• Journal of the Korean Electrochemical Society
• /
• v.10 no.2
• /
• pp.110-115
• /
• 2007

Solid oxide fuel cell(SOFC) has high fuel flexibility due to its high operating temperatures. Hydrocarbonaceous fuels such as diesel has several advantages such as high energy density and established infrastructure for fuel cell applications. However diesel reforming has technical problems like coke formation in a reactor, which results in catastrophic failure of whole system. Performance degradation of diesel autothermal reforming (ATR) leads to increase of undesirable hydrocarbons at reformed gases and subsequently degrades SOFC performance. In this study, we investigate the degradation of SOFC performance(OCV, open circuit voltage) under hydrocarbon(n-Butane) feeds and characteristics of diesel performing under various ratios of reactants($H_2O/C,\;O_2/C$ molar ratios) for improvement of SOFC performance. Especially we achieved relatively high performance of diesel ATR under $H_2O/C=0.8,\;O_2/C=3$ condition.

• Journal of Ceramic Processing Research
• /
• v.19 no.6
• /
• pp.514-518
• /
• 2018

The direct carbon fuel cell (DCFC) has attracted researcher's attention recently, due to its high conversion efficiency and its abundant fuel, carbon. A DCFC mathematical model has developed in two-dimensional, lab-scale, and considers Boudouard reaction and carbon monoxide (CO) oxidation. The model simulates the CO production by Boudouard reaction and additional electron production by CO oxidation. The Boudouard equilibrium strongly depends on operating temperature and affects the amount of produced CO and consequentially affects the overall fuel cell performance. Two different operating temperatures (973 K, 1023 K) has been calculated to discover the CO production by Boudouard reaction and overall fuel cell performance. Moreover, anode thickness of the cell has been considered to find out the influence of the Boudouard reaction zone in fuel cell performance. It was found that in high temperature operating DCFC modeling, the Boudouard reaction cannot be neglected and has a vital role in the overall fuel cell performance.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.10 no.5
• /
• pp.1-8
• /
• 2002

For gasoline engines, a three-way catalytic converter that has the maximum efficiency at stoichiometric air/fuel ratio is used to clean up the exhaust gas. So a precise air/fuel ratio control is necessary to maximize the catalytic conversion efficiency, For a transient condition, a fred-forward air/fuel ratio control method that estimates the air mass inducted into a cylinder is being used. In this study, a fuel injection map that makes an accurate air/fuel ratio control possible was constructed for the very same transient condition. For the same condition above, intake air model and fuel model were refined so that fuel injection values based on air mass through a throttle valve and intake manifold pressure are equal to the map values.

• 한국전기화학회:학술대회논문집
• /
• 2005.04a
• /
• pp.43-43
• /
• 2005

• New & Renewable Energy
• /
• v.4 no.3
• /
• pp.5-14
• /
• 2008

The target for the reduction of $CO_2$ emissions, as specified in the Kyoto Protocol, can only be achieved by an extended use of renewable fuels and the increasing of the energy efficiency. The energy generation from waste gases with a reasonable content of methane like biogas can significantly contribute to reach this target. A further reduction of greenhouse gas emissions is possible by increasing the electrical efficiency using progressive technologies. Fuel cells can be highly energy conversion devices. Utilizing biogas as the fuel for fuel cell systems offers an option that is technically feasible, potentially economically attractive and greenhouse gas neutral. High temperature fuel cells that are able to operate with carbon monoxide in the feed are well suited to these applications. Furthermore, because they do not require noble metal catalysts, the cost of high-temperature fuel cells has the greatest potential to become competitive in the near future compared to other types of fuel cells.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.23 no.4
• /
• pp.410-419
• /
• 2015

In this study, the roadability, fuel economy and emission characteristics were evaluated for a natural gas converted vehicle. The results are as follows; Not only the shortage of power was observed in stall test, but also large deterioration of acceleration performance was exposed in roadability. Compared to the original LPG system, the acceleration is 76% in start acceleration and 45 ~ 65% in overtaking acceleration, especially the decline became larger when air conditioner is at work. Furthermore, because the mapping data, which controls the injection depending on driving condition, do not match up with injection system, the failure of air-fuel ratio feedback control occurs resulting from the large gap between the required and the really supplied amount of fuel. This failure cause the exhaust gas to emit without catalytic conversion and the fuel economy based on the fuel heat value to get worse 22% in the mode test and 16% in road test respectively. In addition, the existing injection system does not secure enough fuel at the starting so that it may lead to the fail of clod start, the deterioration of hot start and inharmonic of engine at the idle after start.

• Proceedings of the KIEE Conference
• /
• 1991.07a
• /
• pp.3-12
• /
• 1991

Fuel cells are electrochemical devices that convert the chemical reaction energy directly into the electrical energy. In a typical fuel cell, gaseous fuel is fed continuously to the anode(negative electrode) compartment and the oxidant(i.e, oxygen from air) is fed continuously to the cathode(positive electrode) compartment; the electrochemical reactions take place at the electrodes to produce an electric current. Many of the operational characteristics of fuel cell systems are superior to those of conventional power generation system because of good efficiency, environmental protection, safty, modularity etc. From those reasons, the fuel cells are considered to be the solution to the future problem of energy conversion. The objective of this paper is to introduce the technical status of fuel cell technologies and our national project for the development of the phosporic acid fuel cell.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2008.06a
• /
• pp.510-511
• /
• 2008

Fuel cell is a modular, high efficient and environmentally energy conversion device, it has become a promising option to replace the conventional fossil fuel based electric power plants. The high temperature fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for solid oxide fuel cell, by the way, Ni-YSZ materials are used as anode of high temperature widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(40vol%) was better excellent than the others.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.15 no.5
• /
• pp.105-111
• /
• 2007

In this study, we investigated the conversion performance of de-NOx catalyst for lean-burn natural gas engine. As a de-NOx catalyst, NOx storage reduction catalyst was composed of Pt, Pd and Rh with washcoat including Ba and Ni, Ru-ZSM-5. Ni, Ru-ZSM-5, which was regarded as a NOx direct decomposition catalyst, was made up of ion exchanged ZSM-5 by 5wt.% Ni or Ru. The performance of de-NOx catalyst was evaluated by NOx storage capacity and catalytic reduction in air/fuel, $\lambda=1.6$. The catalytic reaction was also observed when the added fuel was supplied to fuel rich atmosphere by fuel spike period of 5 seconds. The NOx conversion of the catalysts with Ni-ZSM-5 or Ru-ZSM-5 was mainly caused by the effect of NOx adsorption of Ba rather than the catalytic reduction of Ni, Ru-ZSM-5. Ni, Ru-ZSM-5 catalysts can not use for the NSR catalyst because they have quick process in thermal deactivation.

• 한국신재생에너지학회:학술대회논문집
• /
• 2009.11a
• /
• pp.218-221
• /
• 2009

Solid oxide fuel cells (SOFCs), as high-temperature fuel cells, have various advantages. In some merits of SOFCs, high temperature operation can lead to the capability for internal reforming, providing fuel flexibility. SOFCs can directly use CH4 and CO as fuels with sufficient steam feeds. However, hydrocarbons heavier than CH4, such as ethylene, ethane, and propane, induce carbon deposition on the Ni-based anodes of SOFCs. In the case of the ethylene steam reforming reaction on a Ni-based catalyst, the rate of carbon deposition is faster than among other hydrocarbons, even aromatics. In the reformates of heavy hydrocarbons (diesel, gasoline, kerosene and JP-8), the concentration of ethylene is usually higher than other low hydrocarbons such as methane, propane and butane. It is importatnt that ethylene in the reformate is removed for stlable operation of SOFCs. A new methodology, termed post-reforming was introduced for removing low hydrocarbons from the reformate gas stream. In this work, activity tests of some post-reforming catalysts, such as CGO-Ru, CGO-Ni, and CGO-Pt, are investigated. CGO-Pt catalyst is not good for removing ethylene due to low conversion of ethylene and low selectivity of ethylene dehydrogenation. The other hand, CGO-Ru and CGO-Ni catalysts show good ethylene conversion, and CGO-Ni catalyst shows the best reaction selectivity of ethylene dehydrogenation.