• Title/Summary/Keyword: Fuel additive

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Effect of Process Parameters and Kraft Lignin Additive on The Mechanical Properties of Miscanthus Pellets

  • Min, Chang Ha;Um, Byung Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.6
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    • pp.703-719
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    • 2017
  • Miscanthus had a higher lignin content (19.5 wt%) and carbohydrate (67.6 wt%) than other herbaceous crops, resulting in higher pellet strength and positive effect on combustion. However, miscanthus also contains a high amount of hydrophobic waxes on its outer surface, cuticula, which limits the pellet quality. The glass transition of lignin and cuticula were related to forming inter-particle bonding, which determined mechanical properties of pellet. To determine the effects of surface waxes, both on the pelletizing process and the pellet strength were compared with raw and extracted samples through solvent extraction. In addition, to clarify the relationship between pellet process parameters and bonding mechanisms, the particle size and temperature are varied while maintaining the moisture content of the materials and the die pressure at constant values. Furthermore, kraft lignin was employed to determine the effect of kraft lignin as an additive in the pellets. As results, the removal of cuticula through ethanol extractions improved the mechanical properties of the pellet by the formation of strong inter-particle interactions. Interestingly, the presence of lignin in miscanthus improves its mechanical properties and decreases friction against the inner die at temperatures above the glass transition temperature ($T_g$) of lignin. Consequently, it could found that the use of kraft lignin as an additive in pellet reduced friction in the inner die upon reaching its glass transition temperature.

Multi-step Metals Additive Manufacturing Technologies

  • Oh, Ji-Won;Park, Jinsu;Choi, Hanshin
    • Journal of Powder Materials
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    • v.27 no.3
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    • pp.256-267
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    • 2020
  • Metal additive manufacturing (AM) technologies are classified into two groups according to the consolidation mechanisms and densification degrees of the as-built parts. Densified parts are obtained via a single-step process such as powder bed fusion, directed energy deposition, and sheet lamination AM technologies. Conversely, green bodies are consolidated with the aid of binder phases in multi-step processes such as binder jetting and material extrusion AM. Green-body part shapes are sustained by binder phases, which are removed for the debinding process. Chemical and/or thermal debinding processes are usually devised to enhance debinding kinetics. The pathways to final densification of the green parts are sintering and/or molten metal infiltration. With respect to innovation types, the multi-step metal AM process allows conventional powder metallurgy manufacturing to be innovated continuously. Eliminating cost/time-consuming molds, enlarged 3D design freedom, and wide material selectivity create opportunities for the industrial adoption of multi-step AM technologies. In addition, knowledge of powders and powder metallurgy fuel advances of multi-step AM technologies. In the present study, multi-step AM technologies are briefly introduced from the viewpoint of the entire manufacturing lifecycle.

Improvement of $\lambda$--window Range of the Three-Way Catalyst for Natural Gas Vehicles (천연가스 자동차용 삼원촉매의 $\lambda$-윈도우 영역 개선)

  • 최병철;정필수
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.1
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    • pp.92-100
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    • 2000
  • The model gas reaction tests were carried out to investigate the purification characteristics of methane on the exclusive catalyst for NGV. The experiment was conducted with the factors which affect the conversion efficiency of methane, such as Redox ratio, coexistence components of CO, MO, $H_2$O, precious metals and additives. The catalyst loaded with larger amount of pd and with additive La showed lower light-off temperature. In the presence of CO and NO, the conversion efficiency of methane was varied according to the kind of additive loaded. The conversion efficiency of methane was dropped for the catalyst loaded with La under lean air-fuel ratio, while it increased for the one loaded with Ti+Zr for the same condition. It was shown that the water vapor inhibited methane from oxidation by its poisoning on the surface of catalyst.

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Sintering and Characterization of SiC-matrix Composite Including TRISO Particles (TRISO 입자를 포함하는 SiC 복합소결체의 소결 및 특성 평가)

  • Lee, Hyeon-Geun;Kim, Daejong;Park, Ji Yeon;Kim, Weon-Ju
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.418-423
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    • 2014
  • Fully ceramic micro encapsulated (FCM) nuclear fuel is a concept recently proposed for enhancing the stability of nuclear fuel. FCM nuclear fuel consists of tristructural-isotropic (TRISO) fuel particles within a SiC matrix. Each TRISO fuel particle is composed of a $UO_2$ kernel and a PyC/SiC/PyC tri-layer which protects the kernel. The SiC ceramic matrix is created by sintering. In this FCM fuel concept, fission products are protected twice, by the TRISO coating layer and by the SiC ceramic. The SiC ceramic has proven attractive for fuel applications owing to its low neutron-absorption cross-section, excellent irradiation resistivity, and high thermal conductivity. In this study, a SiC-matrix composite containing TRISO particles was sintered by hot pressing with $Al_2O_3-Y_2O_3$ additive system. Various sintering conditions were investigated to obtain a relative density greater than 95%. The internal distribution of TRISO particles within the SiC-matrix composite was observed using an x-ray radiograph. The fracture of the TRISO particles was investigated by means of analysis of the cross-section of the SiC-matrix composite.

A Study on Lubricant additive of DME Common-rail Vehicle (DME 커먼레일 차량의 윤활향상제에 관한 연구)

  • Park, JungKwon;Kim, Hyunchul;Jeong, SooJin;Chon, MunSoo
    • Journal of Institute of Convergence Technology
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    • v.3 no.1
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    • pp.15-18
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    • 2013
  • The next generation alternative fuel of diesel, DME (Dimethyl Ether) discharges particulate matter hardly due to chemical structural as oxygen-fuel so it has the eco-friendly property. Despite these advantages, the DME has the technical difficulties to apply to the diesel engine because of a low calorific value, viscosity and compressibility effects. From this point of view, we performed experimental studies on improved reliability of DME common-rail vehicle and lubricity enhancement of DME fuel for empirical distribution of eco-friendly DME fuel. Also we analyzed solubility of lubrication enhancer according to a drop in temperature, try to secure reliability about core parts of DME vehicle by applying lubrication enhancer in the DME common-rail vehicle.

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The Characteristics of Exhaust Emissions by using Oxygenated Fuels and EGR in IDI Diesel Engine (함산소연료(Diglyme, DEE)와 EGR 방법을 이용한 간접분사식 디젤기관의 배기가스 배출 특성)

  • 유경현;오영택
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.6
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    • pp.108-116
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    • 2002
  • The diesel engine is one of the most effective transport options available in all sizes and covering a wide range of applications. But, many researchers developing the diesel engine are facing tough challenges in view of the increasingly lower emissions standards. Thus, this study will explore the possible fuel additive technology to further reduce the emissions from the IDI diesel engine. The purpose of this study is to investigate the effects of oxygenated fuels on the exhaust emissions and to attain a better trade-off relation between smoke and NOx in four cylinder diesel engine. Experiments were conducted with oxygenated fuels as an effective way to improve the combustion efficiency. Some of oxygenated fuel(Diglyme and DEE) were added to the conventional diesel fuel which had no an oxygen content. Also, EGR was adopted for reducing NOx without any strong adverse effects on other exhaust emissions. This study concluded that exhaust emissions in diesel engine could be reduced by adding the oxygenated fuels which had lower boiling point, and the combustion efficiency was also improved as the oxygen content in fuel increased.

A Study on the Reduction of Particulate Emission Using Oil Soluble Organometallic Compounds as Combustion Improver for Heavy Fuel Oil (중질유 연소시 유용성 유기금속화합물 연소촉진제의 Dust 저감특성)

  • Kim, Dong-Chan;Nho, Nam-Sun;Woo, Je-Kyung;Kim, Jin-Hoon;Lee, Young-Sea
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.1
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    • pp.55-62
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    • 2008
  • This study is aimed at substantially reducing the particulate matter (dust) emission during the combustion of heavy fuel in boilers by addition of combustion improver. The combustion improver used were the oil-soluble organometallic compounds that were found to be more effective than the dispersing agents that are generally used for reducing the particulate emission. The dust reduction effect was found to depend on the active materials (metals) as well as on the organic ligand part of organometallic compounds. Acetylacetonoate and naphthenate of Fe and Ca were found to be most effective for dust reduction. Addition of Fe and Ca organometallic compounds as combustion improver in concentration of 30 ppm (metal basis) to heavy fuel oil, caused dust reduction by 50 wt% to 80 wt%.

A study on the characteristics of fuel performance according to the oxygenated additive type for gasoline fuel Part 2. Exhaust and Non-regulated, PM emission characteristics (휘발유 연료용 함산소 첨가제 종류에 따른 성능 특성 연구 Part 2. 배출가스 및 미규제 물질, 입자상 물질 특성)

  • Lee, Min-Ho;Kim, Ki-Ho;Ha, Jong-Han
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.2
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    • pp.374-384
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    • 2016
  • Concern about air pollution is gradually rising up in domestic and foreign, automotive and fuel researchers are trying to reduce vehicle exhaust emissions, through a lot of approaches, which consist of new engine design and innovative after-treatment systems, using clean (eco-friendly alternative) fuels and fuel quality improvement. This research is proceeding by two main issues : exhaust emissions and PM particle emissions of gasoline vehicle. Exhaust emissions, non-regulated emissions and PM (particulate matter) particles of automotive are causing many problems which ambient pollution and harmful effects on the human body. The main particulate fraction of automotive exhaust emissions consists of small particles. Because of their small size, inhaled particles can easily penetrate deep into the lungs. The rough surfaces of these particles make it easier for them to combine with other toxins in the environment. Thus, the hazards of particle inhalation are increased. Based on the oxygenated fuel additive types (MTBE, Bio-ETBE, Bio-ethanol, Bio-butanol), this paper discussed the influence of oxygen contents on gasoline vehicle exhaust emissions, non-regulated emissions and nano-particle emissions. Also, this paper assessed exhaust emission characteristics at 2 type test modes. The test modes were FTP-75 and HWFET. All measurement items be verified less than the value of regulated emissions. It could be known difference increase and decrease by each measurement item depending on increase the oxygen contents.

Extinguishing Characteristics of Liquid Pool Eire by Water Mist Containing Sodium Salt (나트륨 염이 첨가된 미분무수의 액체 pool fire소화특성)

  • Park Jae-Man;Shin Chang-Sub
    • Fire Science and Engineering
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    • v.19 no.3 s.59
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    • pp.13-19
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    • 2005
  • An experimental study is presented for extinguishing characteristics of liquid fuel fire by water mist containing sodium acetate trihydrate. To evaluate the extinguishing performance of water mist containing an additive, the evaporation characteristics of a water droplet on a heated surface was examined. The evaporation process was recorded by a charge-coupled-device camera. Also, small-scale extinguishing tests were conducted for n-heptane pool fire in ventilated space to measure flame temperature variation. The average evaporation rate of a water droplet containing an additive was lower than that of a pure water droplet at a given surface temperature due to the precipitation of salt in the liquid-film and change of surface tension. In case of using an additive, the flame temperature was lower than that of pure water at a given discharge pressure and it was because the momentum of a water droplet containing an additive was increased reducing flame size. And also dissociated metal atoms, sodium, were reacted as a scavenger of the major radical species OH^-,\;H^+$ which were generated for combustion process. Moreover, at a high pressure of 4MPa, the fire was extinguished through blowing effect as well as primary extinguishing mechanisms.

Fuel Characteristics of Pitch Pine and Mongolian Oak Pellets Fabricated with Coffee Waste and Used Frying Oil as an Additive Using a Pilot-scale Flat-die Pellet Mills (식품부산물인 커피박과 폐식용유를 첨가제로 사용하여 파일럿 규모의 평다이 성형기로 제조한 리기다소나무 및 신갈나무 펠릿의 연료적 특성)

  • Yang, In;Jin, Xuanjun;Han, Gyu-Seong
    • New & Renewable Energy
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    • v.18 no.3
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    • pp.23-31
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    • 2022
  • This study evaluated the potential of coffee waste (CW) and used frying oil (UFO) as an additive in the production of pitch pine (PIP) and Mongolian oak (MOK) pellets. Ash contents obtained from CW and UFO were 0.5% and <0.1%, respectively. The calorific values of UFO (31.4 MJ/kg) and CW (26.3 MJ/kg) are higher than PIP (20.6 MJ/kg) and MOK (19.1 MJ/kg). For pellets fabricated using a pilot-scale flat-die pellet mill, regardless of fabricating conditions, moisture content (MC) and bulk density of PIP and MOK pellets satisfied the A1 wood pellet standard for residential and small-scale commercial uses, as designated by the National Institute of Forest Science (NIFOS) of the Republic of Korea. When CW was used as an additive, durability of PIP pellets made with 12%-MC sawdust and MOK pellets increased. The optimal conditions for producing PIP and MOK pellets could be by adding 20 mesh CW as an additive and the using of 12%-MC sawdust. However, durability of PIP pellets and ash content MOK pellets did not satisfy the A1 wood pellet standard of NIFOS. Thus, further research is needed to improve the properties of wood pellets with additives.