• Title/Summary/Keyword: Functional Polyurethane

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Development of Functional Uniform for Caregivers (간병인을 위한 기능적 유니폼 개발 -노인의료복지시설 간병인을 대상으로-)

  • Lee, Eun-Young;Choi, Hei-Sun;Kim, Eun-Kyong
    • Journal of the Korean Society of Clothing and Textiles
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    • v.31 no.5 s.164
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    • pp.788-800
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    • 2007
  • The purpose of this study was to develop a caregiver's uniform that is appropriate for nursing and to improve movement adaptability as well as having a pleasing appearance. Based on the results of preliminary study, I investigated the inconvenience and problems with the existing uniforms and made a sample uniform taking into consideration the design, the material, and the pattern. We carried out a sensory assessment and quantitative assessment in order to compare the sample uniform with existing uniforms. Following are the results of this research. The top is a short-sleeved blouse with a round neckline having no collar and with armpit gussets. The armpit gussets are semicircles and the inverted pleats in the back are an improvement designed for activity. The pants are long reaching to the ankles with elastic in the waist so that the waist measurement may be adjusted. The length of the pants can be adjusted with strings and the pants have a funnel-shaped pocket for adjustment of length. We used a mix of polyurethane and polyester for the outer cloth of the uniform in order to improve activity function and used $Coolever^{TM}$, the sanitary textile that absorbs moisture well and dries in a short time, for gussets in the armpits, which is the heavy sweat area. The appearance assessment and movement adaptability assessment were performed with 5 subjects and 9 experts. For the results of the assessment, the sample uniform was appraised to be better than the existing uniforms in every item of an appearance comparison assessment except for the neckline assessment by the experts. As for the assessment of movement appropriateness and wearing assessment, the same subjects were used for analysis. As the results of the assessment, the sample uniform was rated higher than the existing uniforms in movement adaptability and pleasing appearance.

A Study on Improvement of the low temperature flex resistance test method about high waterproof materials (고기능성 투습방수 소재의 저온굴곡 시험방법 개선 연구)

  • Lee, Minhee;Moon, Sunjeong;Ko, Hyeji;Hong, Seongdon
    • Journal of Korean Society for Quality Management
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    • v.46 no.3
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    • pp.425-440
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    • 2018
  • Purpose: This study is aimed at developing of the flex resistance testing process at low temperature with the waterproof fabric to suit the military environment, and is designed to fit for the purpose of the waterproof materials in order to optimize the test method by finding out matters to improve from existing the test method and through previous studies. Methods: The test method, which has been applied to flex resistance of existing water-repellent materials, was improved and consequently, differentiated test results could be obtained according to the test temperature, sample size, and flexing method. Results: The testing of the total of 8 samples revealed that performance of the military requirement could hardly be met just by presenting the materials or 2~3 layers when the quality criteria for high functional water repellent fabrics were applied. PTFE(Polytetrafluoroethylene) is preferred to PU(Polyurethane) to be used in the extremely low-temperature environment, but durability under the low-temperature environment may be varied depending on film thickness or laminating technique even if the materials of waterproof films are identical. Therefore, in addition to the material or texture, the test method capable of reflecting durability under the low-temperature environment shall be suggested, and the newly designed test method proposed in this study was shown to suggest differentiated quality criteria by the material. Conclusion: The water resistance measurement and the test method following flex resistance with expanded range of flex will enable the differentiable test of the samples according to the number of repetition. This study is meaningful in that it suggests a differentiable test method capable of establishing a basis of deciding suitable material when selecting military goods made of water repellent material by properly improving the test method.

Trend on Development of Polymeric Organosilicone Surfactants (고분자 유기실리콘 계면활성제의 개발 동향)

  • Rang, Moon Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.546-567
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    • 2015
  • Silicone-based surfactants consist of a hydrophobic organosilicone group coupled to one or more hydrophilic polar groups, while the hydrophobic groups of hydrocarbon surfactants are hydrocarbons. Silicone surfactants have been widely used in many industrial fields starting from polyurethane foam to construction materials, cosmetics, paints & inks, agrochemicals, etc., because of their low surface tension, lubricity, spreading, water repellency and thermal and chemical stability. A wide range of silicone surfactant structures are required to provide the functional diversity for reflecting the necessities in the various applications. This review covers the basic properties and the synthetic schemes of polydimethylsiloxane and reactive polysiloxanes as hydrophobic siloxane backbones, the main reaction schemes, such as hydrosilylation reaction, for coupling reactive polysiloxanes to hydrophilic groups, and the synthetic schemes of the main polysiloxane surfactants including polyether-, ionic-, carbohydrate-type surfactants.

A Design for Summer Safety Shoes for Agricultural Work Using a Survey

  • Lee, Kyung Suk;Kim, Do Hee;Oh, Young Soon;Oh, Sae Loom;Chae, Hye Seon;Kim, Kyung Ran
    • Journal of the Ergonomics Society of Korea
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    • v.35 no.1
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    • pp.1-10
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    • 2016
  • Objective: This study aimed to find good design for summer functional farm shoes under the agricultural environment and working characteristics, which can help safe farm work and further promote the efficiency of working. Background: Most accidents at farms were overturn accidents caused by slipping or falling, and it was found that the main factors which caused the overturn accidents were inappropriate work shoes for the working conditions. These inappropriate work shoes often cause overturn accidents in the rural areas with steep paths. Method: A survey on work shoes was conducted with 174 farmers, and the outcome of this survey was used to find problems of work shoes and improvement ideas for the design of work shoes which can be used at farms. Results: Regarding the form of farm shoes, the ankle height was set at 6 inches to prevent the bending of the ankle and the inflow of foreign substances. The size and groove of the pattern of the outsole were extended to prevent catching of foreign substances. In the upper part, polyurethane and cordura were used in combination to secure air permeability, which was pointed out as the reason for the discomfort during the work wearing existing work shoes. Conclusion: Since farmers felt discomfort with the shoes which they were currently wearing, this study suggested a design of farm shoes by analyzing the important matters of the work shoes in development in order to improve such discomfort. Application: This study can help develop farm shoes that would practically ease farmers' burden of working at farm worksites and keep them safe.

An Experimental Study on the Thermal Physiological Response in the Pesticide Proof Clothing Textile Materials for a Fruit-grower (과수용 농약방제복 소재 특성에 따른 인체생리반응에 관한 연구)

  • Hwang, Kyoung-Sook;Kim, Kyung-Ran;Lee, Kyung-Suk;Kim, Hyo-Cher;Baek, Yoon-Jeong
    • Journal of the Korean Society of Clothing and Textiles
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    • v.32 no.11
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    • pp.1792-1801
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    • 2008
  • This study was to develope the pesticide-proof clothes(PPC) for fruit-grower which has been well known over applied agricultural chemicals. The ergonomic evaluation of PPC were tested in two ways. Male adults volunteered the tests to evaluate the safety to pesticide in the field and the thermal comforts in the climate-chamber($30^{\circ}C$, 60%R.H.). PPC were made of 4 different fabrics. Two of them were on the market(coated non-woven and coated nylon). Others were water-repellent treatment and coated waterproof film by developed polyester. The field study was conducted for farmers growing apples to evaluate pesticide exposure. In this experiment, we collected data with patch test on the head, chest, back, right upperarm, right forearm, left thigh and left calf. From the results, the developed PPC showed the more excellent comfort than an existing PPC with nylon coated polyurethane. But the developed PPC of water-repellent fabric was penetrated into the PPC. Therefore, we designed the functional pesticide-proof clothes of 2 different developed polyester fabrics(water-repellent treatment in chest, abdomen, the lower of back, waist, and calf; coated waterproof film in head, shoulder, the upper of back, the crotch, hip, upper arm and thigh).

Preserved Superficial Fat Skin Composite Graft for Correction of Burn Scar Contracture of Hand (얕은 지방층을 포함한 피부복합조직이식을 이용한 손화상 반흔구축의 교정)

  • Son, Daegu;Jeong, Hoijoon;Choi, Taehyun;Kim, Junhyung;Han, Kihwan
    • Archives of Plastic Surgery
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    • v.35 no.6
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    • pp.716-722
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    • 2008
  • Purpose: Split or full thickness skin graft is generally used to reconstruct the palmar skin and soft tissue defect after release of burn scar flexion contracture of hand. As a way to overcome and improve aesthetic and functional problems, the authors used the preserved superficial fat skin(PSFS) composite graft for correction of burn scar contracture of hand. Methods: From December of 2001 to July of 2007, thirty patients with burn scar contracture of hand were corrected. The palmar skin and soft tissue defect after release of burn scar contracture was reconstructed with the PSFS composite graft harvested from medial foot or below lateral and medial malleolus, with a preserved superficial fat layer. To promote take of the PSFS composite graft, a foam and polyurethane film dressing was used to maintain the moisture environment and Kirschner wire was inserted for immobilization. Before and after the surgery, a range of motion was measured by graduator. Using a chromameter, skin color difference between the PSFS composite graft and surrounding normal skin was measured and compared with full thickness skin graft from groin. Results: In all cases, the PSFS composite graft was well taken without necrosis, although the graft was as big as $330mm^2$(mean $150mm^2$). Contracture of hand was completely corrected without recurrence. The PSFS composite graft showed more correlations and harmonies with surrounding normal skin and less pigmentation than full thickness skin graft. Donor site scar was also obscure. Conclusion: The PSFS composite graft should be considered as a useful option for correction of burn scar flexion contracture of hand.

Improvement of adhesion of Polyester Fabric and Knit by Corona Treatment (코로나 처리를 이용한 폴리에스테르 편·직물의 접착력 향상)

  • Lee, Eon Pil;Yoon, Rae Won;Lee, Jae Ho
    • Journal of Adhesion and Interface
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    • v.8 no.3
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    • pp.16-23
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    • 2007
  • Polyester fabrics and knits were corona treated with different current intensity (5, 10, 15, 20 A) and feeding speed (5, 10, 15 m/min). We confirmed the surface change of polyester fabrics and knits using scanning electron microscopy (SEM) and X-ray photoelectron spectrometer (XPS). And the change of physical properties through measuring the tensile strength, dry and wet bonding strength. Thermosetting reactive polyurethane hot melt adhesive was used in the adhesion of polyester fabrics and knits. Functional groups were introduced on PET fabrics and knits surface by treating the PET fabrics and knits in air atmosphere with corona discharge, and take placed unevenness, the result adhesion was improved. When consider both dry and wet bonding strength, we think that appropriate conditions in the PET fabrics corona treatment are feeding speed 10 m/min, current intensity 15 A and appropriate conditions in the mesh type PET knits corona treatment are feeding speed 10 m/min, current intensity above 10 A.

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Value-added Utilization of Lignin Residue from Pretreatment Process of Lignocellulosic Biomass (목질계 바이오매스 전처리 공정에서 발생하는 리그닌 부산물 활용 기술 개발 동향)

  • Jung, Jae Yeong;Lee, Yumi;Lee, Eun Yeol
    • Applied Chemistry for Engineering
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    • v.27 no.2
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    • pp.135-144
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    • 2016
  • Due to the high price volatility and environmental concern of petroleum, biofuels such as bioethanol produced from lignocellulosic biomass have attracted much attention. It is also expected that the amount of lignin residue generated from pretreatment of lignocellulosic biomass will increase as the volume of cellulosic bioethanol increases. Lignin is a natural aromatic polymer and has very complex chemical structures with chemical functional groups. Chemical modification of lignin such as oxypropylation and epoxidation has also been applied to the production of value-added bioplastics such as polyurethane and polyester with enhanced thermal and mechanical properties. In addition, lignin can be used for carbon fiber production in automobile industries. This review highlights recent progresses in utilizations and chemical modifications of lignin for the production of bioplastics, resins, and carbon fiber.

Synthesis of Silane Group Modified Polyurethane Acrylate and Analysis of Its UV-curing Property (실란기가 도입된 폴리우레탄 아크릴레이트 합성 및 자외선 경화 특성 분석)

  • Kim, Jung Soo
    • Journal of Adhesion and Interface
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    • v.22 no.3
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    • pp.98-105
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    • 2021
  • In this study, we prepared a silver nanoparticle transferable adhesive composition with transparency and adhesive properties using UV-curable urethane acrylate containing silane groups. The urethane-based adhesive composition was applied between the Ag/PET film in which silver nanoparticles were patterned on PET and the PC film to be transferred. Immediately after UV-curing with UV, PET was removed to complete the manufacture of Ag/PC film. UV-curable urethane acrylate containing silane groups was synthesized using polycaprolactone diol (PCL), isophrone diisocyanate (IPDI), 2-hydroxyethyl methacrylate (HEMA), and (3-aminopropyl) triethoxysilane (APTES). The silane group of APTES can improve interfacial adhesion by reacting with the specially treated silver nanoparticle surface of the Ag/PET film. In addition, we improved the adhesion between silver nanoparticle and PC film by mixing UV-curable urethane acrylate containing a silane group and a functional acrylic diluent used as a diluent. We analyzed the synthesis process of urethane acrylate using FT-IR, and compared the adhesive properties, optical properties, and transfer properties according to the molar ratio of APTES and the acrylic diluent composition. As a result, the best transfer properties were confirmed in the adhesive composition prepared under the conditions of PUA2S1_0.5.

Trend on Development of Low Molecular Weight Organosilicone Surfactants (Part 1) (저분자 유기실리콘 계면활성제의 개발 동향 (제1보))

  • Rang, Moon Jeong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.1
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    • pp.66-82
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    • 2017
  • Organosilicone-based surfactants consist of hydrophobic organosilicone groups coupled to hydrophilic polar groups. Organosilicone surfactants have been widely used in many industrial fields starting from polyurethane foam to construction materials, cosmetics, paints & inks, agrochemicals, etc., because of their low surface tension, lubricity, spreading, water repellency and thermal and chemical stability, resulted from the unique properties of organosilicone. Especially, trisiloxane surfactants, having low molecular weight organosilicone as hydrophobe, exhibit low surface tension and excellent wettability and spreadability, leading to their applications as super wetter/super spreader, but have the disadvantage of vulnerability to hydrolysis. A variety of trisiloxane surfactant structures are required to provide the functional improvement and the defect resolution for reflecting the necessities in the various applications. This review covers the synthetic schemes of reactive trisiloxanes as hydrophobic siloxane backbones, the main reaction schemes, such as hydrosilylation reaction, for coupling reactive trisiloxanes to hydrophilic groups, and the synthetic schemes of the main trisiloxane surfactants including polyether-, carbohydrate-, gemini-, bolaform-, double trisiloxane-type surfactants.