• Title/Summary/Keyword: Fuel Properties

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The CO2 Emission in the Process of Cement Manufacture Depending on CaO Content (시멘트 생산과정에 따른 CaO 함량과 CO2의 발생량)

  • Kim, Sang-Hyo;Hwang, Jun-Pil
    • Journal of the Korea Concrete Institute
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    • v.25 no.4
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    • pp.365-370
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    • 2013
  • In this study, contents of limestone in cement manufactured by six domestic plants for Portland cement were investigated in terms of the strength and its relation to the $CO_2$ emission due to limestone material and its physical properties in cement manufacturing process. the relationship among CaO content, compressive strength, and $CO_2$ emission was surveyed for the limestone quantity in decomposition reaction and the loss of limestone quantity contained in each cement. As a result of $CO_2$ emission calculation for unit cement, it was found that the $CO_2$ emission due to decomposition of limestone was occupied 67% of total emission quantity. Furthermore, there was a difference in $CO_2$ emission quantity depending on the cement manufacturing process management. Also, it was shown that fossil fuel usage and material loss had a major influence as main factors of $CO_2$ emission. An increase in the CaO content in cement resulted in an increase in the compressive strength. On the contrary, CaO content and compressive strength were reduced with the growth of loss quantity of limestone. It was verified that the material and process management were more effective than CaO yield in cement manufacturing for $CO_2$ emission with the growth of $CO_2$ emission quantity. Pozzolanic materials such as PFA and GGBS in concrete mix affected the price, $CO_2$ emission and development of strength of concrete.

A Study on the oxidation characteristics of micro-algal bio diesel derived from Dunaliella tertiolecta LB999 (Dunaliella tertiolecta LB999 유래 바이오디젤의 산화특성 연구)

  • Lee, Don-Min;Lee, Mi-Eun;Ha, Jong-Han;Ryu, Jin-Young;Choi, Chang-Yong;Shim, Sang-Hyuk;Lim, Sang-Min;Lee, Choul-Gyun;Lee, Bong-Hee
    • Journal of Marine Bioscience and Biotechnology
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    • v.7 no.1
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    • pp.1-10
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    • 2015
  • Bio diesel has advantages to reduce GHG(Greenhouse Gas) compare with the fossil fuel by using oil comes from plant/animal sources and even waste such as used cook oil. The diversity of energy feeds brings the positive effects to secure the national energy mix. In this circumstance, micro-algae is one of the prospective source, though some technical barriers. We analyzed the bio diesel which was derived from Dunaliella tertiolecta LB999 through the BD100 quality specifications designated by the law. From that result, it is revealed that the oxidation stability is one of the properties to be improved. In order to find the reason for low oxidation stability, we analyzed the oxidation tendency of each FAME components through some methods(EN 14111, EN14112, EN16091). In this study, we could find the higher double bond FAME portion, the more oxidative property(C18:1${\ll}C18:3$) in bio diesel and main unsaturated FAME group is acted as the key component deciding the bio diesel's oxidation stability. It is proved experimentally that C18:3 FAME are oxidized easily under the modified accelerated oxidation test. We also figure out low molecular weight hydrocarbon and FAME were founded as a result of thermal degradation. Some alcohol and aldehydes were also made by FAME oxidation. In conclusion, it is necessary to find the way to improve the micro-algal bio diesel's oxidation stability.

Characteristics of Ambient Particulate Matter in Gwangju (광주지역 먼지 특성에 관한 연구)

  • Seo, Gwang-Yeob;Kim, Seung-Ho;Lee, Kyoung-Seok;Min, Kyoung-Woo;Seo, Hee-Jeong;Kang, Yeong-Ju;Paik, Ke-Jin;Moon, Young-Woon;Shin, Dae-Yewn
    • Journal of Environmental Health Sciences
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    • v.36 no.2
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    • pp.108-117
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    • 2010
  • In this study, ambient particulate matter ($PM_{2.5}$ and $PM_{10}$) levels were measured and their chemical and physical properties were characterized. Two sites in Gwangju were sampled once a month from December 2008 to November 2009. The annual mean concentrations of $PM_{2.5}$ and $PM_{10}$ were $26.9\;{\mu}g/m^3$ and $46.3\;{\mu}g/m^3$, respectively, in Nongseongdong and $26.1\;{\mu}g/m^3$ and $44.8\;{\mu}g/m^3$, respectively, in Duam-dong. $PM_{2.5}$ levels were 1.8 times higher than the USA Environmental Protection Agency (EPA) national ambient air quality standard for $PM_{2.5}$ ($15\;{\mu}g/m^3$). The average $PM_{2.5}/PM_{10}$ ratio of 0.58 suggested that $PM_{2.5}$ is a significant component of the ambient particle pollution. The order of concentration of metallic elements in $PM_{2.5}$ and $PM_{10}$ was Si > Al > Fe > Zn > Pb > Cu > Mn. Cd was not detected. The earth crustal enrichment factors for Cr, Cu, Pb and Zn in $PM_{2.5}$ were higher than those in $PM_{10}$. When the earth crustal enrichment factors for Cr, Cu, Pb and Zn were higher than 10, this suggested influence from anthropogenic sources. The soil contribution ratios for $PM_{2.5}$ and $PM_{10}$ were 11.3% and 16.4%, respectively, and were higher in the fall and winter. Anions (${SO_4}^{-2}$, ${NO_3}^-$, and $Cl^-$) comprise 28.7% of $PM_{2.5}$ and 21.4% of $PM_{10}$. The correlation coefficient of Zn-Fe, Mn-Cu, Fe-Cu and Fe-Mn in $PM_{2.5}$ was high in the sampling sites, and metallic elements were primarily from anthropogenic sources such as fuel combustion and vehicle emissions.

VISUALIZATION AND MEASUREMENT OF A NARROW-CONE DI GASOLINE SPRAY FOR THE IMPINGEMENT ANALYSIS

  • Park, J.S.;Im, K.S.;Kim, H.S.;Lai, M.C.
    • International Journal of Automotive Technology
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    • v.5 no.4
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    • pp.221-238
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    • 2004
  • Wall interactions of direct injection spray were investigated using laser-sheet imaging, shadowgraphy, wetted footprint and phase Doppler interferometry techniques. A narrow-cone high-pressure swirl injector is used to inject iso-octane fuel onto a plate, which has three different impact angles inside a pressurized chamber. Heated air and plate conditions were compared with unheated cases. Injection interval was also varied in the heated case to compare dry- and wet- wall impingement behaviors. High-speed macroscopic Mie-scattering images showed that presence of wall and air temperature has only minor effect on the bulk spray structure and penetration speed for the narrow-cone injector tested. The overall bulk motions of the spray plume and its spatial position at a given time are basically unaffected until a few millimeters before impacting the wall. The surface properties of the impact surface, such as the temperature, the presence of a preexisting liquid film also have a small effect on the amount of wetting or the wetted footprint; however, they have strong influence on what occurs just after impact or after a film is formed. The shadowgraph in particular shows that the plate temperature has a significant effect on vapor phase propagation. Generally, 10-20% faster horizontal vapor phase propagation is observed along the wall at elevated temperature condition. For impingement onto a preexisting film, more splash and evaporation were also observed. Contrary to some preconceptions, there is no significant splashing and droplet rebounding from surfaces that are interposed in the path of the DI gasoline spray, especially for the oblique impact angle cases. There also appears to be a dense spray front consists of large sac spray droplets in the oblique impact angle cases. The bulk of the spray is not impacted on the surface, but rather is deflected by it The microscopic details as depicted by phase Doppler measurements show that the outcome of the droplet impaction events can be significantly influenced. Only droplets at the spray front have high enough Weber numbers for wall impact to wet, splash or rebound. Using the sign of vertical velocity, the time-resolved downward droplets and upward droplets are compared. The Weber number of upward moving droplets, which seldom exceeds unity, also decreases as the impact angle decreases, as the droplets tend to impact less and move along the wall in the deflected spray plume.

The Vegetation and Soil Characteristics of Urban Forest as Geological Location in Daejeon, Korea (대전시 도시숲의 입지에 따른 식생 및 토양특성)

  • Lee, Ho-Young;Oh, Choong-Hyeon;Kim, Eun-Shik;Son, Yo-Whan;Park, Kwan-Soo
    • Korean Journal of Environment and Ecology
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    • v.24 no.5
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    • pp.566-574
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    • 2010
  • This study was carried out for the purpose of understanding the situation of the urban forest and presenting basic data bases for a proper management plan through the analysis of forest vegetation and soil characteristics. In three representative urban forests of Deajeon, we analyzed the differences of vegetation and soil properties in each geological location. The indices of ecological health such as Species Diversity and Maximum Species Diversity are increasing in the order of Namseon Park, Wolpyung Park and Mt. Bomun; the first is in the center of the city, the second is well-conserved inner-city park and the third is in the border of the city. In the soil analysis of Namseon Park where human disturbance is strong, the surface fuel bed was very thin just 0.5cm and the soil was harder than the other two urban forests, the soil hardness was $0.5{\sim}3.7kg/cm^2$. All three urban forests showed low $pH_{1:5}$ under 5.0 except Robinia pseudo-acasia association of Wolpyung and low exchangeable cation level. These results say that the urban forests of Deajeon have been being acidified severely and the eluviation of exchangeable cation is proceeding. The organic matter and the available phosphate level was lower than the average level of Korean forest. It means that nutrition supply is not sufficient. In Daejeon urban forests, the management plan of urban forest is necessary according to the analysis result of vegetation and soil.

Thermal Storage Characteristics of Low Temperature Phase Change Materials for Thermal Environmental Control of Protected Cultivation System (시설 농업의 열환경조절을 위한 저온 상변화 물질의 축열 특성)

  • 송현갑;유영선;노정근;박종길
    • Journal of Bio-Environment Control
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    • v.6 no.3
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    • pp.216-224
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    • 1997
  • In the recent 10 years the protected cultivation area in Korea has been increased rapidly, and now it is very important issue to develop the heating and cooling system using the renewable energy, because the greenhouse heating and cooling cost is increased with the fossil fuel price rises. Actually the development of the cooling system is more difficult than that of the heating system, since the cooling load of greenhouse in the summer season is 2―3 times larger than the heating load in the winter season. In this study low temperature phase change materials (LTPCM) for the cold storage system were selected and developed. The theoretical and experimental analysis of thermal characteristics of LTPCM makes it possible to control the phase change temperature and stabilize the thermo-physical properties. LTPCM developed in this study has good advantages to be used as the cold storage not only for the house and working space in factory but also for the cold storage of agricultural and live-stock products.

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A Study on the Method for the Removal of Radioactive Corrosion Produce Using Permanent and Electric Magnets

  • Kong Tae-Young;Song Min-Chul;Lee Kun-Jai
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.2
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    • pp.113-123
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    • 2005
  • The removal of radioactive corrosion products from the reactor coolant through a magnetic filter system is one of the many approaches being investigated as a means to reduce radiation sources and exposures to the operational and maintenance personnel in a nuclear power plant. Many research activities in water chemistry, therefore, have been performed to provide a filtration system with high reliability and feasibility and are still in process. In this study, it was devised the magnetic filter system with permanent and electric magnets to remove the corrosion products in the coolant stream taking an advantage of the magnetic properties of corrosion particles. Permanent magnets were used for separation of corrosion products and electric magnets were utilized for flocculation of colloidal particles to increase in their size. Experiments using only permanent magnets, in the previous study, displayed the satisfactory outcome of filtering corrosion products and indicated that the removal efficiency was more than 90 $\%$ for above 5 $\mu$m particles. Experiments using electric magnets also showed the good performance of flocculation without chemical agents and exhibited that most corrosion particles were flocculated into larger aggregates about 5 $\mu$m and over in diameter. It is, thus, expected that the magnetic filter system with the arrangement of permanent and electric magnets will be an effective way for the removal of radioactive corrosion products with considerably high removal efficiency.

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A Study on the Constructing Discrete Fracture Network in Fractured-Porous Medium with Rectangular Grid (사각 격자를 이용한 단열-다공암반내 분리 단열망 구축기법에 대한 연구)

  • Han, Ji-Woong;Hwang, Yong-Soo;Kang, Chul-Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.1
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    • pp.9-15
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    • 2006
  • For the accurate safety assessment of potential radioactive waste disposal site which is located in the crystalline rock it is important to simulate the mass transportation through engineered and natural barrier system precisely, characterized by porous and fractured media respectively. In this work the methods to construct discrete fracture network for the analysis of flow and mass transport through fractured-porous medium are described. The probability density function is adopted in generating fracture properties for the realistic representation of real fractured rock. In order to investigate the intersection between a porous and a fractured medium described by a 2 dimensional rectangular and a cuboid grid respectively, an additional imaginary fracture is adopted at the face of a porous medium intersected by a fracture. In order to construct large scale flow paths an effective method to find interconnected fractures and algorithms of swift detecting connectivities between fractures or porous medium and fractures are proposed. These methods are expected to contribute to the development of numerical program for the simulation of radioactive nuclide transport through fractured-porous medium from radioactive waste disposal site.

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Feasibility Study on Vitrification for Rare Earth Wastes of PyroGreen Process (파이로그린공정 희토류폐기물 유리화 타당성 연구)

  • Kim, Cheon-Woo;Lee, Byeong Gwan
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.1
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    • pp.1-9
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    • 2013
  • The rare earth oxide wastes consisting of major 8 nuclides Y, La, Ce, Pr, Nd, Sm, Eu and Gd, are generated during the salt waste treatment of PyroGreen process. The final form of the rare earth is generated as the oxide state. In this study, six candidate glasses were developed to evaluate the feasibility for vitrifying the rare earth oxide wastes within the borosilicate glass system. The solubilities of the mixture of the rare earth oxide waste showed less than 25wt% at $1,200^{\circ}C$, less than 30wt% at $1,300^{\circ}C$, respectively. It means that solubility is increased with the temperature increment. The liquidus temperature of the homogeneous glass with 20wt% waste loading was determined as less than $950^{\circ}C$. In more than solubility of rare earth oxides glass, formation of rare earth-oxide-silicate crystal in glass-ceramic occurred as the secondary phase. As their viscosity at melting temperature $1,200{\sim}1,300^{\circ}C$ was less than 100 poise, electrical conductivity was higher than 1 S/cm, 20~25wt% waste loading glasses with good surface homogeneity are judged to have good operability in cold crucible induction melter. Other physicochemical properties of the developed glasses are going to be experimented in the future.

Dynamic Response Analysis for Upper Structure of 5MW Offshore Wind Turbine System based on Multi-Body Dynamics Simulation (다물체 동역학 시뮬레이션 기반 5MW급 해상풍력발전시스템의 상부구조물에 대한 동적 응답 해석)

  • Lee, Kangsu;Im, Jongsoon;Lee, Jangyong;Song, Chang Yong
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.16 no.4
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    • pp.239-247
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    • 2013
  • Recently renewable energy such as offshore wind energy takes a higher interest due to the depletion of fossil fuel and the environmental pollution. This paper deals with multi-body dynamics (MBD) analysis technique for offshore wind turbine system considering aerodynamic loads and Thevenin equation used for determination of electric generator torque. Dynamic responses of 5MW offshore wind turbine system are evaluated via the MBD analysis, and the system is the horizontal axis wind turbine (HAWT) which generates electricity from the three blades horizontally installed at upwind direction. The aerodynamic loads acting on the blades are computed by AeroDyn code, which is capable of accommodating a generalized dynamic wake using blade element momentum (BEM) theory. In order that the characteristics of dynamic loads and torques on the main joint parts of offshore wind turbine system are simulated similarly such an actual system, flexible body modeling including the actual structural properties are applied for both blade and tower in the multi-body dynamics model.