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http://dx.doi.org/10.5012/bkcs.2012.33.10.3317

Synthesis, Structure and Thermal Properties of Bifurazano[3,4-b:3',4'-f]furoxano[3'',4''-d]oxacyclohetpatriene (BFFO)  

Zhou, Yanshui (Xi'an Modern Chemistry Research Institute)
Xu, Kangzhen (Department of Chemical Engineering, Northwest University)
Wang, Bozhou (Xi'an Modern Chemistry Research Institute)
Zhang, Hang (Department of Chemical Engineering, Northwest University)
Qiu, Qianqian (Department of Chemical Engineering, Northwest University)
Zhao, Fengqi (Xi'an Modern Chemistry Research Institute)
Publication Information
Bulletin of the Korean Chemical Society / v.33, no.10, 2012 , pp. 3317-3320 More about this Journal
Abstract
A novel energetic compound, bifurazano[3,4-b:3',4'-f]furoxano[3'',4''-d] oxacyclohetpatriene (BFFO), was synthesized through special etherification and its structure was determined by single crystal X-ray diffraction. The crystal of $BFFO{\cdot}H_2O$ is monoclinic, space group P2(1)/c with crystal parameters of a = $9.324(4){\AA}$, b = $9.727(4){\AA}$, c = $10.391(4){\AA}$, ${\beta}=106.305(6)^{\circ}$, V = $904.5(6){\AA}^3$, Z = 4, ${\mu}=0.17mm^{-1}$, F(000) = 512 and $D_c=1.866g\;cm^{-3}$. Spectroscopic properties and thermal behaviors of BFFO were studied. BFFO presents good detonation properties.
Keywords
Bifurazano[3,4-b:3',4'-f]furoxano[3'',4''-d]oxacyclohetpatriene (BFFO); Furazan; Crystal structure; Thermal properties;
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