• Title/Summary/Keyword: GAC

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A Study on Selective Adsorption of Phenanthrene Dissolved in Triton X-100 Solution using Activated Carbons (활성탄을 이용한 Triton X-100 용액에서의 phenanthrene의 선택적 흡착에 관한 연구)

  • Ahn, Chi-Kyu;Kim, Young-Mi;Woo, Seung-Han;Park, Jong-Moon
    • Journal of Soil and Groundwater Environment
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    • v.11 no.2
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    • pp.13-21
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    • 2006
  • Polycyclic aromatic hydrocarbons (PAHs) are widespread soil contaminants and major environmental concerns. PAHs have extremely low water solubility and are strongly sorbed to soil. A potential technology for remediation of PAHcontaminated soils is a soil washing with surfactant solutions. While the use of surfactants significantly enhances the performance of soil remediation, operation costs are increased. Selective adsorption of PAHs by activated carbons is proposed to reuse the surfactants in the soil-washing process. The adsorption isotherms of pure chemicals (Triton X-100 and phenanthrene) onto three granular activated carbons were obtained. The selective adsorption of phenanthrene in mixed solution was examined at various concentrations of phenanthrene and Triton X-100. The selectivity results were discussed with pore size distribution of activated carbons and molecular sizes of phenanthrene and the Triton X-100 monomer. The selectivity for phenanthrene was much larger than 1 regardless of the particle size of activated carbons. The selective adsorption using activated carbons with proper pore size distribution would greatly reduce the material cost for the soil washing process by the reuse of the surfactants.

Adsorption Characteristics for Nitrosamines in Granular Activated Carbon Process (입상활성탄 공정에서의 nitrosamine류 흡착 특성)

  • Kim, Kyung-A;Son, Hee-Jong;Lee, Sang-Won;Bin, Jae-Hoon;Kim, Chang-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.10
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    • pp.709-714
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    • 2012
  • This study accessed the adsorption characteristics of the nine nitrosamine species on coal-based granular activated carbon (GAC). The breakthrough appeared first for NDMA and sequentially for NMOR, NPYR, NMEA, NDPA, NDEA, and NPIP. On the other hand, NDBA and NDPHA were not detected in the treated effluent for the operation period. The maximum adsorption capacity (X/M) for the seven nitrosamine species with apparent breakthrough points ranged from $27.5{\mu}g/g$ (for NDMA) to $671.0{\mu}g/g$ (for NPIP). Carbon usage rate (CUR) for NDMA was 1.07 g/day, 13.4 times higher than that for NPIP (0.08 g/day). The X/M values for the seven nitrosamine species were fitted well with a linear regression ($r^2$ = 0.94) by their octanol-water partitioning coefficient ($K_{ow}$).

Gaseous TCE and PCE Degradation with or without a Nonionic Surfactant (비이온 계면활성제의 주입과 비주입 할 경우 기체 상태의 TEC와 PEC 분해)

  • Kim, Jong-O
    • Journal of Korean Society for Atmospheric Environment
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    • v.13 no.1
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    • pp.31-40
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    • 1997
  • This study was conducted to investigate the biodegradation of gaseous trichloroethylene (TCE) and tetrachloroethylene (PCE) in an activated carbon biofilter inoculated with phenol-oxidizing microorganisms and to study the effect of surfactant concentration below its critical micelle concentration (CMC) on the re-moval efficiency of TCE or PCE. The investigation was conducted using two specially built stainless steel biofilters, one for TCE and the other for PCE, at residence times of 1.5~7 min. The removal efficiency of gaseous TCE was 100% at a residence time of 7 min and its average inlet concentration of 85 ppm. For gaseous PCE, 100% removal efficiency was obtained at residence times of 4~7 min and its average concentrations of 47~84 ppm. It was found that adsorption by GAC was a minor mechanism for TCE and PCE removal in the activated carbon biofilters. Transformation yields of gaseous TCE and PCE were about 8~48 g of TCE/g of phenol and 6~25g of PCE/g of phenol, according to residence times. This values showed one or two orders of magnitude less than aqueous TCE degradation. The TCE and PCE activated carbon biofilter performances were observed to be a little enhanced but not significantly, when the surfactant was introduced at concentrations of 5~50 mg/L.

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Studies on the Chemical Composition of Korean Cruciferal Seed (한국산(韓國産) 겨자과(科) 종실류(種實類)의 화학적(化學的) 조성(組成))

  • Kim, Chung-Ki;Lee, Sung-Ho
    • Applied Biological Chemistry
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    • v.30 no.1
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    • pp.46-53
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    • 1987
  • For the effective utilization of Korean Crnciferal seeds, the chemical characteristics, lipid composition and amino acid composition were analysed in six kinds. The content of crude lipid was 39.1% to 46.5% in Korean Cruciferal seeds. The iodine value, saponification value and acid value were 93.4 to 107.2, 170.4 to 185.0 and 0.7 to 1.2 in Cruciferal seed oils, respectively. The content of neutral lipids was 95.3% to 96.4% to total lipid, while that of compound lipids was 3.6% to 4.2%. The content of erucic acid teas 33.4% to 51.5% to total fatty acid in Gerg-gac, Chin-ju Daepung, Seoul-cabbage, and that of Mok-po 71 was only 0.8%. The content of erucic acid was decreased with increasing amount of oleic acid, Among the amino acid in defatted seed meals, glutamic acid, leucine, lysine, arginine and proline showed high quantity and the sum of these amino acids occupied 50% to total amino acid. While cystine and methionine were poor in content.

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Investigation of ICAM-1 and β3 Integrin Gene Variations in Patients with Brain Tumors

  • Yilmaz, Umit;Zeybek, Umit;Kahraman, Ozlem Timirci;Kafadar, Ali Metin;Toptas, Bahar;Yamak, Nesibe;Celik, Faruk;Yaylim, Ilhan
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.10
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    • pp.5929-5934
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    • 2013
  • Background: Primary brain tumors constitute a small percent of all malignant cancers, but their etiology remains poorly understood. ${\beta}3$ integrin (ITGB3) has been recognized to play influential roles in angiogenesis, tumor growth and metastasis. Intercellular adhesion molecule-1 (ICAM-1) is a surface glycoprotein important for tumor invasion and angiogenesis. The aim of this study was to investigate whether specific genetic polymorphisms of ICAM-1 and ITGB3 could be associated with brain cancer development and progression in a Turkish population. Our study is the first to our knowledge to investigate the relationship between brain tumor risk and ICAM-1 and ${\beta}3$ integrin gene polymorphisms. Materials and Methods: The study covered 92 patients with primary brain tumors and 92 age-matched healthy control subjects. Evaluation of ${\beta}3$ integrin (Leu33Pro (rs5918)) and ICAM-1 (R241G (rs1799969) and K469E (rs5498)) gene polymorphisms was performed by polymerase chain reaction-restriction fragment length polymorphism (PCR-RFLP). Results: According to results of our research, the A allele of the ICAM-1 R241G gene polymorphism appeared to be a risk factor for primary brain tumors (p<0.001). Similarly, the frequency of the A mutant allele of ICAM-1 R241G was statistically significant in patients with brain tumors classified as glioma (p<0.001). When allele and genotype distributions of ICAM-1 K469E, ICAM-1 R241G and ${\beta}3$ integrin Leu33Pro gene polymorphisms were evaluated with age, sex, and smoking, there were no statistically significant differences. Haplotype analysis revealed that the frequencies of GAC (rs1799969-rs5498-rs5918) and GAT (rs1799969-rs5498-rs5918) haplotypes were significantly lower in patients as compared with controls (p=0.001; p=0.036 respectively). Conclusions: This study provides the first evidence that ICAM-1 R241G SNP significantly contributes to the risk of primary brain tumors in a Turkish population. In addition, our results suggest that ICAM-1 R241G in combination ICAM-1 K469E may have protective effects against the development of brain cancer.

Adaptive Control of End Milling Machine to Improve Machining Straightness (직선도 개선을 위한 엔드밀링머시인 의 적응제어)

  • 김종선;정성종;이종원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.9 no.5
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    • pp.590-597
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    • 1985
  • A recursive geometric adaptive control method to compensate for machining straightness error in the finished surface due to tool deflection and guideway error generated by end milling process is developed. The relationship between the tool deflection and the feedrate is modeled by a modified Taylor's tool life equation. Without a priori knowledge on the variations off cutting parameters, time varying parameters are then estimated by an exponentially windowed recursive least squares method with only post-process measurements of the straightness error. The location error is controlled by shifting the milling bed in the direction perpendicular to the finished surface and adding a certain amount of feedrate with respect to the tool deflection model before cutting. The waviness error is compensated by adjusting the feedrate during machining. Experimental results show that location error is controlled within a range of fixturing error of the bed on the guideway and that about 60% reduction in the waviness error can be achieved within a few steps of parameter adaption under wide operating ranges of cutting conditions even if the parameters do not converge to fixed values.

A LuxR-type Transcriptional Regulator, PsyR, Coordinates Regulation of Pathogenesis-related Genes in Pseudomonas syringae pv. tabaci (Pseudomonas syringae pv. tabaci 에서 LuxR-type 전사조절자인 PsyR에 의한 병원성 유전자들의 조절)

  • Choi, Yeon Hee;Lee, Jun Seung;Yun, Sora;Baik, Hyung Suk
    • Journal of Life Science
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    • v.25 no.2
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    • pp.136-150
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    • 2015
  • Pseudomonas syringae pathovar tabaci is a plant pathogenic bacterium that causes wildfire disease in tobacco plants. In P. syringae pv. tabaci, PsyI, a LuxI-type protein, acts as an AHL synthase, while primary and secondary sequence analysis of PsyR has revealed that it is a homolog of the LuxR-type transcriptional regulator that responds to AHL molecules. In this study, using phenotypic and genetic analyses in P. syringae pv. tabaci, we show the effect of PsyR protein as a quorum-sensing (QS) transcriptional regulator. Regulatory effects of PsyR on swarming motility and production of siderophores, tabtoxin, and N-acyl homoserine lactones were examined via phenotypic assays, and confirmed by quantitative real-time reverse transcription-polymerase chain reaction (qRT-PCR). Further qRT-PCR showed that PsyR regulates expression of these virulence genes in response to environmental signals. However, an upstream region of the gene was not bound with purified MBP-PsyR protein; rather, PsyR was only able to shift the upstream region of psyI. These results suggested that PsyR may be indirectly controlled via intermediate-regulatory systems and that auto-regulation by PsyR does not occur.

Development of a New PCR Method for Detection of Pectobacterium carotovorum (Pectobacterium carotovorum의 검출을 위한 PCR 진단법의 개발)

  • No, Ji-Na;Yoo, Mi-Sun;Park, Dong-Suk;Kim, Jeong-Gu;Yoon, Byoung-Su
    • Korean Journal of Microbiology
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    • v.45 no.4
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    • pp.306-311
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    • 2009
  • A new PCR method was developed to detect Pectobacterium carotovorum which is the causative agent of soft rot in Brassica pekinensis. A specific detection primer set based on Lytic murein transglycolase gene was designed and evaluated. Using ERB3_F (5'-TGC GAC ACC TCC TCA TCA CG-3') and ERB3_R (5'-CTT ATC ACG CTG TAA CCA GC-3') primers, 437 nucleotides long fragment was specifically amplified. The amplified products were observed in 52 out of 55 strains of P. carotovorum or Pectobacterium carotovorum subsp. carotovorum. On the other hand, no amplification was observed in 8 organisms including Chinese cabbage and potato. The optimal PCR condition for the ERB3_F/ERB3_R primer set was $58^{\circ}C$ for annealing and 15 mM for $MgCl_2$. With serially diluted templates, the specific PCR sensitivitie limit was $2\times10^3$ copies. Also, this method can be applied not only to DNA but also to field samples. This PCR method may be expected to be useful for specific detection of P. carotovorum.

A Study on the Preparation of GAC(Granular Activated Carbon) for BAC(Biological Activated Carbon) Process using Oak Wood (참나무를 이용한 BAC(Biological Activated Carbon) Process용 활성탄 제조에 관한 연구)

  • Choi, Jung-il;Lee, Sang-bong;Kim, Dong-Youn
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.6
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    • pp.1037-1044
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    • 2000
  • The objective of this study is the preparation of activated carbon for BAC(biological activated carbon). Prepared activated carbon was measured iodine adsorption(mg/g). methylene blue adsorption(mg/g), B.E.T($m^2/g$), PSD(Pore Size Distribution) and 'Picabiol' which in commercial activated carbon for BAC. Activation method for this study was a chemical activation used the phosphoric acid. In the method, two important factors affected activation characterized in preparation were temperature and impregnated phosphoric acid concentration. Activation temperature and impregnated phosphoric acid concentration were changed the $600{\sim}800^{\circ}C$ and 35~50wt% respectively. Activation time was fixed for 3 hour. Optimal activation temperature was $800^{\circ}C$ and impregnated phosphoric acid concentrations was about 50wt%. By the above condition specific surface area, iodine adsorption number and methylene blue adsorption number resulted $1643.3m^2/g$, 1093 mg/g, 445.6 mg/g, respectively.

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Adsorption characteristics of Amitrol, Nonylphenol, Bisphenol-A with GACs (흡착특성이 다른 내분비계 장애물질 3종, Amitrol, Nonylphenol, Bisphenol-A의 GACs에서의 흡착 특성)

  • Choi, Keun-Joo;Kim, Sang-Goo;Kwon, Ki-Won;Ji, Yong-dae;Kim, Seung-Hyun;Kim, Chang-Won
    • Journal of Korean Society on Water Environment
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    • v.20 no.3
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    • pp.256-264
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    • 2004
  • Adsorption characteristics of three endocrine disruptors, amitrol, nonylphenol, and bisphenol-A, were evaluated depending on the type and service duration of activated carbon (AC). Bituminous coal-, wood-, and coconut-based coals were tested. Bituminous coal-based AC (BCAC) had the greatest sorption capacity for the three chemicals tested, followed by wood-based AC (WAC) for nonylphenol and coconut palm-based AC (CAC) for bisphenol-A. During the column test, amitrol removal efficiency increased over time, indicating that hydrophilic endocrine disruptors are biodegraded in the AC column. Removal efficiencies of hydrophobic compounds such as nonylphenol and bisphenol-A decreased over time since the main removal mechanism was adsorption. The order of the amitrol removal was: BCAC-5.9 yr, CAC-3.l yr > BCAC-2.2 yr > BCAC-virgin > CAC-virgin > WAC-virgin > WAC-3.l yr. In general, used AC had greater removals than virgin AC. The order of the bisphenol-A removal was: CAC-virgin > BCAC-2.2 yr > CAC-3.l yr > WAC-virgin > BCAC-5.9 yr > WAC-3.l yr. The order of the nonylphenol removal was: BCAC-virgin > WAC-virgin > CAC-3.1 yr, WAC-3.1yr> BCAC-2.2 yr > BCAC-5.9 yr > CAC-3.1 yr. Bituminous coal AC performed the best over time. Endocrine disruptors such as these three compounds appear to be removed effectively by activated carbon through biodegradation and adsorption. Wood and coal based among the virgin ACs and 3.1 years used wood base among the used ACs appeared the lowest carbon usage rate(CUR) for nonylphenol removal by prediction model. Virgin and used coconut base ACs except BCAC had the lowest CUR for removal Bisphenol-A. Biodegradation of nonylphenol and Bisphenol-A did not occurred during the 9,800 bed volume experiment period. BCAC had the highest biodegradation capacity of 46% for amitrol among virgin ACs and the used coal based ACs had 33-44% higher biodegradation capacity than virgin's for amitrol so biodegradation is the effective removal technology for hydrophilic material such as amitrol.