• Journal of Korean Society of Environmental Engineers
• /
• v.33 no.3
• /
• pp.167-173
• /
• 2011

The Effects of external resistance on electrical properties such as current density, power density and coulombic efficiency were investigated in two-chamber type MFCs using a ferricyanide as reducing agent. A stable electricity was produced when a constant time elapsed after innoculation of mixed cultures into the anode compartment; voltages from 0.13 to 0.16 V was measured at $50{\Omega}$ of external resistance. When the external resistance was increased, the current density decreased and the power density rapidly increased and then slowly decreased. Big variation of electrical properties was observed in high-current density region due to the concentration loss related with substrate consumption in repeated experiments changing the external resistance. The maximum power density ($175.8mW/m^2$) and coulombic efficiency (46.1%) were obtained at $100{\Omega}$ of the external resistance which is nearest with the internal resistance ($134{\Omega}$) of MFC system.

• Applied Chemistry for Engineering
• /
• v.18 no.4
• /
• pp.337-343
• /
• 2007

The reforming catalyst and the electrodes in fuel cells can be poisoned by the organic sulfur compound which is added as an odorant for checking out the leakage of natural gas, and that makes a big problem of system degradation. In this study, various adsorbents, such as silica, ${\gamma}$-alumina, activated carbon, HZSM-5, Ultra-stable Y zeolite (USY), and beta zeolite (BEA), were utilized to remove tetra-hydrothiophene (THT) and tert-butylmercaptan (TBM), and to confirm the performance in the adsorption of those odorants by using a continuous adsorptive bed. The effects of Si/Al ratio of zeolites, adsorption temperature and the type of balance gas (methane or He) on the adsorption performance in the packed bed have been investigated. In addition, the competitive adsorption between TBM and THT on the adsorbents was also estimated. The result shows that H-type BEA zeolite exhibited the highest adsorption capacity for TBM and THT odorant, and the higher amount of THT was removed adsorptively on the same adsorbent than TBM. The physical and chemical adsorption of those compounds on acid sites of zeolite were confirmed by temperature programmed desorption (TPD) and infrared spectrum (IR) analyses.

• Korean Chemical Engineering Research
• /
• v.49 no.5
• /
• pp.644-651
• /
• 2011

Storing hydrogen in solid state hydride is one of the best promising methods for the future hydrogen economy. The total performance of such systems depends on the rate at which the amount of mass and heat migration is supplied to solid hydride. Therefore, an accurate modeling of the heat and mass transfer is of prime importance in optimizing the design of such systems. In this work, Hydrogen storage in Pt-CNTs hydrogen reactor has been intensively investigated by solving 2 dimensional mathematical models. Using a CFD computer software, systematic studies have been performed to elucidate the effect of heat and mass transfer during hydrogen charging periods. It was revealed that the optimized design of hydrogen storage vessel can prevent the increase of system temperature and the charging time due to the convective cooling effects inside the vessels at even high charging pressure. Because none has reported the critical issues of heat and mass transfer for CNT based hydrogen storage system, this work can support the first insight of the optimal design for solid state hydrogen storage system based on CNT in the near future.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.34 no.8
• /
• pp.767-774
• /
• 2010

In a passive-type PEMFC stack, axial fans operate to supply both oxidant and coolant to cathode side of the stack. It is possible to make a simple system because the passive-type PEMFC stack does not require additional cooling equipment. However, the performance of a cooling system in which water is used as a coolant is better than that of the air-cooling system. To ensure system reliability, it is essential to make cooling system effective by adopting an optimal stack design. In this study, a numerical investigation has been carried out to identify an optimum cooling strategy. Various channel configurations were applied to the test section. The passive-type PEMFC was tested by varying airflow rate distribution at the cathode side and external heat transfer coefficient of the stack. The best cooling performance was achieved when a channel with thick ribs was used, and the overheating at the center of the stack was reduced when a case in which airflow was concentrated at the middle of the stack was used.

• Journal of the Korea Convergence Society
• /
• v.2 no.4
• /
• pp.21-27
• /
• 2011

Recently, new distributed power sources such as photovoltaic, wind power, fuel cell systems etc. are energetically interconnected and operated in the distribution feeders, as one of the national projects for alternative energy. When new power sources are considered to be interconnected to distribution systems, bi-directional power flow and interconnection conditions of new power sources may cause several power quality problems like voltage sag, voltage swell, harmonics, since new power sources can change typical characteristics of distribution systems. Under these situations, this paper deals with the analysis the power quality problems at primary and secondary feeders in distribution systems, when new power sources like photovoltaic (PV) systems are interconnected, by using the test devices for PV systems based on the LabVIEW S/W. This paper presents the test device which is consisted with model distribution system and model PV systems. By performing the simulation for power quality operation characteristic based on the test facilities, this paper presents the optimal countermeasures for power quality.

• 한국신재생에너지학회:학술대회논문집
• /
• 2007.06a
• /
• pp.759-762
• /
• 2007

본 연구는 부문별 수소 및 연료전지의 수요량을 산정하고 원활한 수소공급을 위한 수소제조원의 최적믹스를 바탕으로 수소 도입 이후의 에너지믹스를 제시하는 것을 목표로 하고 있다. BaU 전망은 에너지경제연구원의 전망을 바탕으로 하였으며 기준안, 고유가안, 저유가안의 세가지 시나리오를 설정하여 각 시나리오별 분석을 수행하였다. 기준안에 따르면 수소 및 연료전지는 2015년 시장에 도입되어 2031년 5%의 시장보급률을 확보한 이후 보급률이 급격히 증가하는 것으로 나타났다. 수소 연료전지 시장중 특히 수송부문이 선도적 역할을 할 것으로 기대되며 FCV 보급대수는 2040년 1,132만대로 전체 자동차 시장의 48.4%를 차지할 전망이다. 최종에너지 중 수소의 비중은 2040년 8.7%에 이를 것으로 예측되며 수소의 도입으로 인해 1차에너지 중 신${\cdot}$재생에너지 비중이 BaU 대비 약 5.1%p 증가한 12.1%에 이를 것으로 분석되었다. 총 수소수요량은 777만톤에 이를 전망이다. 고유가안에서는 수소 및 연료전지가 2012년에 시장에 도입되는 것으로 가정하였으며 2040년 FCV 보급대수는 1,633만대에 이를 전망이다. 최종에너지 중 수소 비중은 11.5%에 이를 것으로 예상되며 1차에너지 신${\cdot}$재생에너지 비중은 11.6%로 분석되었다. 수소수요량은 1,015만톤으로 전망된다. 저유가안에서는 수소 및 연료전지가 2018년 도입되는 것으로 가정 하였다. 이 경우 2040년 FCV는 641만대가 보급되어 자동차 등록대수의 27.4%를 차지할 것으로 전망된다. 최종에너지 중 수소 비중과 1차에너지중 신${\cdot}$재생에너지 비중은 각각 5.5%, 9.1%에 이를 것으로 분석되었으며 수소수요량은 496만톤으로 전망된다.

• Membrane Journal
• /
• v.18 no.4
• /
• pp.274-281
• /
• 2008

Covalent-crosslinked sulfonated poly(arylene ether sulfone) (SPAES) copolymers were synthesized copolymerization technique and additionally crosslinked with divinylbenzene (DVB). To optimize the reaction condition, a concentration of crosslinking agent and a reaction time were varied in the ranges of $30{\sim}90\;v/v%$ and $30{\sim}720\;min$. The properties of the crosslinked membranes were investigated by SEM, TGA and the measurement of proton conductivity. It was found that the proton conductivity of crosslinked membranes decreased depending on a degree of crosslinking while water uptake and methanol permeability reduced.

• The Journal of the Korea institute of electronic communication sciences
• /
• v.6 no.6
• /
• pp.865-871
• /
• 2011

DC-DC converter commonly used in photovoltaic systems or fuel cell systems is a boost converter. Among several types of boost converter, the interleaved boost converter with small input and output current ripples is widely used in recent years. Because of small input and output current ripples, the circuit can reduce the size of the input and output capacitors. Thus, instead of conventional electrolytic capacitor, the film capacitor with high reliability can be used and this is the life and reliability of the entire system can be improved. In this paper, the input/output current ripple formulas of the multi-stage interleaved boost converter are derived, and the characteristics in accordance with duty are found out. In order to verify the above mentioned contents, the derived results will make a comparison with the calculated values by using PSIM tool.

• Korean Chemical Engineering Research
• /
• v.48 no.4
• /
• pp.534-539
• /
• 2010

The adsorptive removal of organic sulfur compounds including tert-butylmercaptane(TBM), tetrahydrothiophene(THT) and dimethylsulfide(DMS) in methane was investigated over NaY and copper-exchanged NaY(CuNaY) zeolites at 303 K and atmospheric pressure. In the ternary adsorption system, the preferential adsorption of THT over other sulfur compounds on NaY and the concurrent adsorption of all sulfur compounds on CuNaY were achieved, which could be explained by the breakthrough curve, the temperature-programmed desorption, and the apparent activation energy for desorption. The sulfur uptake capacity of CuNaY(2.90~3.20 mmol/g) was much higher than that of NaY(0.70~0.90 mmol/g). A comparative study indicated that the $Cu^{1+}$ sites and acidity of CuNaY were probably responsible for the strong interaction with sulfur atom and high sulfur uptake abilities.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.35 no.4
• /
• pp.361-369
• /
• 2011

The effect of an increase in the temperature of inlet air on the performance of a membrane humidifier for a PEMFC (Polymer Electrolyte Membrane Fuel Cell) vehicle was investigated both experimentally and numerically. A shell-and-tube type gas-to-gas humidifier with Nafion membrane was tested. The experimental result showed that water transfer varies nonlinearly with the temperature elevation. Numerical analysis based on detailed modeling was also conducted in simplified geometry of a single tube to explain this nonlinear behavior. The simulation revealed that the local water flux varies nonlinearly and dramatically along the tube. The analysis was based on the inverse relationship between the increase in temperature and decrease in relative humidity, both of which seriously affect the water conductivity of the membrane.