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http://dx.doi.org/10.4491/KSEE.2012.34.10.709

Adsorption Characteristics for Nitrosamines in Granular Activated Carbon Process  

Kim, Kyung-A (Water Quality Institute, Busan Water Authority)
Son, Hee-Jong (Busan Water Authority)
Lee, Sang-Won (Water Quality Institute, Busan Water Authority)
Bin, Jae-Hoon (Water Quality Institute, Busan Water Authority)
Kim, Chang-Won (Department of Environment System Engineering, Pusan National University)
Publication Information
Journal of Korean Society of Environmental Engineers / v.34, no.10, 2012 , pp. 709-714 More about this Journal
Abstract
This study accessed the adsorption characteristics of the nine nitrosamine species on coal-based granular activated carbon (GAC). The breakthrough appeared first for NDMA and sequentially for NMOR, NPYR, NMEA, NDPA, NDEA, and NPIP. On the other hand, NDBA and NDPHA were not detected in the treated effluent for the operation period. The maximum adsorption capacity (X/M) for the seven nitrosamine species with apparent breakthrough points ranged from $27.5{\mu}g/g$ (for NDMA) to $671.0{\mu}g/g$ (for NPIP). Carbon usage rate (CUR) for NDMA was 1.07 g/day, 13.4 times higher than that for NPIP (0.08 g/day). The X/M values for the seven nitrosamine species were fitted well with a linear regression ($r^2$ = 0.94) by their octanol-water partitioning coefficient ($K_{ow}$).
Keywords
Nitrosamines; NDMA; Granular Activated Carbon; Adsorption; Carbon Usage Rate; Octanol-Water Partitioning Coefficient;
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