• Title/Summary/Keyword: Fundamental characteristics

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Practical Challenges Associated with Catalyst Development for the Commercialization of Li-air Batteries

  • Park, Myounggu;Kim, Ka Young;Seo, Hyeryun;Cheon, Young Eun;Koh, Jae Hyun;Sun, Heeyoung;Kim, Tae Jin
    • Journal of Electrochemical Science and Technology
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    • v.5 no.1
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    • pp.1-18
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    • 2014
  • Li-air cell is an exotic type of energy storage and conversion device considered to be half battery and half fuel cell. Its successful commercialization highly depends on the timely development of key components. Among these key components, the catalyst (i.e., the core portion of the air electrode) is of critical importance and of the upmost priority. Indeed, it is expected that these catalysts will have a direct and dramatic impact on the Li-air cell's performance by reducing overpotentials, as well as by enhancing the overall capacity and cycle life of Li-air cells. Unfortunately, the technological advancement related to catalysts is sluggish at present. Based on the insights gained from this review, this sluggishness is due to challenges in both the commercialization of the catalyst, and the fundamental studies pertaining to its development. Challenges in the commercialization of the catalyst can be summarized as 1) the identification of superior materials for Li-air cell catalysts, 2) the development of fundamental, material-based assessments for potential catalyst materials, 3) the achievement of a reduction in both cost and time concerning the design of the Li-air cell catalysts. As for the challenges concerning the fundamental studies of Li-air cell catalysts, they are 1) the development of experimental techniques for determining both the nano and micro structure of catalysts, 2) the attainment of both repeatable and verifiable experimental characteristics of catalyst degradation, 3) the development of the predictive capability pertaining to the performance of the catalyst using fundamental material properties. Therefore, under the current circumstances, it is going to be an extremely daunting task to develop appropriate catalysts for the commercialization of Li-air batteries; at least within the foreseeable future. Regardless, nano materials are expected to play a crucial role in this field.

Experimental research on the mechanisms of condensation induced water hammer in a natural circulation system

  • Sun, Jianchuang;Deng, Jian;Ran, Xu;Cao, Xiaxin;Fan, Guangming;Ding, Ming
    • Nuclear Engineering and Technology
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    • v.53 no.11
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    • pp.3635-3642
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    • 2021
  • Natural circulation systems (NCSs) are extensively applied in nuclear power plants because of their simplicity and inherent safety features. For some passive natural circulation systems in floating nuclear power plants (FNPPs), the ocean is commonly used as the heat sink. Condensation induced water hammer (CIWH) events may appear as the steam directly contacts the subcooled seawater, which seriously threatens the safe operation and integrity of the NCSs. Nevertheless, the research on the formation mechanisms of CIWH is insufficient, especially in NCSs. In this paper, the characteristics of flow rate and fluid temperature are emphatically analyzed. Then the formation types of CIWH are identified by visualization method. The experimental results reveal that due to the different size and formation periods of steam slugs, the flow rate presents continuous and irregular oscillation. The fluid in the horizontal hot pipe section near the water tank is always subcooled due to the reverse flow phenomenon. Moreover, the transition from stratified flow to slug flow can cause CIWH and enhance flow instability. Three types of formation mechanisms of CIWH, including the Kelvin-Helmholtz instability, the interaction of solitary wave and interface wave, and the pressure wave induced by CIWH, are obtained by identifying 67 CIWH events.

The simulation study on natural circulation operating characteristics of FNPP in inclined condition

  • Li, Ren;Xia, Genglei;Peng, Minjun;Sun, Lin
    • Nuclear Engineering and Technology
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    • v.51 no.7
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    • pp.1738-1748
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    • 2019
  • Previous research has shown that the inclined condition has an impact on the natural circulation (natural circulation) mode operation of Floating Nuclear Power Plant (FNPP) mounted on the movable marine platform. Due to its compact structure, small volume, strong maneuverability, the Integral Pressurized Water Reactor (IPWR) is adopted as marine reactor in general. The OTSGs of IPWR are symmetrically arranged in the annular region between the reactor vessel and core support barrel in this paper. Therefore, many parallel natural circulation loops are built between the core and the OTSGs primary side when the main pump is stopped. and the inclined condition would lead to discrepancies of the natural circulation drive head among the OTSGs in different locations. In addition, the flow rate and temperature nonuniform distribution of the core caused by inclined condition are coupled with the thermal hydraulics parameters maldistribution caused by OTSG group operating mode on low power operation. By means of the RELAP5 codes were modified by adding module calculating the effect of inclined, heaving and rolling condition, the simulation model of IPWR in inclined condition was built. Using the models developed, the influences on natural circulation operation by inclined angle and OTSG position, the transitions between forced circulation (forced circulation) and natural circulation and the effect on natural circulation operation by different OTSG grouping situations in inclined condition were analyzed. It was observed that a larger inclined angle results the temperature of the core outlet is too high and the OTSG superheat steam is insufficient in natural circulation mode operation. In general, the inclined angle is smaller unless the hull is destroyed seriously or the platform overturn in the ocean. In consequence, the results indicated that the IPWR in the movable marine platform in natural circulation mode operation is safety. Selecting an appropriate average temperature setting value or operating the uplifted OTSG group individually is able to reduce the influence on natural circulation flow of IPWR by inclined condition.

Characteristics of Vowel Formants, Voice Intensity, and Fundamental Frequency of Female with Amyotrophic Lateral Sclerosis using Spectrograms (스펙트로그램을 이용한 근위축성측삭경화증 여성 화자의 모음 포먼트, 음성강도, 기본주파수의 변화)

  • Byeon, Haewon
    • Journal of the Korea Convergence Society
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    • v.10 no.9
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    • pp.193-198
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    • 2019
  • This study analyzed the changes of vowel formant, voice intensity, and fundamental frequency of vowels for 11 months using acoustochemical spectrogram analysis of women diagnosed with amyotrophic lateral sclerosis (ALS). The test word was a vowel /a, i, u/ and a diphthong /h + ja + da/, /h + wi + da/, and /h +ɰi+ da/. Speech data were collected through the word reading task presented on the monitor using 'Alvin' program, and the recording environment was set to 5,500 Hz for the nyquist frequency and 11,000 Hz for the sampling rate. The records were analyzed by using spectrograms to vowel formants, voice intensity, and fundamental frequency. As a result of analysis, the fundamental frequency and intensity of the ALS process were decreased and the formant slope of the diphthong was decreased rather than the formant change in the vowel. This result suggests that the vowel distortion of ALS due to disease progression is due to the decrease of tongue and jaw co morbidity.

A new hybrid meta-heuristic for structural design: ranked particles optimization

  • Kaveh, A.;Nasrollahi, A.
    • Structural Engineering and Mechanics
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    • v.52 no.2
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    • pp.405-426
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    • 2014
  • In this paper, a new meta-heuristic algorithm named Ranked Particles Optimization (RPO), is presented. This algorithm is not inspired from natural or physical phenomena. However, it is based on numerous researches in the field of meta-heuristic optimization algorithms. In this algorithm, like other meta-heuristic algorithms, optimization process starts with by producing a population of random solutions, Particles, located in the feasible search space. In the next step, cost functions corresponding to all random particles are evaluated and some of those having minimum cost functions are stored. These particles are ranked and their weighted average is calculated and named Ranked Center. New solutions are produced by moving each particle along its previous motion, the ranked center, and the best particle found thus far. The robustness of this algorithm is verified by solving some mathematical and structural optimization problems. Simplicity of implementation and reaching to desired solution are two main characteristics of this algorithm.

Theoretical Study of the Circuits for Device of the High Voltage Pulse Generator (고전압 펄스 발생 장치의 회로에 관한 이론적 연구)

  • Kim, Young-Ju
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.27 no.1
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    • pp.99-108
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    • 2013
  • The high-voltage pulse generator is consist of transformers of fundamental wave and harmonic waves, and shunt capacitances. The pulse has the fundamental wave and the harmonic waves that have been increased as a series circuit by the transformers to make high voltage pulse. This paper shows that pulse generator circuit is analyzed using Miller's theorem and network theory(ABCD Matrix) and simulated in frequency and time domain using Matlab program. The output voltage of pulse were obtained to 2.5kHz, 1.8kV. Output pulse voltage increases as $L_m$ increases in low voltage circuit. In high voltage circuit, outer capacitors are related to frequency band pass characteristics.

Improvement of Output Characteristics by Triplen-Harmonics Injection in PWM Inverters (3배수차 고주파 주입에 의한 PWM인버터의 출력특성개선)

  • Lee, Sun-Ho;Joe, Jee-Won;Kim, Ho-Jin;Shin, Woo-Seok;Choe, Gyu-Ha
    • Proceedings of the KIEE Conference
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    • 1990.11a
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    • pp.295-300
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    • 1990
  • This paper describes a new method to increase the fundamental output of PWM inverter by adding all triplen-harmonics to sinusoidal reference wave. As a result, the amplitude of the fundamental component is increased upto 21 percent compared with the conventional SPWM method, and hence the conversion efficiency of dc link is higher. Also as the commutation number of the inverter is decreased to two-thirds, the heating of the switch devices is reduced. In addition random carrier modulation is adopted to lower the acoustic noise at given frequency modulation index.

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Fundamental stuyd on reflection phenomenon of weak pressure-wave from an open end of a pipe (관단으로부터 미소 압력파의 반사에 관한 기초적 연구)

  • Kim, Hui-Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.22 no.5
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    • pp.618-626
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    • 1998
  • This paper describes a series of fundamental studies on reflection and emission of weak pressure waves from an open end of a pipe. Acoustical theories which have been employed in the plane pressure waves inside a pipe are applied to the present study. The objective of the present study is to investigate the reflection or emission coefficient of pressure wave at an open end of a pipe, the length of open end correction, and the directivity characteristics of the pressure waves emitted from the pipe. The results show that the reflection coefficient of pressure wave at an open end and the length of open end correction decrease for the wave length of pressure wave to increase. It is also found that the reflection coefficient for a baffle plate at the exit of pipe is larger than that for no baffle plate.

A study of Dimension in Korea traditional House as the Adaptation of thoughts of Truth (전통가옥에 있어서 도사상의 도입을 통한 공간연구)

  • 양우창
    • Korean Institute of Interior Design Journal
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    • no.11
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    • pp.20-25
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    • 1997
  • The purpose of this study is to find out the correlation between Truth(道) and dimension through the understanding of architectural point of value in the aspect of correlation between modern western thoughts and the thoughts of Truth and also through the reading of what kind of composite trend of the Truth can be seen in a Korea traditional house. This stduy takes the following procedure with reference books and traditional house that we have. 1) Making foundation for this study by finding out the fundamental meaning of the thoughts of Truth through the comparing and analyzing between modern western thoughts and the thoughts of Truth. 2) Reviewing the understanding of dimension in the thoughts of Truth. 3) Traslation of the organic correlation through the analysis of composition, placement and characteristics of dimension in a real present traditional Korea house. 4) Finding out the meaning of each dimension through the adaptation of the fundamental rules of nature of Jane(藏:store), Sang(生:life), Jang(長:long), Su(收obtain) to the dimension composite of a traditional house and concluding that the cyclical process in the oriental thoughts could be made.

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Phasor Estimation Algorithm Based on the Least Square Technique during CT Saturation

  • Lee, Dong-Gyu;Kang, Sang-Hee;Nam, Soon-Ryul
    • Journal of Electrical Engineering and Technology
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    • v.6 no.4
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    • pp.459-465
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    • 2011
  • A phasor estimation algorithm based on the least square curve fitting technique for the distorted secondary current due to current transformer (CT) saturation is proposed. The mathematical form of the secondary current during CT saturation is represented as the scaled primary current with magnetizing current. The information on the scaled primary current is estimated using the least square technique, with the measured secondary current in the saturated section. The proposed method can estimate the phasor of a fundamental frequency component during the saturated period. The performance of the algorithm is validated under various fault and CT conditions using a C400 CT model. A series of performance evaluations shows that the proposed phasor estimation algorithm can estimate the phasor of the fundamental frequency component with high accuracy, regardless of fault conditions and CT characteristics.