• Title/Summary/Keyword: Functional state

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Study on Thermodynamics of Three Kinds of Benzindocarbocyanine Dyes in Aqueous Methanol Solution

  • Huang, Wei;Wang, Lan-Ying;Fu, Yi-Le;Liu, Ji-Quan;Tao, You-Ni;Fan, Fang-Li;Zhai, Gao-Hong;Wen, Zhen-Yi
    • Bulletin of the Korean Chemical Society
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    • v.30 no.3
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    • pp.556-560
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    • 2009
  • Aggregation behavior of three kinds of benzindocarbocyanine dyes in aqueous methanol solution was studied by UV-Vis absorption spectrum. The results indicated that the three dyes all existed monomer-dimer equilibrium in aqueous methanol solution (concentration range $10^{−5}\;to\;10^{−6}$ M) at 25.0$\sim$41.0 ${^{\circ}C}$ for Dye 1, 28.0$\sim$49.0 ${^{\circ}C}$ for Dye 2 and 26.0$\sim$47.0 ${^{\circ}C}$ for Dye 3. The fundamental property of the three dyes as the dimeric association constant KD, the dimeric free energy ${\Delta$}G_D, the dimeric entropy ${\Delta$}S_D, and the dimeric enthalpy ${\Delta$}H_D were determined. The ${\Delta$}H_D of three dyes: Dye 1, Dye 2 and Dye 3 was -42.5, -15.1 and -18.9 kJ/mol, respectively. The experimental observations were the subject of a theoretical study including the ground-state geometries which were fully optimized using DFT at B3LYP/6-31G level. The effect of dye molecule structure on ${\Delta$}H_D was discussed by theoretical calculations.

Functional Magnetic Resonance Imaging with Arterial Spin Labeling: Techniques and Potential Clinical and Research Applications

  • Kim, Ju Ho;Choi, Dae Seob;Park, Sung Eun;Choi, Ho Cheol;Kim, Seong Hu
    • Investigative Magnetic Resonance Imaging
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    • v.21 no.2
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    • pp.91-96
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    • 2017
  • Purpose: To describe technical methods for functional magnetic resonance imaging (fMRI) study with arterial spin labeling (ASL) compared to blood oxygenation level-dependent (BOLD) technique and discuss the potential of ASL for research and clinical practice. Materials and Methods: Task-based (n = 1) and resting-state fMRI (rs-fMRI) (n = 20) were performed using ASL and BOLD techniques. Results of both techniques were compared. Results: For task-based fMRI with finger-tapping, the primary motor cortex of the contralateral frontal lobe and the ipsilateral cerebellum were activated by both BOLD and ASL fMRI. For rs-fMRI of sensorimotor network, functional connectivity showed similar results between BOLD and ASL. Conclusion: ASL technique has potential application in clinical and research fields because all brain perfusion imaging, CBF measurement, and rs-fMRI study can be performed in a single acquisition.

Dynamics of Br(2Pj) Formation in the Photodissociation of Bromobenzene

  • Paul, Dababrata;Kim, Hyun-Kook;Hong, Ki-Ryong;Kim, Tae-Kyu
    • Bulletin of the Korean Chemical Society
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    • v.32 no.2
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    • pp.659-663
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    • 2011
  • The photodissociation dynamics of bromobenzene near 234 nm has been investigated using a two-dimensional photofragment ion-imaging technique coupled with a state-selective [2+1] resonance-enhanced multiphoton ionization (REMPI) scheme. The nascent Br atoms are produced by the primary C-Br bond dissociation, which leads to the formation of $C_6H_5$ ($\tilde{X}$) and Br($^2P_j$, j = 1/2, 3/2). The observed translational energy distributions have been fitted by a single Boltzmann function and two Gaussian functions. Trimodal translational energy distributions of Br($^2P_j$) have been assigned to the direct/indirect dissociation mechanisms originating from the initially excited $^3({\pi},{\pi}^*)$ state. The assignments have been confirmed by the recoil anisotropy and distribution width corresponding to the individual components.

Design and Implementation of CCF in Advanced Intelligent Network (고도 지능망의 CCF 기능실체 설계 및 구현)

  • 유영민;조현준;노승환;이형호;김덕진
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.12
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    • pp.10-17
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    • 1993
  • In this paper, CCF(Call Control Function), functional entity for basic call processing in SSP(Service Switching Point), is designed and implemented. This functional entity can provide the IN(Intelligent Network) services which are included in CCITT CS-1(Capability Set-1), near-term process for IN Architecture. UIO(Unique Input Output) method, one of the thest sequence generation methods for the finite state machine, is used for the implementation test of this functional entity.

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CONVERGENCE PROPERTIES OF PREDATOR-PREY SYSTEMS WITH FUNCTIONAL RESPONSE

  • Shim, Seong-A
    • Honam Mathematical Journal
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    • v.30 no.3
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    • pp.411-423
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    • 2008
  • In the field of population dynamics and chemical reaction the possibility or the existence of spatially and temporally nonhomogeneous solutions is a very important problem. For last 50 years or so there have been many results on the pattern formation of chemical reaction systems studying reaction systems with or without diffusions to explain instabilities and nonhomogeneous states arising in biological situations. In this paper we study time-dependent properties of a predator-prey system with functional response and give sufficient conditions that guarantee the existence of stable limit cycles.

GENERALIZED CUBIC FUNCTIONS ON A QUASI-FUZZY NORMED SPACE

  • Kang, Dongseung;Kim, Hoewoon B.
    • Journal of the Chungcheong Mathematical Society
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    • v.32 no.1
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    • pp.29-46
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    • 2019
  • We introduce a generalized cubic functional equation and investigate the Hyers-Ulam stability of the cubic functions as solutions to the generalized cubic functional equation on a quasi-fuzzy anti-${\beta}$-Banach space by both the direct method and the fixed point method.

Different Functional and Structural Characteristics between ApoA-I and ApoA-4 in Lipid-Free and Reconstituted HDL State: ApoA-4 Showed Less Anti-Atherogenic Activity

  • Yoo, Jeong-Ah;Lee, Eun-Young;Park, Ji Yoon;Lee, Seung-Taek;Ham, Sihyun;Cho, Kyung-Hyun
    • Molecules and Cells
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    • v.38 no.6
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    • pp.573-579
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    • 2015
  • Apolipoprotein A-I and A-IV are protein constituents of high-density lipoproteins although their functional difference in lipoprotein metabolism is still unclear. To compare anti-atherogenic properties between apoA-I and apoA-4, we characterized both proteins in lipid-free and lipidbound state. In lipid-free state, apoA4 showed two distinct bands, around 78 and $67{\AA}$ on native gel electrophoresis, while apoA-I showed scattered band pattern less than $71{\AA}$. In reconstituted HDL (rHDL) state, apoA-4 showed three major bands around $101{\AA}$ and $113{\AA}$, while apoA-I-rHDL showed almost single band around $98{\AA}$ size. Lipid-free apoA-I showed 2.9-fold higher phospholipid binding ability than apoA-4. In lipid-free state, $BS_3$-crosslinking revealed that apoA-4 showed less multimerization tendency upto dimer, while apoA-I showed pentamerization. In rHDL state (95:1), apoA-4 was existed as dimer as like as apoA-I. With higher phospholipid content (255:1), five apoA-I and three apoA-4 were required to the bigger rHDL formation. Regardless of particle size, apoA-I-rHDL showed superior LCAT activation ability than apoA-4-rHDL. Uptake of acetylated LDL was inhibited by apoA-I in both lipid-free and lipid-bound state, while apoA-4 inhibited it only lipid-free state. ApoA-4 showed less anti-atherogenic activity with more sensitivity to glycation. In conclusion, apoA-4 showed inferior physiological functions in lipid-bound state, compared with those of apoA-I, to induce more pro-atherosclerotic properties.

Regulatory View of Point on Health Functional Foods in Korea, Japan, and China

  • Jeong, Jeong-Suk;Kim, Sung-Chull;Jeong, Choon-Sik
    • Natural Product Sciences
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    • v.10 no.6
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    • pp.310-314
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    • 2004
  • This is the re-arrangement of the 2004 Asia Nutrition & Dietary Supplement Conference organized by ABF(The Asia Business Forum) in Singapore, especially regulatory view of point of health functional foods for Korea, Japan, and China. Foods that may have health benefits beyond the traditional nutrients that they contain are often called 'Functional Foods'. The concept of functional foods has become popular in recent years, first in Japan and later in other countries, including the USA. In USA, The functional foods was controlled by ACSH (the American Council on Science and Health). In Korea, 'Functional Foods'. was defined on the 'The Law for the Health Functional Foods'(Law No. 6727 : effective as of $26^{th}$, Aug. 2002). KFDA(Korea Food and Drug Administration) is the only authority body for approval, advertisement and claims for the Health Functional Foods in Korea. In Japan, the Japan Health Food and Nutrition Food Association controls the approval, regulate functional foods' advertisement and claims under the name of FOSHU (Foods for Specified Health Uses). In China, the State Food and Drug Administration(SFDA) is the only authoritative organization for the application, supervision and administration of health related products. Asia, especially Korea, Japan and China, is one of the leader in the vitamins and dietary supplement(VDS) market. Regulatory issues on restrictions are the most important how to tap into the health functional foods market including Korea.

Effects of a functional fatty acid blend on growth performance, intestinal morphology, and serum profiles in weaned piglets

  • Huakai Wang;Yanan Wang;Yu Zhang;Juntao Li;Yihai Mi;Yongqiang Xue;Jiaan Li;Yongxi Ma
    • Animal Bioscience
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    • v.36 no.5
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    • pp.761-767
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    • 2023
  • Objective: The objective of this study was to determine whether dietary supplementation with a functional fatty acid blend (FA) that contains 31.4% butyric acid and 4.99% medium-chain FA improve growth performance, antioxidant capacity, immunity status, and anti-inflammatory ability in weaned piglets. Methods: One hundred and forty-four healthy piglets (Duroc×Landrace×Yorkshire) with an average body weight (BW) of 7.98±3.43 kg were randomly divided into three groups with six replicate pens and eight piglets per pen: Normal control (NC): a corn-soybean basal diet; FA1: a basal diet supplemented with 1,000 mg/kg of a functional FA; FA2: a basal diet supplemented with 2,000 mg/kg of a functional FA. The experiment lasted for 28 d. On d 14 and 28, one piglet in each pen from NC and FA2 groups was randomly selected for antioxidative index and immunoglobulins. On d 28, one piglet in each pen from NC and FA2 groups was randomly selected for intestinal morphology and inflammatory factor. Results: We observed that FA supplementation linearly increased (p<0.05) average daily gain and the final BW. There was higher (p<0.05) catalase on d 14, and immunoglobulin (Ig) A and IgM on d 28 in piglets supplemented with FA2 than in the NC group. Moreover, dietary FA2 reduced (p<0.05) crypt depth of ileum in piglets. The concentrations of tumor necrosis factor-α, interleukin (IL)-1β, IL-8, and IL-10 in jejunum were lower (p<0.05) in the FA2 group compared with the NC group. Conclusion: Therefore, the overall results suggests that the FA may help to improve gut health, antioxidant status, and immune parameters resulting in the improvement of growth performance.

Active Short Circuit Control Method to Reduce Overcurrent and Oscillation Current in PMSM (영구자석 동기모터 진동 및 과전류 저감을 위한 능동단락회로 제어 기법)

  • Choi, Jong-Won;Kim, Yoon-Jae
    • The Transactions of the Korean Institute of Power Electronics
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    • v.27 no.4
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    • pp.339-347
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    • 2022
  • This study proposes the mitigation method for overcurrent and oscillation motor current in an active short-circuit operation. This operation is attracting attention as the safe state of electric vehicle traction inverters. However, the active short-circuit operation generates oscillation and overcurrent of motor currents during a transient state. The proposed method uses two different safe states in PMSM, such as active short circuit and freewheeling. The active short circuit is used for safe state in a steady state. To reduce the overshoot and oscillation, a freewheeling state is injected between active short-circuit operation by comparing the motor phase current with an analytically calculated steady-state motor current. Freewheeling state is only used in a transient state. The performance is demonstrated through simulations and experimental results. The peak current of the motor was reduced from 52 A to 40 A, and oscillation time was reduced.