• Korean Chemical Engineering Research
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• v.49 no.3
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• pp.330-337
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• 2011

In this research, the preparation processes for making a series of $\omega$-mercapto alkylamine 1 and $\omega$-mercapto alkanoic acid 2 useful for studying of the self-assembled monolayer(SAM) are described. The preparation methods of the first goal materials, $\omega$-mercapto alkylamines 1 were carried out as follows: First, $\omega$-phthalimide alkanol 3 was synthesized from commercially available potassium phthalimide derivatives and $\omega$-bromoalkanol in DMF at $80{^{\circ}C}$ via substitution reaction. After refluxing $\omega$-phthalimide alkanol 3 with hydrazine hydrate in ethanol followed by treating with c-HCl, $\omega$-aminoalkanol 4 was obtained in 76-98% yield, accompanied with side-product 5. Bromination of hydroxyl moiety of $\omega$-aminoalkanol 4 using aqueous hydrobromic acid furnished $\omega$-bromoamine 6 in 34-97% yields. Substitution reaction 6 with thiourea in 95% ethanol gave $\omega$-aminoalkanthiuronium 7, which was treated with aqueous strong base and aqueous strong sulfuric acid gave desired products, $\omega$-mercapto alkylamines 1 through overall 5 steps. The second target material, $\omega$-mercapto alkanoic acid 2 was prepared via 2 steps. $\omega$-bromo alkanoic acid was reacted with thiourea to give $\omega$-thiourea alkanoic acid 7 in 69-85%, which was treated with aqueous strong base and strong acid to furnish $\omega$-mercapto alkanoic acid 2 in 50-98%. The fabricated long-chain alkylthiol(LCAT) can be used as linkers to immobilize protein, enzyme and various kinds of biomolecules on the surface of metallic materials(Au, Pt, Ti) by SAM, and can be useful chemical tools for the application study on the surface modification of metallic materials.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.18 no.2_spc
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• pp.291-303
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• 2020

The Kori-Unit 1 nuclear power plant, which is scheduled to be decommissioned after permanent shutdown, is expected to generate large amounts of various types of radioactive waste during the decommissioning process. Among these, nuclear reactors and internal structures have high levels of radioactivity and the dismantled structure must have the proper size and weight on the primary side. During decommissioning, it is important to prepare an appropriate and efficient disposal method through analysis of the disposal status and the legal restrictions on wastes generated from the reactors and internal structures. Nuclear reactors and internal structures generate radioactive wastes of various levels, such as medium, very low, and clearance. A radiation evaluation indicates that wastes in the clearance level are generated in the reactor head and upper head insulation. In this study, a clearance waste safety evaluation was conducted using the RESRAD-RECYCLE code, which is a safety evaluation code, based on the activation evaluation results for the clearance level wastes. The clearance scenario for the target radioactive waste was selected and the maximum individual and collective exposure doses at the time of clearance were calculated to determine whether the clearance criteria limit prescribed by the Nuclear Safety Act was satisfied. The evaluation results indicated that the doses were significantly low, and the clearance criteria were satisfied. Based on the safety assessment results, an appropriate metal recycle and disposal method were suggested for clearance, which are the subject of the deregulation of internal structures of nuclear power plant.

• Journal of the Korean Society of Marine Environment & Safety
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• v.26 no.5
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• pp.542-550
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• 2020

The use of high-strength aluminum alloys for ships and of shore structures has many benefits compared to carbon steels. Recently, high-strength aluminum alloys have been widely used in onshore and of shore industries, and they are widely used for the side shell structures of special-purpose ships. Their use in box girders of bridge structures and in the topside of fixed platforms is also becoming more widespread. Use of aluminum material can reduce fuel consumption by reducing the weight of the composite material through a weight composition ratio of 1/3 compared to carbon steel. The characteristics of the stress strain relationship of an aluminum structure are quite different from those of a steel structure, because of the influence of the welding[process heat affected zone (HAZ). The HAZ of aluminum is much wider than that of steel owing to its higher heat conductivity. In this study, by considering the HAZ generated by metal insert gas (MIG) welding, the buckling and final strength characteristics of an aluminum reinforcing plate against longitudinal compression loads were analyzed. MIG welding reduces both the buckling and ultimate strength, and the energy dissipation rate after initial yielding is high in the range of the HAZ being 15 mm, and then the difference is small when HAZ being 25 mm or more. Therefore, it is important to review and analyze the influence of the HAZ to estimate the structural behavior of the stiffened plate to which the aluminum alloy material is applied.

• Membrane Journal
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• v.18 no.4
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• pp.261-267
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• 2008

A graft copolymer consisting of poly(vinyl chloride) (PVC) backbone and poly(hydroxyethyl acrylate) (PHEA) side chains was synthesized via atom transfer radical polymerization (ATRP). Direct initiation of the secondary chlorines of PVC facilitates grafting of hydrophilic PHEA monomer. This graft copolymer, i.e. PVC-g-PHEA was cross-linked with sulfosuccinic acid (SA) via the esterification reaction between -OH of the graft copolymer and -COOH of SA, as confirmed by FT-IR spectroscopy. Ion exchange capacity (IEC) continuously increased to 0.87meq/g with increasing concentrations of SA, due to the increasing portion of charged groups in the membrane. However, the water uptake increased up to 20.0wt% of SA concentration above which it decreased monotonically. The membrane also exhibited a maximum proton conductivity of 0.025 S/cm at 20.0 wt% of SA concentration, which is presumably due to competitive effect between the increase of ionic sites and the crosslinking reaction.

• Journal of Advanced Marine Engineering and Technology
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• v.41 no.4
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• pp.302-309
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• 2017

If a hydrogen explosion occurs in a containment building, its multiplex defense wall may be destroyed and a large amount of radioactive material may be released. The hydrogen occurred interacting with melting fuel rods must be effectively controlled and removed. however, the countermeasures for reducing explosion risk are difficult to carry out, due owing to the various variety of accident scenarios causes and the irregularity of hydrogen distribution and behavior. In this study, We examine the guide structures while considering the ambient flows, in order to improve the efficiency of PAR the widely used Passive Autocatalytic Recombiner(PAR). We simulate the fluid behavior and the hydrogen reduction rate were simulated when a guide is attached to the two-step catalyst PAR. For an upward flow, the consisting of a height of 150mm, a gap of 0mm, and a performs $60^{\circ}$ showed the best. In contrast, for a sideways flow, a consisting of the height of 150mm, a gap of 100mm, and a performs $60^{\circ}$ showed the best in the case of side ward flow. for a downward flow, a consisting of the height of 50mm and a directly attached guide produce the best in the case of down ward flow results.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.4
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• pp.263-273
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• 2016

The effect of recirculated exhaust gas on performance and exhaust emissions with FGR rate are investigated by using a natural circulation, pressurized draft and water tube boiler with FGR system operating at several boiler loads and over fire air damper openings. The purpose of this study is to apply the FGR system to a power plant boiler for reducing $NO_x$ emissions. To activate the combustion, the OFA with 0 to 20% is supplied into the flame. When the suction damper of two stage combustion system installed in the upper side of wind box is opened by handling the lever between $0^{\circ}$ and $90^{\circ}$, also, the combustion air supplied to burner is changed. It is found that the fuel consumption rate per evaporation rate did not show an obvious tendency to increase or decrease with rising the FGR rate, and $NO_x$ emissions at the same OFA damper opening are decreased, as FGR rates are elevated and boiler loads are dropped. While a trace amount of soot is emitted without regard to the operation conditions of boiler load, OFA damper opening and FGR rate, because soot emissions are eliminated by the electrostatic precipitator with a collecting efficiency of 86.7%.

• Proceedings of the Materials Research Society of Korea Conference
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• 2010.05a
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• pp.3.1-3.1
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• 2010

Water splitting reaction using photocatalysts is of great interest in the utilization of solar energy [1]. In the present work, visible light-responsive $TiO_2$ thin films (Vis-$TiO_2$) were prepared by a radio frequency magnetron sputtering (RF-MS) deposition method and applied for the separate evolution of $H_2$ and $O_2$ from water as well as the photofuel cell. Special attentions will be focused on the effect of HF treatment of Vis-$TiO_2$ thin films on their photocatalytic activities. Vis-$TiO_2$ thin films were prepared by an RF-MS method using a calcined $TiO_2$ plate and Ar as the sputtering gas. The Vis-$TiO_2$ thin films were then deposited on the Ti foil substrate with the substrate temperature at 873 K (Vis-$TiO_2$/Ti). Vis-$TiO_2$/Ti thin films were immersed in a 0.045 vol% HF solution at room temperature. The effect of HF treatments on the activity of Vis-$TiO_2$/Ti thin films for the photocatalytic water splitting reaction have been investigated. Vis-$TiO_2$/Ti thin films treated with HF solution (HF-Vis-$TiO_2$/Ti) exhibited remarkable enhancement in the photocatalytic activity for $H_2$ evolution from a methanol aqueous solution as well as in the photoelectrochemical performance under visible light irradiation as compared with the untreated Vis-$TiO_2$/Ti thin films. Moreover, Pt-loaded HF-Vis-$TiO_2$/Ti thin films act as efficient and stable photocatalysts for the separate evolution of $H_2$ and $O_2$ from water under visible light irradiation in the presence of chemical bias. Thus, HF treatment was found to be an effective way to improve the photocatalytic activity of Vis-$TiO_2$/Ti thin films. Furthermore, unique separate type photofuel cell was fabricated using a Vis-$TiO_2$ thin film as an electrode, which can generate electrical power under solar light irradiation by using various kinds of biomass derivatives as fuel. It was found that the introduction of an iodine ($I^-/{I_3}^-$) redox solution at the cathode side enables the development of a highly efficient photofuel cell which can utilize a cost-efficient carbon electrode as an alternative to the Pt cathode.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.6
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• pp.633-648
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• 2010

The study was performed to elucidate the characteristics of VOCs at distinct monitoring sites in urban atmosphere; one is at a roadside in downtown inland city of Jeonju, and the other is at an industrial site in Gunsan near coastal area. The ambient samples were collected for 24 hours in two-bed adsorbent tubes by using MTS-32 sequential tube sampler equipped with Flex air pump every 16 days in a roadside and a industrial complex from February to November in 2009. VOCs were determined by thermal desorption coupled with GC/MSD. Major individual VOCs in roadside samples were shown as following order in magnitude: toluene>m,p-xylene>ethyl benzene>decanal; and those in the industrial complex samples were as follows: toluene>ethanol>ethyl acetate>decanal>m,pxylene. High benzene concentration in the roadside was more frequently occurred than in the industrial complex. However ambient level of toluene in the industrial complex was higher than that in the road side. Results from roadside sample analysis showed that nonane and 1,2,4-trimethylbenzene were very frequently observed with higher concentrations than those in the industrial complex. It seems that nonane and 1,2,4-trimethylbenzene could be the source characteristics for the roadside air. From the diurnal variation, it was found that concentrations of benzene, ethylbenzene, xylene, nonane and 1,2,4-trimethylbenznene in the roadside were higher during rush hours; but those in the industrial complex were higher from 10 to 16 LST when the industrial activities were animated. On weekly base, the concentration of benzene, toluene, ethylbenzene and m,p-xylene in the roadside were higher specifically on Wednesday, but those in the industrial complex were higher on Sunday. It was found that the general trends of VOCs levels at both sites significantly influence on seasonal changes. The results of factor analysis showed that the VOCs in the roadside were mainly affected by the emission of vehicles and the evaporation of diesel fuel, meanwhile those in the industrial complex were influenced by the evaporation of solvents and vehicular emission.

• Fire Science and Engineering
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• v.24 no.4
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• pp.62-68
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• 2010

The present study purposed to develop the water mist package system for the cultural properties fire prevention and fire suppression system through analyzing fire protection system and cultural property's characteristic, and to suggest directions for the development of cultural property fire prevention system in the future. Maximum safety with minimum damage has issued a main objective in fire protection of the cultural property in Korea. Two types of the water mist nozzles having a low pressure had been developed by KEI. The one is for inside using in wooden cultural properties, the flow rate is 30~35 l/min and the discharging pressure is 13~14 bar. The other one is for out-side of wooden properties, the flow rate is 25~30 l/min and the discharging pressure is 14~15 bar. To evaluate the nozzles performance test, we made the fire scenario and full-scale model of wooden cultural properties for fire test. The size of full-scale model was 4.9 m length, 4 m wide, 6.6 m height, all was made by wooden. This real fire test results showed that the low pressure water mist nozzles having a $200{\mu}m$ dour size were very effectively fire extinguishing and suppression on wooden cultural properties fire. Even though the oil fuel fire was not extinguished, the fire suppression effects for the during mobilization of fire brigade was enough.

• International Journal of Automotive Technology
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• v.6 no.3
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• pp.221-227
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• 2005

Aim of this study is to investigate an aerodynamic effect of a drag-reducing device on a heavy-duty truck. The vehicle experiences two different kinds of aerodynamic forces such as drag and uplifting force (or downward force) as it is traveling straight forward at constant speed. The drag force on a vehicle may cause an increase of the rate of fuel consumption and driving instability. The rolling resistance of the vehicle may be increased as result of the negative uplifting or downward force on the vehicle. A device named roof-fairing system has been applied to examine the reduction of aerodynamic drag force on a heavy-duty truck. As for a engineering design information, the drag-reducing system should be studied theoretically and experimentally for the best efficiency of the device. Four different types of roof-fairing model were considered in this study to investigate the aerodynamic effect on a model truck. The drag and downward force generated by vehicle has been obtained from numerical calculation conducted in this study. The forces produced on four fairing models considered in this study has been compared each other to evaluate the best fairing model in terms of aerodynamic performance. The result shows that the roof-fairing mounted truck has bigger negative uplifting or downward force than that of non-mounted truck in all speed ranges, and drag force on roof-fairing mounted truck has smaller than that of non-mounted truck. The drag coefficient $(C_D)$ of the roof-fairing mounted truck (Model-3) is reduced up to $41.3\%$ than that of non-mounted trucks (Model-1). A downward force generated by a roof-fairing mounted on a truck is linearly proportional to the rolling resistance force. Therefore, the negative lifting force on a heavy-duty truck is another important factor in aerodynamic design parameter and should be considered in the design of a drag-reducing device of a tractor-trailer. According to the numerical result obtained from present study, the drag force produced by the model-3 has the smallest of all in all speed ranges and has reasonable downward force. The smaller drag force on model-3 with 2/3h in height may results of smallest thickness of boundary layer generated on the topside of the container and the lowest intensity of turbulent kinetic energy occurs at the rear side of the container.