• Title/Summary/Keyword: Furazan

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Synthesis, Structure and Thermal Properties of Bifurazano[3,4-b:3',4'-f]furoxano[3'',4''-d]oxacyclohetpatriene (BFFO)

  • Zhou, Yanshui;Xu, Kangzhen;Wang, Bozhou;Zhang, Hang;Qiu, Qianqian;Zhao, Fengqi
    • Bulletin of the Korean Chemical Society
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    • v.33 no.10
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    • pp.3317-3320
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    • 2012
  • A novel energetic compound, bifurazano[3,4-b:3',4'-f]furoxano[3'',4''-d] oxacyclohetpatriene (BFFO), was synthesized through special etherification and its structure was determined by single crystal X-ray diffraction. The crystal of $BFFO{\cdot}H_2O$ is monoclinic, space group P2(1)/c with crystal parameters of a = $9.324(4){\AA}$, b = $9.727(4){\AA}$, c = $10.391(4){\AA}$, ${\beta}=106.305(6)^{\circ}$, V = $904.5(6){\AA}^3$, Z = 4, ${\mu}=0.17mm^{-1}$, F(000) = 512 and $D_c=1.866g\;cm^{-3}$. Spectroscopic properties and thermal behaviors of BFFO were studied. BFFO presents good detonation properties.