• Title/Summary/Keyword: G 값

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Solubilization of Cresol Isomers by the Cationic Surfactant of TTTAB in Aqueous Solution of n-Butanol and NaCl (n-부탄올 및 NaCl 수용액에서 양이온 계면활성제인 TTAB에 의한 크레졸 이성질체들의 가용화에 대한 연구)

  • Lee, Byung-Hwan
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.3
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    • pp.832-839
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    • 2021
  • We tried to investigate the effects of substituent position, temperature, and additives such as NaCl and n-butanol on the solubilizations of cresol isomers by tetradecyltrimethylammonium bromide (TTAB), using the UV-Vis spectrophotometric method. The measured solubilization constants (Ks) values for each cresol isomer increased in the order o-cresolo and ∆Ho values for the solubilizations of cresols were all negative values but the ∆So values were all positive values within the measured ranges. The values of ∆Go increased also with increasing the concentration of n-butanol but decreased with increasing the concentration of NaCl. From these facts, we could conclude that both the enthalpy and entropy changes contribute together for the solubilizations of cresols isomers by cationic surfactant of TTAB and they are solubilized in the polar palisade region or at the surface of micelle.

The Analysis for Calcium and Fructooligosaccharides Contents in Nutrients Fortified Dairy Products (유가공품 중 칼슘 및 프락토올리고당 영양강화 함량 분석)

  • Park, Ji-Sung;Park, Jae-Woo;Cho, Byung-Hoon;Song, Sung-Ok;Wee, Sung-Hwan;Oh, Soon-Min;Kim, Jin-Man
    • Food Science of Animal Resources
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    • v.33 no.6
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    • pp.781-786
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    • 2013
  • Nutrients fortified dairy products declare their contents on the label for nutrition claim and marketing. However, there are few monitoring studies about relations between actual quantities of fortified nutrients and the described ones on the label. This study was carried out for comparing actual fortified nutrient contents with labeled ones. Forty calcium fortified dairy products and twenty four fructooligosaccharides (FOS) fortified dairy products were sampled at supermarkets located in Anyang, Korea from March to November in 2010. Calcium contents were analyzed by using inductively coupled plasma optical emission spectrometry followed by microwave sample digestion, and FOS contents were analyzed by HPLC-ELSD followed by solvent extraction. In fresh milk, calcium contents ranged from 1.0 to 2.4 mg/mL, and those values were 87~127% of their labeled contents. In fermented milk products and cheeses, calcium contents ranged from 0.3 to 1.6 mg/g (89~131% of their labeled contents), 4.2 to 23.0 mg/g (83~127% of their labeled contents), respectively. FOS contents ranged from 9.09 to 18.89 mg/g in FOS contents labeled products and showed 83~154% compared to their labeled quantity, and ranged from 1.3~30.8 mg/g in products without quantity labeling. In conclusion, the amounts of calcium and FOS in dairy products were above 80% compared to their labeled ones and conformed to the Korean official livestock products labeling standard.

The Study of Technical Error Analysis on BMD Using DEXA (이중 에너지 X선 흡수 계측법을 이용한 BMD 검사 시 발생할 수 있는 기술적인 오류 분석)

  • Kang, Yeong-Han;Jo, Gwang-Ho
    • Journal of radiological science and technology
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    • v.29 no.4
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    • pp.229-236
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    • 2006
  • Purpose: This study was conducted to search for the type of technical error in DEXA(dual-energy X-ray absorptiometry) and the effect of error to measurement of BMD. Materials and Methods: The changes of BMD($g/cm^2$, T-score) by patients information(Age, Weight, Height, Manopause age) input error and Confirming ROI error were investigated. Using spine phantom, we canned 10 times by age(5, 10), weight(10, 20 kg), height(5, 10 cm), manopause age(5, 10) increase & decrease respectively. Scanning region(L-spine, femur, Forearm) of 10 patients was calculated by changing ROI respectively. Analysis of difference for mean(precision 1%) were carried out. Results: The error of patient information(Age, Weight, Height, Manopause age) was not changed differently. In confirming ROI, the BMD and T-score of L-spine involving T-12 was decreased to $0.063\;g/cm^2$, 0.3 and involving L-5 increased to $0.077\;g/cm^2$, 0.5. In narrowing 1 cm of vertical line of ROI, the BMD and T-score decreased to $0.006\;g/cm^2$, 0.1 and in 2 cm, $0.021\;g/cm^2$, 0.15, each. In hip ROI, Upper and left shift(0.5 cm) of line was not influenced BMD and T-score. In 0.5 cm lower shift(lesser trochanter below), the BMD and T-score increased $0.031\;g/cm^2$, 0.3 and in 1 cm $0.094\;g/cm^2$, 0.65, each. In forearm ROI, the BMD and T-score decreased $0.042\;g/cm^2$, 0.9 involving 1 cm lower wrist. And expanding 1 cm of vertical line, the BMD and T-score decreased $0.008\;g/cm^2$, 0.1 and in 2 cm, $0.021\;g/cm^2$, 0.3, each. The L-spine, hip, forearm ROI error was changed differently. Conclusion: There are so many kinds of technical error in BMD processing. Errors according to age, weight, height, manopause age did not influent to $BMD(g/cm^2)$ and T-score. There are mean differences BMD and T-score in confirming ROI. For the precision exam, in L-spine processing, L1-4 have to confirmed without shift of ROI vertical line. In hip processing, the ROI have to included greater trochanter, femur head and lesser trochanter. In forearm processing, the ROI have to included wrist, radius and ulnar.

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Optimization of Extraction Condition on Fig (Ficus carica L.) by Response Surface Methodology (반응표면분석법에 의한 무화과 열수 추출조건의 최적화)

  • Kim, Jung-Ok;Kwon, Soon-Tae;Lee, Gee-Dong;Hong, Joo-Heon;Moon, Doo-Hwan;Kim, Tae-Wan;Kim, Dae-Ik
    • Food Science and Preservation
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    • v.15 no.1
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    • pp.66-73
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    • 2008
  • Response surface methodology (RSM) was applied for monitor the yields of desirable substances from fig (Ficus carica L) under different extraction conditions. The maximum yield was 66.46% at 22.08 mL/g of solvent to sample ratio, $90.59^{\circ}C$ extraction temperature and 148.04 min extraction time. The maximum total phenolics was $121.31{\mu}g/mL$ at 17.87 mL/g, $98.82^{\circ}C$, and 130.80 min. The maximum electron donating ability was 54.09% at $121.31{\mu}g/mL$, 18.13 mL/g, and $98.81^{\circ}C$. The maximum value of protease activity was 54.51 unit/min at 17.45 mL/g, $99.01^{\circ}C$, and 131.43 min. In addition, the maximum value of reducing sugar content was 19.14 mg/mL in 22.66 mL/g, $86.30^{\circ}C$, and 153.59 min. The optimum conditions estimated by RSM for maximal extraction of the effective components were $17{\sim}25$ mL/g of solvent to sample ratio, $80{\sim}100^{\circ}C$ of extraction temperature, and $100{\sim}170$ min of extraction time.

Interlaminar Fracture Toughness of CFRP Laminates with Carbon Non-Woven Tissue Having Different Weights (무게가 상이한 탄소부직포가 삽입된 CFRP적층판의 층간파괴인성)

  • Cheong, Seong-Kyun
    • Composites Research
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    • v.22 no.2
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    • pp.43-48
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    • 2009
  • For the practical use of improved interlaminar fracture toughness by interleaving carbon non-woven tissue (CNWT), intelaminar fracture toughnesses of CFRP laminates with CNWT having different weights were experimentally investigated. A suitable weight of interleaved CNWT in CFRP laminates was discussed with Mode I and Mode II tests. Mode I and Mode II interlaminar fracture toughnesses (GIC and GIIC) were obtained by DCB and ENF tests. Six kinds of specimens with CNWT were prepared. The weights of CNWT per square meter for six types of specimens are $8g/m^2,\;10g/m^2,\;12g/m^2,\;16g/m^2,\;20g/m^2$, and $24g/m^2$, respectively. The mean GIC and GIIC values of six kinds of specimens were not substantially different from one another. Compared with the CFRP specimen, the mean GIC values of six kinds of specimens were slightly decreased. But the mean GIIC values increased tremendously at least twice by interleaving CNWT. It seems that there is no interrelationship between the interlaminar fracture toughnesses (GIC and GIIC) and the interleaving CNWT weights. Consequently, it would be desirable to use the CNWT of $8g/m^2$ among the six kinds of CNWTs to take advantage of the interlaminar fracture toughness improved by interleaving CNWT, because the CNWT of $8g/m^2$ is a lightweight and low-priced material.

A Study on Mode 1 and Mode 2 Interlaminar Fracture Toughness of Carbon Fiber Reinforced Plastics (탄소섬유 복합재료의 모드1 및 모드 2 층간파괴인성치에 관한 연구)

  • Kim, Jae-Dong;Koh, Sung-Wi
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.31 no.3
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    • pp.272-278
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    • 1995
  • In this paper to investigate mode I and mode II critical energy release rates, G sub(IC) and G sub(IIC), three prepregs which are domestic products are used. Those are used for the unidirectional composites, but only one is used for the cross-ply laminate composites which is molded [0/90] sub(6s), [0/45] sub(6s) and [0/45/90] sub(6s). The value of G sub(IC) is almost same when modified three calculating methods are applied. The highest value of G sub(IC) at crack initiation is obtained at the [0/90] sub(6s) interlaminar and the lowest one is at the [0/45/90] sub(6s) interlaminar.

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A Role of Standard Material in Rare Earth Element Analysis by ICP-MS (ICP-MS를 이용한 희토류원소 분석시 표준시료의 선택이 미치는 영향)

  • Lee Seung-Gu;Kim Kun-Han;Song Yong Sun;Kim Yongje
    • The Journal of the Petrological Society of Korea
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    • v.14 no.4 s.42
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    • pp.237-250
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    • 2005
  • In order to clarify the effect of standard rock material in the chemical analysis of rare earth element abundance with ICP-MS, we measured rare earth element abundance of KIGAM granite standard rock material (KG-1), USGS granite standard rock material (G-2), GSJ granite standard rock materials (JG-1a and JG-2). In REE analysis, we used conventional calibration standard solutions, KG-1, JG-1a, JG-2 and G-2 as standard material, respectively. Chondrite-normalized LREE patterns of low granite standard material correspond well each other in the recommended value and the estimated value regardless of a kind of standard rock. However, the HREE patterns of the estimated value based on G-2 or JG-2 and the recommended value are different from each other. Such difference may be due to the wrong recommended value or a specific geochemical properly of the standard rock material itself, The chondrite-normalized REE patterns of four standard rock materials estimated on the basis of KG-1 or JG-1 a show little deviation compared to the those of the recommended values. This suggests that KG-1 and JG-1a may be a optimum standard material for granitoids.

Baseline Sensitivity and Monitoring for the Resistance to Benomyl of Fusarium Species Causing Bakanae Disease in Korea (국내 벼 키다리병균의 Benomyl 약제에 대한 감수성 기준 및 저항성 변화)

  • Choi, Hyo-Won;Lee, Yong Hwan;Hong, Sung Kee;Lee, Young Kee;Lee, Jae Guem;Kim, Hyo Won
    • The Korean Journal of Mycology
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    • v.43 no.4
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    • pp.260-266
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    • 2015
  • To examine the changes in resistance to benomyl of Fusarium species causing bakanae disease, Fusarium isolates were collected in Korea, and pathogenicity tests were performed using rice seeds in vitro. Minimum inhibitory concentration (MIC) and effective concentration of 50% ($EC_{50}$) values of isolates were examined using the agar dilution method. High frequency distribution of MIC values to benomyl against isolates collected in 2006~2007 and 2013~2014 years were $1.5625{\sim}3.125{\mu}g/mL$ and more than $25{\mu}g/mL$, respectively. The mean $EC_{50}$ value of isolates to benomyl increased from $1.6397{\mu}g/mL$ in 2006~2007 to $2.4892{\mu}g/mL$ in 2013~2014. Based on MIC and $EC_{50}$ values of isolates, the moderate resistance of benomyl were determined as more than $25{\mu}g/mL$ of MIC and less $2.4{\mu}g/mL$ of $EC_{50}$ value, and resistant isolates to benomyl were determined as more than $2.4{\mu}g/mL$ of $EC_{50}$ value. Compared with the ratio of resistant isolates in 2006~2007, the ratio of resistance isolates in 2013~2014 increased from 12.5% to 36.4%. In addition, multiple resistant isolates to prochloraz as well as benomyl increased to 20.3% in 2013~2014.

Optimization of Extraction Conditions for Cabbage (홍월적 양배추의 추출조건 최적화)

  • Do, Jeong-Ryong;Kim, Hyun-Ku;Hong, Joo-Heon;Lee, Gee-Dong
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.34 no.10
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    • pp.1625-1632
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    • 2005
  • This study was conducted to monitor the extraction yields and functional properties from cabbage by a response surface methodology. The extract yield was maximized as 44.47$\%$ under the temperature of 79.86$^{\circ}C$, ethanol concentration of 56.84$\%$ and solvent to sample ratio 25.58 mL/g . The maximum value of electron donating ability was 85.46$\%$ at 46.38$^{\circ}C$,57.06$\%$ of ethanol concentration and 27.71 mL/g of solvent to sample ratio. The maximum value of tyrosinase inhibitory effect was 69.37$\%$ at 37.5$^{\circ}C$,47.71$\%$ of ethanol concentration and 16.03 mL/g of solvent to sample ratio. The maximum value of SOD-like activity was 48.36$\%$ in 66.12$^{\circ}C$, 70.35$\%$ of ethanol concentration and 29.13 mL/g of solvent to sample ratio. Estimated conditions for the maximized extraction including yield, electron donating ability and SOD-like activity were 20 $\∼$ 30 mL/g in ratio of solvent to sample, 25$\∼$85$\%$ in ethanol concentration, and 40$\∼$90$^{\circ}C$ in extraction temperature.

Monitoring for the Resistance to Prochloraz of Fusarium Species Causing Bakanae Disease in Korea (국내 벼키다리병균의 Prochloraz 약제에 대한 저항성 변화)

  • Choi, Hyo-Won;Lee, Yong Hwan;Hong, Sung Kee;Lee, Young Kee;Nam, Young Ju;Lee, Jae Guem;Han, Song Hee
    • The Korean Journal of Mycology
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    • v.43 no.2
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    • pp.112-117
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    • 2015
  • To investigate the changes of the resistance to prochloraz of Fusarium species causing bakanae disease, Fusarium isolates were collected from various regions in Korea, and pathogenicity tests were performed using rice seeds. Minimum inhibitory concentration (MIC) and effective concentration of 50% ($EC_{50}$) values of isolates were determined using the agar dilution method. High frequency distribution of MIC values of prochloraz against isolates collected in 2006~2007 and 2013~2014 years were $3.125{\sim}6.25{\mu}g/mL$ and $6.25{\sim}12.5{\mu}g/mL$, respectively. The mean $EC_{50}$ value of isolates increased from $0.3142{\mu}g/mL$ in 2006~2007 to $0.8124{\mu}g/mL$ in 2013~2014. Based on the $EC_{50}$ value of isolates collected in 2006~2007, the resistant baseline of prochloraz was determined as $0.6{\mu}g/mL$. Compared with the ratio of resistant isolates in 2006~2007, the ratio of resistant isolates in 2013~2014 increased from 6.5% to 41.6%.