• 제목/요약/키워드: Functional Polymer

검색결과 782건 처리시간 0.027초

4개의 폴리카프로락톤 가지 코어를 가지는 스타형 폴리카프로락톤의 합성 및 분석 (Synthesis and characterization of Star Shape Polycaprolactone containing 4-Arm Polycaprolactone Core)

  • An, Sung-Guk;Cho, Chang-Gi
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2002년도 봄 학술발표회 논문집
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    • pp.199-202
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    • 2002
  • The synthesis of materials with controlled composition and architectures continues to be a focus of considerable current research. Dendritic multiarm polymers such as dendrimer, hyperbranched polymer, and star polymers are three dimensional macromolecules, in which a large number of linear arms of similar molecular weight and narrow molecular weight distribution emanate from a central core. (omitted)

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Development of New Functional Materials based on Polyamides

  • Maeda, Shuichi
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.146-147
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    • 2006
  • Polyamides have been widely used in the various industrial fields on account of their excellent properties. Especially the largest market with more than 40% of the total demand is in automobiles and transportation equipment. In this lecture, we would like to introduce several new functional materials (new polyamide elastomer UBESTA XPA, UBESTA gas pipe system and new polyamide terpolymer TERPALEX) based on polyamides developed by UBE. Here UBESTA is the trademark for UBE's polyamide12.

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관능성 단량체로서 Maleic Anhydride를 이용한 Polyolefin의 개질 및 물성 (Modification and Properties of Polyolefin with Maleic Anhydride as a Functional Monomer)

  • 모종헌;이재석;최임철;이원기;박상보;민성기;박찬영
    • Elastomers and Composites
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    • 제47권2호
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    • pp.162-167
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    • 2012
  • 거대분자의 표면개질은 고분자재료의 물성을 향상시키기 위한 점진적이고 바람직한 방안을 제공하며 고분자의 주요 물성을 손상시키지 않고 고분자 표면의 전도도, 젖음성, 안정성, 접착 및 항박테리아성 등을 개선시킨다. PE 또는 PP 등의 polyolefin을 관능성 단량체로서 MAH와 용액상에서 그래프트시켰다. FTIR측정을 통하여 그래프팅이 일어났음을 확인하였다. 그래프팅율은 화학적정에 의하여 결정하였다. MAH량이 많아질수록 접촉각은 낮은 값을 얻었다. 또한 MAH량이 증가함에 따라 polyolefin-g-MAH의 융점($T_m$)은 감소하는 한편 분해온도($T_d$)는 증가하는 경향을 보였다.

PTC Behavior of Polymer Composites Containing Ionomers upon Electron Beam Irradiation

  • Kim, Jong-Hawk;Cho, Hyun-Nam;Kim, Seong-Hun;Kim, Jun-Young
    • Macromolecular Research
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    • 제12권1호
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    • pp.53-62
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    • 2004
  • We have prepared polymer composites of low-density polyethylene (LDPE) and ionomers (Surlyn 8940) containing polar segments and metal ions by melt blending with carbon black (CB) as a conductive filler. The resistivity and positive temperature coefficient (PTC) of the ionomer/LDPE/CB composites were investigated with respect to the CB content. The ionomer content has an effect on the resistivity and percolation threshold of the polymer composites; the percolation curve exhibits a plateau at low CB content. The PTC intensity of the crosslinked ionomer/LDPE/CB composite decreased slightly at low ionomer content, and increased significantly above a critical concentration of the ionomer. Irradiation-induced crosslinking could increase the PTC intensity and decrease the NTC effect of the polymer composites. The minimum switching current (Ι$\sub$trip/) of the polymer composites decreased with temperature; the ratio of Ι$\sub$trip/ for the ionomer/LDPE/CB composite decreased to a greater extent than that of the LDPE/CB composite. The average temperature coefficient of resistance (${\alpha}$$\sub$T/) for the polymer composites increased in the low-temperature region.

RF sputter를 이용한 실리카 증착 고 내구성 반사 방지막 제조 (High Durable Anti-Reflective Polymer with Silica Nanoparticle Array Fabricated by RF Magnetron Sputter)

  • 전성권;정은욱;나종주;권정대
    • 한국표면공학회지
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    • 제52권2호
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    • pp.84-89
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    • 2019
  • We fabricated durable anti-reflective(AR) layer with silica globular coating on polymer by two steps. Firstly, nano-protrusions of polymer were formed by plasma etching known as R.I.E(reactive ion etching) process. Secondly, silica globular coating was deposited on polymer nano-protrusions for mechanically protective and optically enhancing AR layers by RF magnetron sputter. And then durable antireflective polymers were synthesized adjusting plasma power and time, working pressures of RIE and RF sputtering processes. Consequently, we acquired the average transmission (94.10%) in the visible spectral range 400-800 nm and the durability of AR layer was verified to sustain its transmission until 5,000 numbers by rubber test at a load of 500 gf.

Mechanical and Thermal Properties of Liquefied Wood Polymer Composites (LWPC)

  • Hyun, Doh Geum;Kang, In Aeh;Lee, Sun Young;Kong, Young To
    • Journal of the Korean Wood Science and Technology
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    • 제32권6호
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    • pp.67-73
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    • 2004
  • The influence of liquefied wood (LW) on the mechanical and thermal properties of liquefied wood-polymer composites (LWPC) was investigated in this study. The thermal behaviors of LWPC were characterized by means of thermogravimetric (TGA) and differential scanning calorimetric (DSC) analyses. LW showed significant effects on the mechanical strength properties. The increase of flexural MOE and Young's modulus was related to the increase of stiffness of LWPC. The effect of LW was also significant on the flexural and tensile MOR. The impact strength decreased with the increase of LW application level. With the increased stress concentration by the poor bonding between LW and polymer, the impact strength of LWPC decreased, compared with that of high-density polyethylene (HDPE). The thermal stability of LWPC decreased with the increase of LW content up to 40%. The melting temperature of HDPE decreased with the increase of LW loading level. Enthalpy of HDPE also decreased with the addition of LW. This study proves the thermal stability necessary for the consolidation of composition materials.

Synthesis of Various Functional Block Copolymers via Controlled Ring Opening Metathesis Polymerization and the Subsequent Chemical Modifications

  • Kang, Min-Hyuk;Moon, Bong-Jin
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.200-200
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    • 2006
  • Several polynorbornene or poly(norbornene-7-oxide) based functional block copolymers were synthesized by ring opening metathesis polymerization (ROMP) with good molecular weight and polydispersity control. Some representative functional groups in these polymers are a nitrobenzoyl group or ferrocene. These polymers were subjected to various chemical modification reactions to give other block copolymers that contain novel functionality such as amine, diazonium salt, and diazo groups. The resulting polymers were characterized by various techniques such as GPC, NMR, UV-VIS, AFM, and cyclovotammography (CV).

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