• Title/Summary/Keyword: Gas Resistance

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A Study on the Detection Behavior of Chlorine Dioxide on Metal Oxide Sensors (금속산화물센서의 이산화염소 가스에 대한 감지거동에 관한 연구)

  • Yu, Joon-Boo;Byun, Hyung-Gi
    • Journal of Sensor Science and Technology
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    • v.29 no.3
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    • pp.211-214
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    • 2020
  • Chlorine dioxide is very effective gas for sterilization or disinfection (in manufacturing), and does not produce harmful by-products after use. However, if its concentration exceeds 10 %, it become explosive and cannot be compressed or stored. Therefore, it is necessary to measure its concentration. In this study, the concentration of chlorine dioxide with a high oxidizing strength was measured using a metal oxide sensor. The sensor was a commercially available TGS series from Figaro. The sensitivity of the sensor was inversely proportional to a low concentration of chlorine dioxide gas below 6 ppm and returned to the initial resistance at about 6 ppm. When the gas concentration reached multiples of 10 ppm, resistance of the sensor increased to several megaohms.

NOx Gas Detection Characterization with Vgs in the MWCNT Gas Sensor of MOS-FET Type (MOS-FET구조의 MWCNT 가스센서에서 Vgs의 변화에 따른 NOx 가스 검출 특성)

  • Kim, Hyun-Soo;Park, Yong-Seo;Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.4
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    • pp.257-261
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    • 2014
  • Carbon nanotubes (CNT) has the excellent physical characteristics in the sensor, medicine, manufacturing and energy fields, and it has been studied in those fields for the several years. We fabricated the NOx gas sensors of MOS-FET type using the MWCNT. The fabricated sensor was used to detect the NOx gas for the variation of $V_{gs}$ (gate-source voltage) with the ambient temperature. The gas sensor absorbed the NOx gas molecules showed the decrease of resistance, and the sensitivity of sensor was reduced by the NOx gas molecules accumulated on the MWCNT surface. Furthermore, when the voltage ($V_{gs}$) was applied to the gas sensor, the term of the decrease in resistance was increased. On the other hand, the sensor sensitivity for the injection of NOx gas was the highest value at the ambient temperature of $40^{\circ}C$. We also obtained the adsorption energy ($40^{\circ}C$) using the Arrhenius plots by the reduction of resistance due to the $V_{gs}$ voltage variations. As a result, we obtained that the adsorption energy also was increased with the increasement of the applied $V_{gs}$ voltages.

Behavior of Nitrogen in the Variation of Heat Treatment Conditions of Super Duplex Stainless Steel (수퍼 2상 스테인리스강의 열처리 조건변화에 따른 첨가원소 질소의 거동)

  • Joo, Dong Won;Sung, Jang Hyun
    • Journal of the Korean Society for Heat Treatment
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    • v.10 no.1
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    • pp.30-39
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    • 1997
  • After changing the heat treating atmosphere of nitrogen gas, argon gas and vacuum, the nitrogen contents, microstructural changes, hardness and corrosion resistance of 0.25wt.%N alloyed super duplex stainless steel have been investigated in the temperature range from $1050^{\circ}C$ to $1350^{\circ}C$. The nitrogen content showed to be increased up to 0.36wt.% after heat treating the specimen in nitrogen gas at $1200^{\circ}C$, while the decrement of nitrogen content in vacuum atmosphere was shown down to 0.03wt.% at $1350^{\circ}C$. After heat treating in the mixed gas atmosphere of argon and nitrogen at $1250^{\circ}C$, the surface ${\gamma}$ phase existed as ${\alpha}+{\gamma}$ phase increased with increasing nitrogen gas content. The ${\gamma}$ single phase appeared at the surface above $80%N_2$ gas, while the surface ${\alpha}$ single phase was shown below $20%N_2$ gas. When heat treating the specimen in nitrogen gas at $1050^{\circ}C$, the hardness of austenite phases increased above Hv 40 at the surface layer compared to the hardness of the core parts, while decrement of denitriding effect caused to the hardness nearly unchanged between surface and the core parts after heat treating in vacuum atmosphere. The surface ${\gamma}$ single phase specimen showed superior corrosion resistance than the surface ${\alpha}$ single phase specimen. The surface ${\alpha}$ phase existed in the ${\alpha}+{\gamma}$ microstructure showed higher corrosion resistance after heat treating in the nitrogen gas atmosphere than the ${\alpha}$ phase heat treated in the argon gas and vacuum atmosphere.

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Study on the Welding Parameters of Steel Pipes for Higher Sulfide Stress Corrosion Cracking Resistance for Field Application

  • Baek, Kwang Ki;Lee, Ho il;Lee, Chul Hwan
    • Corrosion Science and Technology
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    • v.3 no.4
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    • pp.154-160
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    • 2004
  • The Sulfide Stress Corrosion Cracking (SSCC) resistance of structural steels is one of the critical concerns for the operators, material designers, and fabricators of oil-field equipment, especially treating sour gas (H2S) containing fluids. As far as its fabricators concerned, the systematic care of welding parameters should be taken to obtain comparable SSCC resistance of their weldment to that of its base material. In this respect, every different type of welding joint design for this use should be verified to be SSCC-proof with relevant test procedures. In this study, the welding parameters to secure a proper SSCC resistance of steel pipe's weldments were reviewed on the Welding Procedure Qualification Records (WPQR), which had been employed for actual fabrication of an offshore structure for oil and gas production. Based on this review, a guideline of welding parameters, such as, heat input, welding consumable for Y.S. 65 ksi class steel pipe material is proposed in terms of the NACE criteria for SSCC resistance.

Oil-Jet Ball 윤활시 가스터빈용 고속 Ball Bearing 윤활특성

  • 김기태;권우성
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1996.04b
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    • pp.86-93
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    • 1996
  • The lubrication characteristics of high-speed ball bearings has been investigated empirically using 45mm bore split inner ring ball bearings employed in small industrial gas turbine engines with oil-jet lubrication method. For the close structural simulation, experiments carried out with bearing mounting supports of real engines, such as bearing housings and oil nozzle assemblies with squeeze film dampers. Thus the results of tests can be directly applied to the design and the development of gas turbine engines. Testing was done by varying operating speeds, axial load on bearings, and lubricant flowrates. During testing, the temperature of bearing at outer-ring face, the power consumption of the driving motor, and the rotating resistance of the bearing were measured. From this study, the representative factors for lubrication characteristics at high speed was found, and the most important one was not operating speed but axial load up to 1.95 million dmN speed and 303 kgf axial load. Furthermore, the detailed variation of the rotational resistance of the bearing could be visualized by measuring the change of the radial load under the bearing supports. The rotational resistance consists of the frictional resistance and the bearing-cavity oil resistance.

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Effects of RF Power, Substrate Temperature and Gas Flow Ratio on the Mechanical Properties of WCx Films Deposited by Reactive Sputtering (반응성 스퍼터링법에서의 RF전력, 기판온도 및 가스유량비가 WCx막의 기계적 특성에 끼치는 효과)

  • Park Y. K.;Lee C. M.
    • Korean Journal of Materials Research
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    • v.15 no.10
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    • pp.621-625
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    • 2005
  • Effects of rf power, pressure, sputtering gas composition, and substrate temperature on the deposition rate of the $WC_x$ coatings were investigated. The effects of rf power and sputtering gas composition on the hardness and corrosion resistance of the $WC_x$ coatings deposited by reactive sputtering were also investigated. X-ray diffraction (XRD) and Auger electron spectroscopy (AES) analyses were performed to determine the structures and compositions of the films, respectively. The hardnesses of the films were investigated using a nanoindenter, scanning electron microscopy, ana a salt-spray test, respectively. The deposition rate of the films was proportional to rf power and inversely proportional to the $CH_4$ content of $Ar/CH_4$ sputtering gas. The deposition rate linearly increased with increasing chamber pressure. The hardness of the $WC_x$ coatings Increased as rf power increased. The highest hardness was obtained at a $Ar/CH_4$ concentration of $10 vol.\%$ in the sputtering gas. The hardness of the $WC_x$ film deposited under optimal conditions was found to be much higher than that of the electroplated chromium film, although the corrosion resistance of the former was slightly lower than that of the latter.

The Effect of Post Oxidation on Corrosion Characteristics of Gas Nitrocarburised Carbon Steels (Nitrocarburising 처리된 탄소강의 내식특성에 미치는 Post Oxidation 효과)

  • Kim, Y.H.;Jung, K.H.
    • Journal of the Korean Society for Heat Treatment
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    • v.12 no.1
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    • pp.9-20
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    • 1999
  • The effect of post oxidation, water-quenched after holding in air for 5~420 seconds or cooling or furnace cooling, on corrosion resistance and phase formation characteristics of the surface layer of SM20C and SM45C carbon steels after gas nirtrocarbursing in the $NH_3-5%CO_2-N_2$ gas atmosphere at $580^{\circ}C$ for 3hours is studied. The compound layers of two steels consist of ${\varepsilon}-Fe_{2-3}N$, ${\gamma}^{\prime}-Fe_4N$ and $Fe_3O_4$, phases, however, the quantity of ${\gamma}^{\prime}-Fe_4N$ phase increases for the furnace cooled specimen compared to that of air cooling specimen. With increasing $NH_3$ content in the gas mixture and also increasing the keeping time in the air after gas nitrocarburising, the ${\varepsilon}-Fe_{2-3}N$ phase of compound layer increases, while the decreased current density recognizing the improvement of corrosion resistance are shown. the passive current density of SM45C steel is lower than that of SM20C steel at the same nitrocarburising conditions.

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Fast Responding Gas Sensors Using Sb-Doped SnO2 Nanowire Networks (Sb-첨가 SnO2 나노선 네트워크를 이용한 고속응답 가스센서)

  • Kwak, Chang-Hoon;Woo, Hyung-Sik;Lee, Jong-Heun
    • Journal of Sensor Science and Technology
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    • v.22 no.4
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    • pp.302-307
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    • 2013
  • The Sb-doped $SnO_2$ nanowire network sensors were prepared by thermal evaporation of the mixtures between tin and antimony powders. Pure $SnO_2$ nanowire networks showed high sensor resistance in air ($99M{\Omega}$), similar gas responses to 4 diffferent gases (5 ppm $C_2H_5OH$, CO, $H_2$, and trimethylamine), and very sluggish recovery speed (90% recovery time > 800 s). In contrast, 2 wt% Sb-doped $SnO_2$ showed the selective detection toward $C_2H_5OH$ and trimethylamine, relatively low resistance ($176k{\Omega}$) for facile measurement, and ultrafast recovery speed (90% recovery times: 6 - 18 s). The change of gas sensing charactersitics by Sb doping was discussed in relation to gas sensing mechanism.

Throat Carriage Rate and Antimicrobial Resistance of Streptococcus pyogenes In Rural Children in Argentina

  • Delpech, Gaston;Sparo, Monica;Baldaccini, Beatriz;Pourcel, Gisela;Lissarrague, Sabina;Allende, Leonardo Garcia
    • Journal of Preventive Medicine and Public Health
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    • v.50 no.2
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    • pp.127-132
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    • 2017
  • Objectives: The aim of this study was to determine the prevalence of asymptomatic carriers of group A ${\beta}-hemolytic$ streptococci (GAS) in children living in a rural community and to investigate the association between episodes of acute pharyngitis and carrier status. Methods: Throat swabs were collected from September to November 2013 among children 5-13 years of age from a rural community (Maria Ignacia-Vela, Argentina). The phenotypic characterization of isolates was performed by conventional tests. Antimicrobial susceptibility was assayed for penicillin, tetracycline, chloramphenicol, erythromycin, and clindamycin (disk diffusion). The minimum inhibitory concentration was determined for penicillin, cefotaxime, tetracycline, and erythromycin. Results: The carriage of ${\beta}-hemolytic$ streptococci was detected in 18.1% of participants, with Streptococcus pyogenes in 18 participants followed by S. dysgalactiae ssp. equisimilis in 5. The highest proportion of GAS was found in 8 to 10-year-old children. No significant association between the number of episodes of acute pharyngitis suffered in the last year and the carrier state was detected (p>0.05). Tetracycline resistance (55.5%) and macrolide-resistant phenotypes (11.1%) were observed. Resistance to penicillin, cefotaxime, or chloramphenicol was not expressed in any streptococcal isolate. Conclusions: The present study demonstrated significant throat carriage of GAS and the presence of group C streptococci (S. dysgalactiae ssp. equisimilis) in an Argentinian rural population. These results point out the need for continuous surveillance of GAS and non-GAS carriage as well as of antimicrobial resistance in highly susceptible populations, such as school-aged rural children. An extended surveillance program including school-aged children from different cities should be considered to estimate the prevalence of GAS carriage in Argentina.

The Effect of Shielding N2 gas on The Pitting Corrosion of Seal-welded Super Austenitic Stainless Steel by Autogenous Welding

  • Kim, Ki Tae;Chang, Hyun Young;Kim, Young Sik
    • Corrosion Science and Technology
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    • v.16 no.2
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    • pp.49-58
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    • 2017
  • Many research efforts on the effect of nitrogen on the corrosion resistance of stainless steels have been reported, but little research has been conducted on the effect of nitrogen for the weldment of stainless steels by the seal-weld method. Therefore, this work focused on the determining the corrosion resistance of tube/tube sheet mock-up specimen for sea water condensers, and elucidating the effect of shielding nitrogen gas on its resistance. The pitting corrosion of autogenously welded specimen propagated preferentially along the dendritic structure. Regardless of the percent of shielding nitrogen gas, the analyzed nitrogen contents were very much lower than that of the bulk specimen. This can be arisen because the nitrogen in shielding gas may partly dissolve into the weldment, but simultaneously during the welding process, nitrogen in the alloy may escape into the atmosphere. However, the pitting resistance equivalent number (PREN) of the interdendrite area was higher than that of the dendrite arm, regardless of the shielding gas percent; and the PREN of the interdendrite area was higher than that of the base metal; the PREN of the dendrite arm was lower than that of the base metal because of the formation of (Cr, Mo) rich phases by welding.