• 제목/요약/키워드: Fuel cell power generation

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100 kW급 용융탄산염 연료전지 시스템 개발 III (시스템 제어 및 운전모드) (System Development of a 100 kW Molten Carbonate Fuel Cell III (System Control and Operation Mode))

  • 임희천;안교상;서혜경;엄영창
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 하계학술대회 논문집 B
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    • pp.1350-1352
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    • 2003
  • For developing a 100 kW MCFC power generation system, Several design parameters for a fuel cell stack and system analysis results by Cycle Tempo, a processing computer soft ware, were described. Approximately two substacks with 90 cells are required to generate 100 kW at a current density of $125\;mA/cm^2$ with $6000\;cm^2$ of cells. An overall heat balance was calculated to predict exit temperature. The 100 kW power is expected only under pressurized operation condition at 3 atm. Recycle of cathode gas by more than 50% is recommended to run the stack at $125\;mA/cm^2$ and 3 atm. Manifolds should be designed based on gas flow rates for the suggested operating condition. The fuel cell power generation system was designed conceptually with several choices of utilization of anode exhaust gas. To operate and evaluate the MCFC system, control and measurement system and operation mode are designed before 100 MCFC system construction. In system control schematics, OS, PLC and MMI were consisted and have roles for MCFC system control. For operation of 100 kW MCFC system, NS, PS PR mode were considerated step by step and simulated.

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인산형 연료전지 발전 기술 (Assessment of Phosphoric Acid Fuel Cell Technology)

  • 고영태;이진홍
    • 에너지공학
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    • 제2권1호
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    • pp.16-21
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    • 1993
  • 연료전지 발전기술은 에너지 절약 및 환경보호 측면에서의 우수한 특성으로 인해 새로운 발전기술로서 평가되고 있다. 여러가지 연료전지 기술중 인산형 연료전지는 기술적으로 가장 성숙되어 있는 상태이며, 상용화를 눈앞에 두고 있다. 본 고에서는 인산형 연료전지에 대한 최근의 기술동향 및 상용화 노력을 소개하고자 한다. 미국과 일본의 개발노력 및 기술상태를 비교 분석하였으며, 향후 기술 개발 방향 등에 대해서도 언급하고자 한다.

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3[kW]급 연료전지용 전력변환장치의 개발 (Development of 3.0[kW]class Fuel Cell Power Conversion System)

  • 서기영
    • 조명전기설비학회논문지
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    • 제21권2호
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    • pp.54-63
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    • 2007
  • 최근 저전압 대전류 출력 특성을 갖는 연료전지를 위한 새로운 발전시스템으로 주목받고 있다. 연료전지 발전시스템에서는 DC-DC 승압용 컨버터와 DC-AC 인버터가 필요하다. 그러므로 본 논문에서는 연료전지의 전압을 $380[V_{DC}]$로 승압하기 위한 절연형 DC-DC 컨버터와 단상 $220[V_{AC}]$로 변환하기 위한 LC필터를 가진 PWM 인버터로 구성된 전력변환장치를 제안하였다. 특히 제안한 고주파 절연형 ZVZCS PWM DC-DC 컨버터는 환류 다이오드를 포함한 탭부 인덕터 필터를 이용하여 순환 전류를 저감시켰으며, 스위치 및 변압기의 턴-온, 턴-오프시에 오버슈트 전압이나 과도현상이 발생하지 않는다. 그리고 넓은 출력 전압 조정에도 효율을 $93{\sim}97[%]$정도 얻을 수 있으며, 출력 부하전류의 변화에 대해 거의 일정한 출력 전압 특성을 가졌다.

다상부스트를 적용한 연료전지 발전시스템 (A Fuel Cell Generation System with Interleaved boost converter)

  • 유병훈;이태원;장수진;이병국;원충연
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2006년도 전력전자학술대회 논문집
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    • pp.19-21
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    • 2006
  • In contrast with DC source, Fell cell has non linear characteristics that has lange voltage fluctuation due to load variation, and slow dynamic characteristics. when the loads are increase, the ripples of input and output voltage, also power densities, of inductor, capacitor, and switching devices, are bulky. This paper presents Interleaved boost converter using Fuel cell stacks, proposed converter has merits to promote power densities without increasing loss. Because each converter has same switching frequency and constant phase difference. In this paper, Interleaved boost converter was design for 1[kW], it's validity was proved by simulation and experiments.

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미생물 연료전지에서 Fe[III] 환원 미생물 Geobacter sulfurreducens를 이용한 전기 생산 (Electricity Production from Fe[III]-reducing Bacterium Geobacter sulfurreducens in Microbial Fuel Cell)

  • 이유진;오유관;김미선
    • 한국수소및신에너지학회논문집
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    • 제19권6호
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    • pp.498-504
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    • 2008
  • Metal-reducing bacterium, Geobacter sulfurreducens is available for mediator-less microbial fuel cell (MFC) because it has biological nanowires(pili) which transfer electrons to outside the cell. In this study, in the anode chamber of the MFC system using G. sulfurreducens, the concentrations of NaCl, sodium phosphate and sodium bicarbonate as electrolytes were mainly optimized for the generation of electricity from acetate. 0.4%(w/v) NaClO and 0.5M $H_2SO_4$ could be utilized for the sterilization of acrylic plates and proton exchange membrane (major construction materials of the MFC reactor), respectively. When NaCl concentration in anode phosphate buffer increased from 5 to 50 mM, power density increased from 6 to $20\;mW/m^2$. However, with increasing sodium phosphate buffer concentration from 5 to 50 mM, power density significantly decreased from 18 to $1\;mW/m^2$. Twenty-four mM sodium bicarbonate did not affect electricity generation as well as pH under 50 mM phosphate buffer condition. Optimized anode chamber of MFC using G. sulfurreducens generated relatively high power density ($20\;mW/m^2$) with the maximum coulombic efficiency (41.3%).

폐수처리를 위한 미생물연료전지의 전기생산 특성 (Characteristics of Electricity Generation by Microbial Fuel Cell for Wastewater Treatment)

  • 김선일;이성욱;김경량;이재욱;노성희
    • 공업화학
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    • 제20권2호
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    • pp.213-217
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    • 2009
  • 폐수처리와 동시에 전기를 생산할 수 있는 새로운 대체 에너지 기술로 주목받고 있는 미생물 연료전지(microbial fuel cell, MFC)는 혐기성 조건의 산화전극(anode)에서 미생물에 의한 촉매작용을 통해 유기물질을 분해하면서 화학에너지를 전기에너지로 전환시키는 장치이다. 본 연구에서는 MFC의 성능을 파악하기 위하여 도시하수를 사용하여 폐수처리 효율과 전기생산 특성을 평가하였다. 도시하수에 탄소원으로서 acetate를 주입하였을 때 COD 제거율은 75.7%에서 88.2%로 증가하였으며 전압은 0.22 V에서 0.4 V까지 급격하게 상승하였다. 다양한 외부저항 하에서 전기생산에 미치는 산화전극과 환원전극(cathode) 사이의 전극 거리에 대한 영향 및 산화전극의 표면적에 대한 영향을 조사하였다. 최고 전력밀도는 $610mW/m^2$이었으며, 전극간 거리가 가깝고 산화전극의 표면적이 작을수록 전기발생에 효과적임을 알 수 있었다.

Effects of electron donors and acceptors in generating bioelectrical energy using microbial fuel cells

  • Gurung, Anup;Oh, Sang-Eun
    • 한국환경농학회지
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    • 제31권1호
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    • pp.24-29
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    • 2012
  • BACKGROUND: In recent years, microbial fuel cells (MFCs) have emerged as a promising technology for recovering renewable energy from waste biomass, especially wastewater. In this study, the possibility of bioelectricity generation in two chambered mediator-less microbial fuel cells (MFCs) was successfully demonstrated using fermentable and non-fermentable substrates. METHODS AND RESULTS: Two different electron acceptors have been tested in the cathode chamber for the effects of reducing agent on the power generation in MFCs. The average voltages of $0.26{\pm}0.014$ V and $0.36{\pm}0.02$ V were achieved with acetate using oxygen and potassium ferricyanide as reducing agent, respectively. Similarly, with glucose the average voltages of $0.256{\pm}0.05$ V and $0.340{\pm}0.04$ V were obtained using oxygen and ferricyanide, respectively. Using potassium ferricyanide as the reducing agent, the power output increases by 39 and 43% with acetate and glucose, respectively, as compared to the dissolved oxygen. Slightly higher coulombic efficiency (CE%) was obtained in acetate as compared to MFCs operated with glucose. The maximum power densities of 124 mW/$m^2$ and 204 mW/$m^2$ were obtained using dissolved oxygen and $K_3Fe(CN)_6$, respectively. CONCLUSION(s): This study demonstrates that power generation from the MFCs can be influenced significantly by the different types of catholyte. Relatively higher CE was obtained with $K_3Fe(CN)_6$. Thus, application of $K_3Fe(CN)_6$ as the catholyte can be vital for scaling uppower generation from the MFCs forreal time applications.

평판형 고체전해질 연료전지의 운전특성평가 (Evaluation of generation characteristics for planar SOFC)

  • 김귀열;엄승욱;문성인;윤문수;박필양;임희천;이창우
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1995년도 하계학술대회 논문집 C
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    • pp.1215-1216
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    • 1995
  • Planar Solid Oxide fuel cell may have some advantages, particularly in their potential for allowing a higher power density, and simpler, less costly methods of fabrication. This study has examined generation characteristics of unit cell for planar Solid Oxide fuel cell.

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