문집
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• 제35권1호
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• pp.34-39
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• 2024

Korea government is trying to supply liquid hydrogen from another country to domestic The research for liquid hydrogen transportation and liquefaction plant of hydrogen underway for several years, and empirical research is also planned in the future. Along with the development of liquid hydrogen transport ship/liquefaction plant technology, the development of liquid hydrogen reception base technology must be carried out. In this study, a concept level liquid hydrogen receiving terminal is constructed based on the process of the LNG receiving terminal. Based on this, a study is conducted on the development of analysis technology for the amount of BOG (pipe, tank) generated during cooldown and unloading in the liquid hydrogen unloading line (loading arm to storage tank). The research results are intended to be used as basic data for the design and liquid hydrogen receiving terminal in the future.

• 한국산업융합학회 논문집
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• 제23권5호
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• pp.727-733
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• 2020

Recently, reciprocating cryogenic pumps are mainly developed for small-and-mid sized fuel supply systems. Centrifugal type pumps are not actively developed. Most cryogenic submerged pumps are imported. For transportation, cryogenic liquefied natural gas requires the liquid pump technology that can works in extreme evironments. In order to transport liquefied natural gas, it is necessary to apply pump technology. This is the fundamental research for developing the submerged pump technology applicable to the transportation and storage system equipment of cryogenic liquefied system. It tries to secure basic design materials through reverse-engineering in the cryogenic submerged pump development. Regarding materials, STS-304 and STS-431 which are stainless materials widely used in the cryogenic area are applied. Aluminum alloy is applied to impeller and upper manifolder and the pump rotates at the high speed of 6,000rpm.

• 대한기계학회논문집B
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• 제28권10호
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• pp.1279-1287
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• 2004

The vaporization characteristics of a liquid heptane droplet in a supercritical nitrogen flow are numerically studied. The transient conservation equations of mass, momentum, energy, and species are expressed in an axisymmetric coordinate system. The governing equations are solved time marching method with preconditioning scheme. The modified Soave-Redlich-Kwong equation of state is employed for taking account of real gas effects such as thermodynamic non-ideality and transport anomaly. Changing the convective velocity and ambient pressure, several parametric studies are conducted. The numerical results show that the two parameters, Reynolds number and dimensionless combined parameter(${\mu}$s/${\mu}$d)(equation omitted), have influence on supercritical droplet vaporization.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집E
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• pp.524-529
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• 2001

Because of the ozone layer depletion and global wanning, new alternative refrigerants are being developed. Among them, HFC refrigerants are thought promising, but some European countries are arguing that these refrigerants are also harmful to the global wanning. Therefore, natural refrigerants should be considered as an eventual alternative in refrigerators and heat pumps. In the present study, the supercritical gas cooling process are computationally analysed by employing various turbulence models of carbon dioxide in a trans critical refrigeration cycle. The gas cooling process near the critical point experiences a drastic change in thermodynamic and transport properties, thus the heat transfer characteristics would be different from those of two or single phases. Based on the computational results, the correlations to estimate the near-critical heat transfer characteristics will are obtained.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 춘계학술대회논문집
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• pp.335-338
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• 2003

A finite element-based, integrated process model has been developed and applied to predict the detailed, three-dimensional aspects of the thermo-mechanical behavior occurring in the slab caster considering inclusion removal from molten steel by argon bubble flotation. Gas bubbles are simulated using the dispersion model calculating the volume fraction, and the bubble capture effect is included by a source term in the transport equation for particles. The process model is applied to the investigation of the effect of various process parameters on the inclusion removal in the molten steel.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2004년도 추계학술발표대회 개요집
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• pp.183-184
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• 2004

High capacity container carrier has been considered for many decades to transport the more containers at the same time. Therefore, it is required for high capacity container ship to be applied thicker plate to accomodate a number of containers compared to that of general container ship. To maintain the same productivity of this thicker plate, new welding process should be considered. One of the process for vertical-up position is 2 electrodes EGW(Electro Gas Welding). 2 ectrodes EGW was applied and evaluated whether it can be applicable or not. The heat input used for 72mm thick plate was 520k11cm. from the mechanical test, it is considered that this process can be applicable, showing satisfaction of mechanical properties such as tensile strength, elongation and impact property.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2001년도 춘계 학술대회논문집
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• pp.111-115
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• 2001

The study of nonlinear gas transport in rarefied condition or associated with the microscale length of the geometry has emerged as an interesting topic in recent years. Along with the DSMC method, several fluid dynamic models that come under the general category of the moment method or the Chapman-Enskog method have been used for this type of problem. In the present study, on the basis of Eu's generalized hydrodynamics, a computational model for diatomic gases is proposed. The preliminary result indicates that the bulk viscosity plays a considerable role in fundamental flow problems such as the shock structure and shear flow. The general properties of the constitutive equations are obtained through a simple mathematical analysis. With an iterative computational algorithm of the constitutive equations, numerical solutions for the multi-dimensional problem can be obtained.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2007년도 춘계학술대회
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• pp.9-12
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• 2007

The transport mechanisms of the MTES (methyltriethoxysilane) templating silica/a-alumina composite membrane were evaluated by using four binary and one quaternary hydrogen mixtures through permeation experiments at unsteady- and steady-states. Since the permeation flux in the MTES membrane, through the experimental and theoretical studies, was affected by molecular sieving effects as well as surface diffusion properties, the kinetic and equilibrium separation should be considered simultaneously according to molecular properties. In order to depict the transient multi-component permeation on the templating silica membrane, the GMS (generalized Maxwell-Stefan) and DGM (dust gas model) were adapted to unsteady-state material balance.

• 대한기계학회논문집B
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• 제27권11호
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• pp.1595-1603
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• 2003

Droplet combustion at high ambient pressures is studied numerically by formulating one dimensional combustion model in the mixture of n-heptane fuel and air. The ambient pressure is supercritical conditions. The modified Soave-Redlich-Kwong state equation is used in the evaluation of thermophysical properties to account for the real gas effect on fluid p-v-T properties in high pressure conditions. Non-ideal thermodynamic and transport property at near critical and supercritical conditions are also considered. Several parametric studies are performed by changing ambient pressure and initial droplet diameter. Droplet lifetime decreased with increasing pressure. Surface temperature increased with increasing pressure. Ignition time increased with increasing initial droplet diameter. Temporal or spatial distribution of mass fraction, mass diffusivity, Lewis number, thermal conductivity, and specific heat were presented.